Difference between revisions of "Zinc peroxide"
From Sciencemadness Wiki
| (6 intermediate revisions by 2 users not shown) | |||
| Line 1: | Line 1: | ||
| − | + | {{Chembox | |
| − | '''Zinc peroxide''', ZnO<sub>2</sub>, is a unique and chemically interesting compound of [[zinc]]. | + | | Name = Zinc peroxide |
| + | | Reference = | ||
| + | | IUPACName = Zinc peroxide | ||
| + | | PIN = | ||
| + | | SystematicName = | ||
| + | | OtherNames = Zinc dioxide | ||
| + | <!-- Images --> | ||
| + | | ImageFile = ZnO2 by Tdep.png | ||
| + | | ImageSize = 260 | ||
| + | | ImageAlt = | ||
| + | | ImageName = | ||
| + | | ImageCaption = Zinc Peroxide reacts to an open flame | ||
| + | | ImageFile1 = | ||
| + | | ImageSize1 = | ||
| + | | ImageAlt1 = | ||
| + | | ImageName1 = | ||
| + | | ImageFile2 = | ||
| + | | ImageSize2 = | ||
| + | | ImageAlt2 = | ||
| + | | ImageName2 = | ||
| + | | ImageFile3 = | ||
| + | | ImageSize3 = | ||
| + | | ImageAlt3 = | ||
| + | | ImageName3 = | ||
| + | | ImageFileL1 = | ||
| + | | ImageSizeL1 = | ||
| + | | ImageAltL1 = | ||
| + | | ImageNameL1 = | ||
| + | | ImageFileR1 = | ||
| + | | ImageSizeR1 = | ||
| + | | ImageAltR1 = | ||
| + | | ImageNameR1 = | ||
| + | | ImageFileL2 = | ||
| + | | ImageSizeL2 = | ||
| + | | ImageAltL2 = | ||
| + | | ImageNameL2 = | ||
| + | | ImageFileR2 = | ||
| + | | ImageSizeR2 = | ||
| + | | ImageAltR2 = | ||
| + | | ImageNameR2 = | ||
| + | <!-- Sections --> | ||
| + | | Section1 = {{Chembox Identifiers | ||
| + | | 3DMet = | ||
| + | | Abbreviations = | ||
| + | | SMILES = | ||
| + | }} | ||
| + | | Section2 = {{Chembox Properties | ||
| + | | AtmosphericOHRateConstant = | ||
| + | | Appearance = White-yellow solid | ||
| + | | BoilingPt = | ||
| + | | BoilingPtC = | ||
| + | | BoilingPt_ref = | ||
| + | | BoilingPt_notes = (decomposes) | ||
| + | | Density = 1.57 g/cm<sup>3</sup> | ||
| + | | Formula = ZnO<sub>2</sub> | ||
| + | | HenryConstant = | ||
| + | | LogP = | ||
| + | | MolarMass = 97.408 g/mol | ||
| + | | MeltingPt = | ||
| + | | MeltingPtC = 212 | ||
| + | | MeltingPt_ref = | ||
| + | | MeltingPt_notes = (decomposes) | ||
| + | | pKa = ~7 (3% solution) | ||
| + | | pKb = | ||
| + | | Solubility = Insoluble | ||
| + | | SolubleOther = Insoluble in organic solvents | ||
| + | | Solvent = | ||
| + | | VaporPressure = | ||
| + | }} | ||
| + | | Section3 = {{Chembox Structure | ||
| + | | Coordination = | ||
| + | | CrystalStruct = Cubic | ||
| + | | MolShape = | ||
| + | }} | ||
| + | | Section4 = {{Chembox Thermochemistry | ||
| + | | DeltaGf = | ||
| + | | DeltaHc = | ||
| + | | DeltaHf = | ||
| + | | Entropy = | ||
| + | | HeatCapacity = | ||
| + | }} | ||
| + | | Section5 = {{Chembox Explosive | ||
| + | | ShockSens = | ||
| + | | FrictionSens = | ||
| + | | DetonationV = | ||
| + | | REFactor = | ||
| + | }} | ||
| + | | Section6 = {{Chembox Hazards | ||
| + | | AutoignitionPt = | ||
| + | | ExploLimits = | ||
| + | | ExternalMSDS = [https://www.docdroid.net/QTSV6Ru/zinc-peroxide-sa.pdf.html Sigma-Aldrich] | ||
| + | | FlashPt = | ||
| + | | LD50 = | ||
| + | | LC50 = | ||
| + | | MainHazards = Oxidizer | ||
| + | | NFPA-F = | ||
| + | | NFPA-H = | ||
| + | | NFPA-R = | ||
| + | | NFPA-S = | ||
| + | }} | ||
| + | | Section7 = {{Chembox Related | ||
| + | | OtherAnions = | ||
| + | | OtherCations = | ||
| + | | OtherFunction = | ||
| + | | OtherFunction_label = | ||
| + | | OtherCompounds = [[Hydrogen peroxide]] | ||
| + | }} | ||
| + | }} | ||
| + | '''Zinc peroxide''', '''ZnO<sub>2</sub>''', is a unique and chemically interesting compound of [[zinc]]. It is an insoluble zinc salt of [[hydrogen peroxide]]. | ||
==Properties== | ==Properties== | ||
| Line 8: | Line 116: | ||
It was once used as an antiseptic, because it introduces large amounts of [[oxygen]] into the environment of anaerobic bacteria. | It was once used as an antiseptic, because it introduces large amounts of [[oxygen]] into the environment of anaerobic bacteria. | ||
| − | Zinc peroxide will react with diluted acids to release oxygen.<ref>http://ec.europa.eu/health/ph_risk/committees/sccp/documents/out180_en.pdf</ref> It will also slowly decompose in water.<ref>Handbook for Pharmacy Technicians, By United States Department of the Army, p. 285</ref> | + | Zinc peroxide will react with diluted acids to release oxygen.<ref>http://ec.europa.eu/health/ph_risk/committees/sccp/documents/out180_en.pdf</ref> It, as a salt of a very weak acid and a very weak base, will also slowly decompose in water.<ref>Handbook for Pharmacy Technicians, By United States Department of the Army, p. 285</ref> |
===Physical=== | ===Physical=== | ||
| Line 17: | Line 125: | ||
==Production== | ==Production== | ||
| − | Zinc peroxide can be made by reacting concentrated [[hydrogen peroxide]] with [[zinc chloride]]. | + | Zinc peroxide can be made by reacting concentrated [[hydrogen peroxide]] with [[zinc chloride]]. [[Zinc acetate]] can also be used. |
A suspension of zinc oxide in hydrogen peroxide will eventually turn a shade of yellow as ZnO<sub>2</sub> is formed but it does not go to completion in dilute peroxide and separating the two insoluble oxides formed this way is impossible. Some energetic properties can still be observed with this mixture however. | A suspension of zinc oxide in hydrogen peroxide will eventually turn a shade of yellow as ZnO<sub>2</sub> is formed but it does not go to completion in dilute peroxide and separating the two insoluble oxides formed this way is impossible. Some energetic properties can still be observed with this mixture however. | ||
| Line 23: | Line 131: | ||
==Projects== | ==Projects== | ||
*Flash powder | *Flash powder | ||
| + | *Antiseptic | ||
==Handling== | ==Handling== | ||
| Line 40: | Line 149: | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=24626 Zinc peroxide] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=24626 Zinc peroxide] | ||
| − | [[Category: | + | [[Category:Chemical compounds]] |
| − | [[Category:Inorganic | + | [[Category:Inorganic compounds]] |
| + | [[Category:Zinc compounds]] | ||
| + | [[Category:Oxides]] | ||
[[Category:Oxidizing agents]] | [[Category:Oxidizing agents]] | ||
| + | [[Category:Peroxides]] | ||
| + | [[Category:Inorganic peroxides]] | ||
| + | [[Category:Insoluble compounds]] | ||
| + | [[Category:Irritants]] | ||
Latest revision as of 16:07, 6 July 2017
 Zinc Peroxide reacts to an open flame
| |
| Names | |
|---|---|
| IUPAC name
Zinc peroxide
| |
| Other names
Zinc dioxide
| |
| Properties | |
| ZnO2 | |
| Molar mass | 97.408 g/mol |
| Appearance | White-yellow solid |
| Density | 1.57 g/cm3 |
| Melting point | 212 °C (414 °F; 485 K) (decomposes) |
| Boiling point | (decomposes) |
| Insoluble | |
| Solubility | Insoluble in organic solvents |
| Acidity (pKa) | ~7 (3% solution) |
| Hazards | |
| Safety data sheet | Sigma-Aldrich |
| Related compounds | |
| Related compounds
|
Hydrogen peroxide |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Zinc peroxide, ZnO2, is a unique and chemically interesting compound of zinc. It is an insoluble zinc salt of hydrogen peroxide.
Contents
Properties
Chemical
Zinc peroxide is an oxidizer capable of sustaining energetic mixtures.
It was once used as an antiseptic, because it introduces large amounts of oxygen into the environment of anaerobic bacteria.
Zinc peroxide will react with diluted acids to release oxygen.[1] It, as a salt of a very weak acid and a very weak base, will also slowly decompose in water.[2]
Physical
Zinc peroxide is a white to bright yellow solid, insoluble in water. It has a density of 1.57 g/cm3. Zinc peroxide decomposes explosively if heated to 212 °C.[3]
Availability
Zinc peroxide is sold by dentistry suppliers, usually 60% pure.
Production
Zinc peroxide can be made by reacting concentrated hydrogen peroxide with zinc chloride. Zinc acetate can also be used.
A suspension of zinc oxide in hydrogen peroxide will eventually turn a shade of yellow as ZnO2 is formed but it does not go to completion in dilute peroxide and separating the two insoluble oxides formed this way is impossible. Some energetic properties can still be observed with this mixture however.
Projects
- Flash powder
- Antiseptic
Handling
Safety
Zinc peroxide is irritant to eyes, nose and mouth. Proper protection should be worn when handling the compound.[4]
Storage
Zinc peroxide should be stored in closed containers, away from moisture and acidic vapors.
Disposal
Zinc peroxide can be neutralized with acids.
References
- ↑ http://ec.europa.eu/health/ph_risk/committees/sccp/documents/out180_en.pdf
- ↑ Handbook for Pharmacy Technicians, By United States Department of the Army, p. 285
- ↑ http://cameochemicals.noaa.gov/chemical/1724
- ↑ http://www.t3db.ca/system/msds/attachments/000/000/786/original/T3D0737.pdf
