Difference between revisions of "Sodium chlorite"
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| + | {{distinguish|sodium chloride}} | ||
{{Chembox | {{Chembox | ||
| Name = Sodium chlorite | | Name = Sodium chlorite | ||
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===Physical=== | ===Physical=== | ||
| − | Sodium chlorite is a solid soluble in water. | + | Sodium chlorite is a colorless solid soluble in water. |
==Availability== | ==Availability== | ||
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Sodium chlorite can be made by reducing [[sodium chlorate]] in a strong acid solution with a suitable reducing agent, like [[sodium sulfite]], [[sulfur dioxide]] or even [[hydrochloric acid]]. This produces [[chlorine dioxide]], which is then absorbed into an alkaline solution and reduced with [[hydrogen peroxide]], yielding sodium chlorite. The final product will always contain 20% sodium chloride. | Sodium chlorite can be made by reducing [[sodium chlorate]] in a strong acid solution with a suitable reducing agent, like [[sodium sulfite]], [[sulfur dioxide]] or even [[hydrochloric acid]]. This produces [[chlorine dioxide]], which is then absorbed into an alkaline solution and reduced with [[hydrogen peroxide]], yielding sodium chlorite. The final product will always contain 20% sodium chloride. | ||
| − | Reaction of [[chlorine]] with [[sodium nitrate]] will yield sodium chlorite and [[nitrosyl chloride]]. | + | Reaction of [[chlorine]] with [[sodium nitrate]] will yield sodium chlorite and [[nitrosyl chloride]].<ref>http://site.iugaza.edu.ps/bqeshta/files/2010/02/94398_16.pdf However this doesn't list any sources for this claim and couldn't be confirmed with other literature. See also https://www.sciencemadness.org/whisper/viewthread.php?tid=18929#pid278332 and http://www.sciencemadness.org/talk/viewthread.php?tid=3314#pid36848</ref> |
| − | : NaNO<sub>3</sub> + Cl<sub>2</sub> → NaClO<sub>2</sub> | + | : NaNO<sub>3</sub> + Cl<sub>2</sub> → NaClO<sub>2</sub> + NOCl |
==Projects== | ==Projects== | ||
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==Handling== | ==Handling== | ||
===Safety=== | ===Safety=== | ||
| − | Sodium chlorite is a strong oxidant and ingestion will cause methemoglobinemia, hemolysis, renal failure. A dose of 10-15 grams of sodium | + | Sodium chlorite is a strong oxidant and ingestion will cause methemoglobinemia, hemolysis, renal failure. A dose of 10-15 grams of sodium chlorite can be lethal. |
===Storage=== | ===Storage=== | ||
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===Relevant Sciencemadness threads=== | ===Relevant Sciencemadness threads=== | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=3314 Preparation of sodium chlorite] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=3314 Preparation of sodium chlorite] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=156885 How to make Sodium chlorite??] | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=18929 Chlorite production] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=18929 Chlorite production] | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=76404 Safe Disposal of Sodium Chlorite] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=76404 Safe Disposal of Sodium Chlorite] | ||
Latest revision as of 22:41, 13 February 2021
Not to be confused with sodium chloride.
| Names | |
|---|---|
| IUPAC name
Sodium chlorite
| |
| Preferred IUPAC name
Sodium chlorite | |
| Systematic IUPAC name
Sodium chlorite | |
| Other names
Chlorous acid, sodium salt
Textone | |
| Properties | |
| NaClO2 | |
| Molar mass | 90.442 g/mol (anhydrous) 144.487 g/mol (trihydrate) |
| Appearance | White solid |
| Odor | Odorless |
| Density | 2.468 g/cm3 |
| Melting point | anhydrous 180–200 °C (356-392 °F; 453-473 K) (decomposes) trihydrate 38 °C (100.4 °F; 311 K) (decomposes) |
| Boiling point | Decomposes |
| 75.8 g/100 ml (25 °C) 122 g/100 ml (60 °C) | |
| Solubility | Reacts with acids Slightly soluble in ethanol, methanol |
| Acidity (pKa) | 10-11 |
| Thermochemistry | |
| Std enthalpy of
formation (ΔfH |
-307.0 kJ/mol |
| Hazards | |
| Safety data sheet | Sigma-Aldrich (80%) |
| Flash point | Non-flammable |
| Lethal dose or concentration (LD, LC): | |
| LD50 (Median dose)
|
350 mg/kg (rat, oral) |
| Related compounds | |
| Related compounds
|
Sodium hypochlorite Sodium chlorate Sodium perchlorate |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Sodium chlorite is an oxidizer used in the manufacturing of paper and as a disinfectant. It has the chemical formula NaClO2.
Contents
Properties
Chemical
Sodium chlorite reacts with acids and elemental chlorine to yield chlorine dioxide.
- 2 NaClO2 + Cl2 → 2 ClO2 + 3 NaCl + H2O
- 5 NaClO2 + 4 HCl → 5 NaCl + 4 ClO2 + 2 H2O
Physical
Sodium chlorite is a colorless solid soluble in water.
Availability
Sodium chlorite is sold by lab suppliers.
Preparation
Sodium chlorite can be made by reducing sodium chlorate in a strong acid solution with a suitable reducing agent, like sodium sulfite, sulfur dioxide or even hydrochloric acid. This produces chlorine dioxide, which is then absorbed into an alkaline solution and reduced with hydrogen peroxide, yielding sodium chlorite. The final product will always contain 20% sodium chloride.
Reaction of chlorine with sodium nitrate will yield sodium chlorite and nitrosyl chloride.[1]
- NaNO3 + Cl2 → NaClO2 + NOCl
Projects
- Make chlorine dioxide
- Pinnick oxidation
- Disinfectant and biocide
Handling
Safety
Sodium chlorite is a strong oxidant and ingestion will cause methemoglobinemia, hemolysis, renal failure. A dose of 10-15 grams of sodium chlorite can be lethal.
Storage
In closed plastic bottles, away from acids and light.
Disposal
Can be neutralized with a reducing agent, like sodium metabisulfite.
References
- ↑ http://site.iugaza.edu.ps/bqeshta/files/2010/02/94398_16.pdf However this doesn't list any sources for this claim and couldn't be confirmed with other literature. See also https://www.sciencemadness.org/whisper/viewthread.php?tid=18929#pid278332 and http://www.sciencemadness.org/talk/viewthread.php?tid=3314#pid36848
