Difference between revisions of "Cyanogen"
(Created page with "{{Chembox | Name = Cyanogen | Reference = | IUPACName = Oxalonitrile | PIN = | SystematicName = | OtherNames = Bis(nitridocarbon)(C—C)<br>Carbon nitride<br>Cyanogen<br>Di...") |
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===Disposal=== | ===Disposal=== | ||
| − | Can be destroyed by bubbling it in an oxidizing solution. Burning it is not recommended as it may release cyanide fumes. | + | Can be destroyed by bubbling it in an oxidizing solution. Burning it is not recommended as it may release hydrogen cyanide fumes. |
==References== | ==References== | ||
Revision as of 16:11, 14 April 2017
| Names | |
|---|---|
| IUPAC name
Oxalonitrile
| |
| Other names
Bis(nitridocarbon)(C—C)
Carbon nitride Cyanogen Dicyan Dicyanogen Ethanedinitrile Nitriloacetonitrile Oxalic acid dinitrile Oxalyl cyanide | |
| Properties | |
| C2N2 (CN)2 | |
| Molar mass | 52.036 g/mol |
| Appearance | Colorless gas |
| Odor | Almond-like |
| Density | 0.002321 g/cm3 (0 °C) |
| Melting point | −28 °C (−18 °F; 245 K) |
| Boiling point | −21.1 °C (−6.0 °F; 252.1 K) |
| 45 g/100 ml (at 20 °C) | |
| Solubility | Soluble in diethyl ether, ethanol |
| Vapor pressure | 5.1 atm (21 °C) |
| Thermochemistry | |
| Std molar
entropy (S |
241.57 J·K−1·mol−1 |
| Std enthalpy of
formation (ΔfH |
309.07 kJ/mol |
| Hazards | |
| Safety data sheet | Matheson |
| Related compounds | |
| Related compounds
|
Hydrogen cyanide |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Cyanogen, also known as dicyanogen or oxalonitrile is a colorless, toxic gas with a pungent almond-like odor. It is a pseudohalogen, with the chemical formula (CN)2.
Contents
Properties
Chemical
Hydrolysis of cyanogen gives oxamide.
Physical
Cyanogen is a colorless gas, with an almond-like odor, highly poisonous. It is soluble in water, but more soluble in alcohols and ethers.
Availability
Cyanogen is sold by industrial gas companies, but due to its extreme dangers, it is not sold to the general public.
Preparation
Cyanogen can be produced by the pyrolysis of oxamide at 350 °C, which in turn can be obtained from the thermal decomposition of ammonium oxalate.
Projects
Due to the extreme toxicity of cyanogen, it's best to work with it only if you have experience working with toxic gaseous compounds. Work in well ventilated chambers or under a fumehood and proper protection equipment, such as cyanide-rated filter mask and gloves must be worn at all times.
- Make oxamide
- Make paracyanogen
- Make the second hottest flame known to man
Handling
Safety
Dicyanogen is metabolized by the organism to cyanide, which is very toxic. Lethal dose through inhalation typically ranges from 100 to 150 mg. Inhalation of 900 ppm over a period of 10 minutes is considered lethal.
Storage
Cyanogen should only be stored in metal gas cylinders, away from light and heat, and preferably in an isolated place. Periodically inspect the tube for any signs of corrosion.
Disposal
Can be destroyed by bubbling it in an oxidizing solution. Burning it is not recommended as it may release hydrogen cyanide fumes.
