Difference between revisions of "Sulfur hexafluoride"

Revision as of 16:30, 1 April 2016

Sulfur hexafluoride, sometimes shorted to SF6, is an inorganic, colorless, odorless, non-flammable heavy gaseous chemical compound with interesting properties. Its chemical formula is SF₆.

Properties

Chemical

Sulfur hexafluoride is almost chemically inert. It will not burn in air, nor will react with other gases. SF6 will not react with molten sodium, but will react with molten lithium metal. When electric current is applied, SF6 will disproportionate to disulfur decafluoride and fluorine gas:

2 SF₆ → S₂F₁₀ + F₂

Physical

Sulfur hexafluoride is a colorless, odorless, inert gas. It is a good electric insulator. Its density of 6.12 g/L at standard conditions is nearly 5 times that of air (1.225 g/L).

Availability

Sulfur hexafluoride can be purchased from several companies, such as Praxair, Concordeair, Airgas, ElectronicFluorocarbons in compressed gas cylinders. In Russia, it is marketed under the name "Elegas" (Элегаз), from "electric insulation" and "gas".

Preparation

Sulfur hexafluoride can be prepared by reacting elemental sulfur with fluorine gas, and then scrubbing the resulting gas in an alkali solution to remove sulfur tetrafluoride. However, because this process requires the highly dangerous elemental fluorine, it's safer to just buy the gas from sellers.

Projects

• Inert gas for casting air-sensitive metals (ex: magnesium)
• Alternative inert gas for storing air-sensitive chemical compounds
• Gaseous dielectric medium
• Magic floating [foil] boat
• Baritone voice

Handling

Safety

Sulfur hexafluoride, while not a noble gas, has similar properties, such as being non-toxic and inert. However it can displace the oxygen in lungs and carries the risk of asphyxia if too much is inhaled. SF6 will react with molten lithium, but not with other common metals, making it safe to use as an inert gas.

Storage

SF6 cylinders should be stored in cold places away from any heat source. It's best to avoid storing it in the basement though, as in case of a leak, it may displace all air from the room, posing slightly greater asphyxiation hazard that CO₂, as it cannot be removed with scrubbers.

Disposal

Sulfur hexafluoride is one of the most potent greenhouse gases, with a global warming potential of 23,900 times that of CO₂. However, given the low amounts of SF6 released compared to other greenhouse gases such as carbon dioxide, its overall contribution to global warming is estimated to be less than 0.2%.

References

Relevant Sciencemadness threads

• Sulfur Hexafluoride source?