Difference between revisions of "Zinc carbonate"
(→Relevant Sciencemadness threads) |
|||
| Line 1: | Line 1: | ||
| − | '''Zinc carbonate''' is a white, insoluble, [[zinc]] salt with chemical formula [[Zinc|Zn]][[Carbonate|CO<sub>3</sub>]]. With it, most simple zinc salts can be made by reaction with the corresponding proportions of sulfate. | + | {{Chembox |
| + | | Name = Zinc carbonate | ||
| + | | Reference = | ||
| + | | IUPACName = Zinc carbonate | ||
| + | | PIN = | ||
| + | | SystematicName = | ||
| + | | OtherNames = Smithsonite<br>Zinc monocarbonate<br>Zinc spar<br>Zincspar | ||
| + | <!-- Images --> | ||
| + | | ImageFile = | ||
| + | | ImageSize = | ||
| + | | ImageAlt = | ||
| + | | ImageName = | ||
| + | | ImageFile1 = | ||
| + | | ImageSize1 = | ||
| + | | ImageAlt1 = | ||
| + | | ImageName1 = | ||
| + | | ImageFile2 = | ||
| + | | ImageSize2 = | ||
| + | | ImageAlt2 = | ||
| + | | ImageName2 = | ||
| + | | ImageFile3 = | ||
| + | | ImageSize3 = | ||
| + | | ImageAlt3 = | ||
| + | | ImageName3 = | ||
| + | | ImageFileL1 = | ||
| + | | ImageSizeL1 = | ||
| + | | ImageAltL1 = | ||
| + | | ImageNameL1 = | ||
| + | | ImageFileR1 = | ||
| + | | ImageSizeR1 = | ||
| + | | ImageAltR1 = | ||
| + | | ImageNameR1 = | ||
| + | | ImageFileL2 = | ||
| + | | ImageSizeL2 = | ||
| + | | ImageAltL2 = | ||
| + | | ImageNameL2 = | ||
| + | | ImageFileR2 = | ||
| + | | ImageSizeR2 = | ||
| + | | ImageAltR2 = | ||
| + | | ImageNameR2 = | ||
| + | <!-- Sections --> | ||
| + | | Section1 = {{Chembox Identifiers | ||
| + | | 3DMet = | ||
| + | | Abbreviations = | ||
| + | | SMILES = | ||
| + | }} | ||
| + | | Section2 = {{Chembox Properties | ||
| + | | AtmosphericOHRateConstant = | ||
| + | | Appearance = White or multicolored (smithsonite) | ||
| + | | BoilingPt = | ||
| + | | BoilingPtC = | ||
| + | | BoilingPt_ref = | ||
| + | | BoilingPt_notes = Decomposes | ||
| + | | Density = 4.398 g/cm<sup>3</sup> (20 °C) | ||
| + | | Formula = ZnCO<sub>3</sub> | ||
| + | | HenryConstant = | ||
| + | | LogP = | ||
| + | | MolarMass = 125.388 g/mol | ||
| + | | MeltingPt = | ||
| + | | MeltingPtC = 300 | ||
| + | | MeltingPt_ref = | ||
| + | | MeltingPt_notes = (decomposes) | ||
| + | | Odor = Odorless | ||
| + | | pKa = | ||
| + | | pKb = | ||
| + | | Solubility = 0.001 g/100 ml (20 °C) | ||
| + | | SolubleOther = Reacts with acids<br>Insoluble in organic solvents | ||
| + | | Solvent = | ||
| + | | VaporPressure = ~0 mmHg | ||
| + | }} | ||
| + | | Section3 = {{Chembox Structure | ||
| + | | Coordination = | ||
| + | | CrystalStruct = Trigonal | ||
| + | | MolShape = | ||
| + | }} | ||
| + | | Section4 = {{Chembox Thermochemistry | ||
| + | | DeltaGf = | ||
| + | | DeltaHc = | ||
| + | | DeltaHf = | ||
| + | | Entropy = | ||
| + | | HeatCapacity = | ||
| + | }} | ||
| + | | Section5 = {{Chembox Explosive | ||
| + | | ShockSens = | ||
| + | | FrictionSens = | ||
| + | | DetonationV = | ||
| + | | REFactor = | ||
| + | }} | ||
| + | | Section6 = {{Chembox Hazards | ||
| + | | AutoignitionPt = Non-flammable | ||
| + | | ExploLimits = | ||
| + | | ExternalMSDS = | ||
| + | | FlashPt = Non-flammable | ||
| + | | LD50 = | ||
| + | | LC50 = | ||
| + | | MainHazards = | ||
| + | | NFPA-F = | ||
| + | | NFPA-H = | ||
| + | | NFPA-R = | ||
| + | | NFPA-S = | ||
| + | }} | ||
| + | | Section7 = {{Chembox Related | ||
| + | | OtherAnions = | ||
| + | | OtherCations = | ||
| + | | OtherFunction = | ||
| + | | OtherFunction_label = | ||
| + | | OtherCompounds = [[Calcium carbonate]] | ||
| + | }} | ||
| + | }} | ||
| + | '''Zinc carbonate''' is a white, insoluble, [[zinc]] salt with chemical formula '''[[Zinc|Zn]][[Carbonate|CO<sub>3</sub>]]'''. With it, most simple zinc salts can be made by reaction with the corresponding proportions of sulfate. | ||
Zinc carbonate occurs in nature as the mineral ''Smithsonite'' aka ''zinc spar''. | Zinc carbonate occurs in nature as the mineral ''Smithsonite'' aka ''zinc spar''. | ||
Revision as of 14:22, 4 May 2017
| Names | |
|---|---|
| IUPAC name
Zinc carbonate
| |
| Other names
Smithsonite
Zinc monocarbonate Zinc spar Zincspar | |
| Properties | |
| ZnCO3 | |
| Molar mass | 125.388 g/mol |
| Appearance | White or multicolored (smithsonite) |
| Odor | Odorless |
| Density | 4.398 g/cm3 (20 °C) |
| Melting point | 300 °C (572 °F; 573 K) (decomposes) |
| Boiling point | Decomposes |
| 0.001 g/100 ml (20 °C) | |
| Solubility | Reacts with acids Insoluble in organic solvents |
| Vapor pressure | ~0 mmHg |
| Hazards | |
| Flash point | Non-flammable |
| Related compounds | |
| Related compounds
|
Calcium carbonate |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Zinc carbonate is a white, insoluble, zinc salt with chemical formula ZnCO3. With it, most simple zinc salts can be made by reaction with the corresponding proportions of sulfate.
Zinc carbonate occurs in nature as the mineral Smithsonite aka zinc spar.
Contents
Properties
Chemical properties
Zinc carbonate, like other carbonates, dissolves easily in acidic solution due to its basic nature, but is insoluble in water. This reaction gives off carbon dioxide. It will also dissolve in an excess of strong base to form zincates. Zinc carbonate can be thermally decomposed to form zinc oxide.
Physical
Zinc carbonate is a white compound. The natural variety contains impurities, giving it blue, pink or green coloring. ZnCO3 has a density of 4,398 g/cm3. At high temperatures it will begin to decompose. Zinc carbonate is insoluble in water.
Availability
Zinc carbonate can be purchased from chemical suppliers, such as Chemisphere Limited.
Preparation
Zinc carbonate can be made by reacting zinc sulfate or any other water soluble zinc(II) salt with sodium carbonate or sodium bicarbonate. It can also be made by the reaction of zincates with carbon dioxide. The resulting precipitate can then be filtered and dried, then stored in an environment free of acidic vapors.
Uses
Zinc carbonate can be reacted with acids to form other zinc salts. It can also be used similarly to zinc oxide as a white pigment.
Handling
Safety
Zinc carbonate poses little toxicity to organisms and environment.
Storage
Zinc carbonate should be stored in closed containers, away from any acidic vapors.
Disposal
No special disposal is required. Zinc carbonate can be discarded in soil, as long as it doesn't contain any heavy metals.
