Difference between revisions of "Cobalt(II) sulfate"
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| OtherNames = Cobalt sulphate<br>Cobaltous sulfate<br>Red vitriol | | OtherNames = Cobalt sulphate<br>Cobaltous sulfate<br>Red vitriol | ||
<!-- Images --> | <!-- Images --> | ||
| − | | ImageFile = | + | | ImageFile = Cobalt_sulfate_heptahydrate.jpg |
| − | | ImageSize = | + | | ImageSize = 270px |
| ImageAlt = | | ImageAlt = | ||
| ImageName = | | ImageName = | ||
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| Solvent1 = methanol | | Solvent1 = methanol | ||
| SolubleOther = Slightly soluble in [[ethanol]]<br>Insoluble in [[ammonia]], [[toluene]], [[xylene]] | | SolubleOther = Slightly soluble in [[ethanol]]<br>Insoluble in [[ammonia]], [[toluene]], [[xylene]] | ||
| − | | VaporPressure = | + | | VaporPressure = ~0 mmHg |
}} | }} | ||
| Section3 = {{Chembox Structure | | Section3 = {{Chembox Structure | ||
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| Section6 = {{Chembox Hazards | | Section6 = {{Chembox Hazards | ||
| AutoignitionPt = Non-flammable | | AutoignitionPt = Non-flammable | ||
| − | | ExploLimits = | + | | ExploLimits = Non-explosive |
| ExternalMSDS = [http://www.ch.ntu.edu.tw/~genchem99/msds/exp18/CoSO4.pdf AcrosOrganics] (monohydrate)<br>[http://www.labchem.com/tools/msds/msds/LC13190.pdf LabChem] (hexahydrate)<br>[http://www.ch.ntu.edu.tw/~genchem99/msds/exp18/Cobalt%28II%29%20sulfate%20heptahydrate.pdf FisherSci] (heptahydrate) | | ExternalMSDS = [http://www.ch.ntu.edu.tw/~genchem99/msds/exp18/CoSO4.pdf AcrosOrganics] (monohydrate)<br>[http://www.labchem.com/tools/msds/msds/LC13190.pdf LabChem] (hexahydrate)<br>[http://www.ch.ntu.edu.tw/~genchem99/msds/exp18/Cobalt%28II%29%20sulfate%20heptahydrate.pdf FisherSci] (heptahydrate) | ||
| FlashPt = Non-flammable | | FlashPt = Non-flammable | ||
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}} | }} | ||
}} | }} | ||
| − | '''Cobalt(II) sulfate''' is a red or pink crystalline chemical compound with the chemical formula '''CoSO<sub>4</sub>'''. It is commonly encountered in its hydrated form. | + | '''Cobalt(II) sulfate''' is a red or pink crystalline chemical compound of [[cobalt]] with the chemical formula '''CoSO<sub>4</sub>'''. It is commonly encountered in its hydrated form. |
==Properties== | ==Properties== | ||
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===Physical=== | ===Physical=== | ||
| − | Cobalt(II) sulfate is a red (anhydrous, monohydrate) or pink (hexa-, heptahydrate) crystalline solid, soluble in water, with the hydrated form more soluble in [[methanol]] than the anhydrous one. It also displays moderate solubility in ethanol, but insoluble in non-polar solvents. It decomposes when heated above 735 °C. | + | Cobalt(II) sulfate is a red (anhydrous, monohydrate) or pink (hexa-, heptahydrate) crystalline solid, soluble in water, with the hydrated form more soluble in [[methanol]] than the anhydrous one. It also displays moderate solubility in [[ethanol]], but insoluble in non-polar solvents. It decomposes when heated above 735 °C. |
==Availability== | ==Availability== | ||
Cobalt sulfate is sold by various suppliers and can also be found on eBay. | Cobalt sulfate is sold by various suppliers and can also be found on eBay. | ||
| − | Cobalt(II) sulfate, along with | + | Cobalt(II) sulfate, along with most cobalt compounds, is classified as "Substance of very high concern" in the EU and the sale of this compound is regulated, making it difficult to obtain. |
==Preparation== | ==Preparation== | ||
| Line 129: | Line 129: | ||
*Make pigment | *Make pigment | ||
*Make blue glass | *Make blue glass | ||
| + | *Grow beautiful red crystals | ||
==Handling== | ==Handling== | ||
===Safety=== | ===Safety=== | ||
| − | Cobalt(II) sulfate is harmful and | + | Cobalt(II) sulfate is harmful and research have shown that exposure to this substance increases the risk of developing cancer. |
===Storage=== | ===Storage=== | ||
| − | + | Cobalt(II) sulfate should be kept in closed bottles, away from moisture. The anhydrous form should be stored in sealed containers. | |
===Disposal=== | ===Disposal=== | ||
Latest revision as of 14:00, 23 May 2021
| |
| Names | |
|---|---|
| IUPAC name
Cobalt(II) sulfate
| |
| Other names
Cobalt sulphate
Cobaltous sulfate Red vitriol | |
| Properties | |
| CoSO4 | |
| Molar mass | 154.996 g/mol (anhydrous) 173.01 g/mol (monohydrate) 263.08 g/mol (hexahydrate) 281.103 g/mol (heptahydrate) |
| Appearance | Red solid (anhydrous, monohydrate) Pink solid (hexahydrate) |
| Odor | Odorless |
| Density | 3.71 g/cm3 (anhydrous) 3.075 g/cm3 (monohydrate) 2.019 g/cm3 (hexahydrate) 1.948 g/cm3 (heptahydrate) |
| Melting point | 735 °C (1,355 °F; 1,008 K) (decomposes) |
| Boiling point | Decomposes |
| anhydrous: 36.2 g/100 mL (20 °C) 38.3 g/100 mL (25 °C) 84 g/100 mL (100 °C) heptahydrate: 60.4 g/100 mL (3 °C) 67 g/100 mL (70 °C) | |
| Solubility | Slightly soluble in ethanol Insoluble in ammonia, toluene, xylene |
| Solubility in methanol | anhydrous: 1.04 g/100 mL (18 °C) heptahydrate: 54.5 g/100 mL (18 °C) |
| Vapor pressure | ~0 mmHg |
| Hazards | |
| Safety data sheet | AcrosOrganics (monohydrate) LabChem (hexahydrate) FisherSci (heptahydrate) |
| Flash point | Non-flammable |
| Lethal dose or concentration (LD, LC): | |
| LD50 (Median dose)
|
424 mg/kg (oral, rat) |
| Related compounds | |
| Related compounds
|
Cobalt(II) chloride |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Cobalt(II) sulfate is a red or pink crystalline chemical compound of cobalt with the chemical formula CoSO4. It is commonly encountered in its hydrated form.
Contents
Properties
Chemical
Like many transition metal hydrates, cobalt(II sulfate) hexahydrate is a metal aquo complex consisting of octahedral [Co(H2O)6]2+ ions associated with sulfate anions.
Physical
Cobalt(II) sulfate is a red (anhydrous, monohydrate) or pink (hexa-, heptahydrate) crystalline solid, soluble in water, with the hydrated form more soluble in methanol than the anhydrous one. It also displays moderate solubility in ethanol, but insoluble in non-polar solvents. It decomposes when heated above 735 °C.
Availability
Cobalt sulfate is sold by various suppliers and can also be found on eBay.
Cobalt(II) sulfate, along with most cobalt compounds, is classified as "Substance of very high concern" in the EU and the sale of this compound is regulated, making it difficult to obtain.
Preparation
Cobalt sulfate can be prepared by reacting cobalt metal, or cobalt oxide/hydroxide with aqueous sulfuric acid. Heating the solution to drive off the water will give the hydrated forms of cobalt sulfate. If anhydrous cobalt(II) sulfate is desired, the hydrated crystals must be heated to 250 °C to drive off the water and then left to cool in a desiccator.
Projects
- Make pigment
- Make blue glass
- Grow beautiful red crystals
Handling
Safety
Cobalt(II) sulfate is harmful and research have shown that exposure to this substance increases the risk of developing cancer.
Storage
Cobalt(II) sulfate should be kept in closed bottles, away from moisture. The anhydrous form should be stored in sealed containers.
Disposal
Cobalt sulfate should be taken to special disposal centers.
