Difference between revisions of "Sulfur hexafluoride"
(→Availability) |
|||
| (One intermediate revision by the same user not shown) | |||
| Line 1: | Line 1: | ||
| − | '''Sulfur hexafluoride''', sometimes shorted to '''SF6''', is an inorganic, colorless, odorless, non-flammable heavy gaseous chemical compound with interesting properties. Its chemical formula is SF<sub>6</sub>. | + | {{Chembox |
| + | | Name = Sulfur hexafluoride | ||
| + | | Reference = | ||
| + | | IUPACName = Sulfur hexafluoride | ||
| + | | PIN = | ||
| + | | SystematicName = Hexafluoro-λ<sup>6</sup>-sulfane | ||
| + | | OtherNames = Elagas<br>Esaflon<br>SonoVue<br>Sulfur(VI) fluoride<br>Sulfuric fluoride | ||
| + | <!-- Images --> | ||
| + | | ImageFile = | ||
| + | | ImageSize = | ||
| + | | ImageAlt = | ||
| + | | ImageName = | ||
| + | | ImageFile1 = | ||
| + | | ImageSize1 = | ||
| + | | ImageAlt1 = | ||
| + | | ImageName1 = | ||
| + | | ImageFile2 = | ||
| + | | ImageSize2 = | ||
| + | | ImageAlt2 = | ||
| + | | ImageName2 = | ||
| + | | ImageFile3 = | ||
| + | | ImageSize3 = | ||
| + | | ImageAlt3 = | ||
| + | | ImageName3 = | ||
| + | | ImageFileL1 = | ||
| + | | ImageSizeL1 = | ||
| + | | ImageAltL1 = | ||
| + | | ImageNameL1 = | ||
| + | | ImageFileR1 = | ||
| + | | ImageSizeR1 = | ||
| + | | ImageAltR1 = | ||
| + | | ImageNameR1 = | ||
| + | | ImageFileL2 = | ||
| + | | ImageSizeL2 = | ||
| + | | ImageAltL2 = | ||
| + | | ImageNameL2 = | ||
| + | | ImageFileR2 = | ||
| + | | ImageSizeR2 = | ||
| + | | ImageAltR2 = | ||
| + | | ImageNameR2 = | ||
| + | <!-- Sections --> | ||
| + | | Section1 = {{Chembox Identifiers | ||
| + | | 3DMet = | ||
| + | | Abbreviations = | ||
| + | | SMILES = | ||
| + | }} | ||
| + | | Section2 = {{Chembox Properties | ||
| + | | AtmosphericOHRateConstant = | ||
| + | | Appearance = Colorless gas | ||
| + | | BoilingPt = | ||
| + | | BoilingPtC = −64 | ||
| + | | BoilingPt_ref = | ||
| + | | BoilingPt_notes = | ||
| + | | Density = 6.17 g/L | ||
| + | | Formula = SF<sub>6</sub> | ||
| + | | HenryConstant = | ||
| + | | LogP = | ||
| + | | MolarMass = 146.06 g/mol | ||
| + | | MeltingPt = | ||
| + | | MeltingPtC = −50.8 | ||
| + | | MeltingPt_ref = | ||
| + | | MeltingPt_notes = | ||
| + | | Odor = Odorless | ||
| + | | pKa = | ||
| + | | pKb = | ||
| + | | Solubility = 0.003% (25 °C) | ||
| + | | SolubleOther = Very soluble in aq. alkali, [[benzene]], [[ethanol]], [[hexane]] | ||
| + | | Solvent = | ||
| + | | VaporPressure = 2.9 MPa (at 21.1 °C) | ||
| + | }} | ||
| + | | Section3 = {{Chembox Structure | ||
| + | | Coordination = Orthogonal hexagonal | ||
| + | | CrystalStruct = Orthorhombic, oP28 | ||
| + | | MolShape = Octahedral | ||
| + | }} | ||
| + | | Section4 = {{Chembox Thermochemistry | ||
| + | | DeltaGf = | ||
| + | | DeltaHc = | ||
| + | | DeltaHf = −1,209 kJ/mol | ||
| + | | Entropy = 292 J·mol<sup>−1</sup>·K<sup>−1</sup> | ||
| + | | HeatCapacity = | ||
| + | }} | ||
| + | | Section5 = {{Chembox Explosive | ||
| + | | ShockSens = Non-explosive | ||
| + | | FrictionSens = Non-explosive | ||
| + | | DetonationV = Non-explosive | ||
| + | | REFactor = Non-explosive | ||
| + | }} | ||
| + | | Section6 = {{Chembox Hazards | ||
| + | | AutoignitionPt = Non-flammable | ||
| + | | ExploLimits = | ||
| + | | ExternalMSDS = [https://www.docdroid.net/Ft3Eli8/sulfur-hexafluoride-sa.pdf.html Sigma-Aldrich] | ||
| + | | FlashPt = Non-flammable | ||
| + | | LD50 = | ||
| + | | LC50 = | ||
| + | | MainHazards = Asphyxiant | ||
| + | | NFPA-F = | ||
| + | | NFPA-H = | ||
| + | | NFPA-R = | ||
| + | | NFPA-S = | ||
| + | }} | ||
| + | | Section7 = {{Chembox Related | ||
| + | | OtherAnions = | ||
| + | | OtherCations = | ||
| + | | OtherFunction = | ||
| + | | OtherFunction_label = | ||
| + | | OtherCompounds = | ||
| + | }} | ||
| + | }} | ||
| + | '''Sulfur hexafluoride''', sometimes shorted to '''SF6''', is an inorganic, colorless, odorless, non-flammable heavy gaseous chemical compound with interesting properties. Its chemical formula is '''SF<sub>6</sub>'''. | ||
==Properties== | ==Properties== | ||
| Line 43: | Line 152: | ||
[[Category:Fluorine compounds]] | [[Category:Fluorine compounds]] | ||
[[Category:Gases]] | [[Category:Gases]] | ||
| + | [[Category:Inert chemicals]] | ||
[[Category:Inert atmospheres]] | [[Category:Inert atmospheres]] | ||
Latest revision as of 17:53, 14 March 2017
| Names | |
|---|---|
| IUPAC name
Sulfur hexafluoride
| |
| Systematic IUPAC name
Hexafluoro-λ6-sulfane | |
| Other names
Elagas
Esaflon SonoVue Sulfur(VI) fluoride Sulfuric fluoride | |
| Properties | |
| SF6 | |
| Molar mass | 146.06 g/mol |
| Appearance | Colorless gas |
| Odor | Odorless |
| Density | 6.17 g/L |
| Melting point | −50.8 °C (−59.4 °F; 222.3 K) |
| Boiling point | −64 °C (−83 °F; 209 K) |
| 0.003% (25 °C) | |
| Solubility | Very soluble in aq. alkali, benzene, ethanol, hexane |
| Vapor pressure | 2.9 MPa (at 21.1 °C) |
| Thermochemistry | |
| Std molar
entropy (S |
292 J·mol−1·K−1 |
| Std enthalpy of
formation (ΔfH |
−1,209 kJ/mol |
| Hazards | |
| Safety data sheet | Sigma-Aldrich |
| Flash point | Non-flammable |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Sulfur hexafluoride, sometimes shorted to SF6, is an inorganic, colorless, odorless, non-flammable heavy gaseous chemical compound with interesting properties. Its chemical formula is SF6.
Contents
Properties
Chemical
Sulfur hexafluoride is almost chemically inert. It will not burn in air, nor will react with other gases. SF6 will not react with molten sodium, but will react with molten lithium metal. When electric current is applied, SF6 will disproportionate to disulfur decafluoride and fluorine gas:
- 2 SF6 → S2F10 + F2
Physical
Sulfur hexafluoride is a colorless, odorless, inert gas. It is a good electric insulator. Its density of 6.12 g/L at standard conditions is nearly 5 times that of air (1.225 g/L).
Availability
Sulfur hexafluoride can be purchased from several companies, such as Praxair, Concordeair, Airgas, ElectronicFluorocarbons in compressed gas cylinders. In Russia, it is marketed under the name "Elegas" (Элегаз), from "electric insulation" and "gas".
Preparation
Sulfur hexafluoride can be prepared by reacting elemental sulfur with fluorine gas, and then scrubbing the resulting gas in an alkali solution to remove sulfur tetrafluoride. However, because this process requires the highly dangerous elemental fluorine, it's safer to just buy the gas from sellers.
Projects
- Inert gas for casting air-sensitive metals (ex: magnesium)
- Alternative inert gas for storing air-sensitive chemical compounds
- Gaseous dielectric medium
- Magic floating [foil] boat
- Baritone voice
Handling
Safety
Sulfur hexafluoride, while not a noble gas, has similar properties, such as being non-toxic and inert. However it can displace the oxygen in lungs and carries the risk of asphyxia if too much is inhaled. SF6 will react with molten lithium, but not with other common metals, making it safe to use as an inert gas.
Storage
SF6 cylinders should be stored in cold places away from any heat source. It's best to avoid storing it in the basement though, as in case of a leak, it may displace all air from the room, posing slightly greater asphyxiation hazard that CO2, as it cannot be removed with scrubbers.
Disposal
Sulfur hexafluoride is one of the most potent greenhouse gases, with a global warming potential of 23,900 times that of CO2. However, given the low amounts of SF6 released compared to other greenhouse gases such as carbon dioxide, its overall contribution to global warming is estimated to be less than 0.2%.
