Difference between revisions of "Erbium"
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+ | {{Infobox element | ||
+ | <!-- top --> | ||
+ | |image name= | ||
+ | |image alt= | ||
+ | |image size= | ||
+ | |image name comment= | ||
+ | |image name 2= | ||
+ | |image alt 2= | ||
+ | |image size 2= | ||
+ | |image name 2 comment= | ||
+ | <!-- General properties --> | ||
+ | |name=Erbium | ||
+ | |symbol=Er | ||
+ | |pronounce= | ||
+ | |pronounce ref= | ||
+ | |pronounce comment= | ||
+ | |pronounce 2= | ||
+ | |alt name= | ||
+ | |alt names= | ||
+ | |allotropes= | ||
+ | |appearance=Silvery-white | ||
+ | <!-- Periodic table --> | ||
+ | |above= | ||
+ | |below=Fm | ||
+ | |left=[[Holmium]] | ||
+ | |right=[[Thullium]] | ||
+ | |number= | ||
+ | |atomic mass=167.259(3) | ||
+ | |atomic mass 2= | ||
+ | |atomic mass ref= | ||
+ | |atomic mass comment= | ||
+ | |series= | ||
+ | |series ref= | ||
+ | |series comment= | ||
+ | |series color= | ||
+ | |group= | ||
+ | |group ref= | ||
+ | |group comment= | ||
+ | |period=6 | ||
+ | |period ref= | ||
+ | |period comment= | ||
+ | |block=f | ||
+ | |block ref= | ||
+ | |block comment= | ||
+ | |electron configuration=[Xe] 4f<sup>12</sup> 6s<sup>2</sup> | ||
+ | |electron configuration ref= | ||
+ | |electron configuration comment= | ||
+ | |electrons per shell=2, 8, 18, 30, 8, 2 | ||
+ | |electrons per shell ref= | ||
+ | |electrons per shell comment= | ||
+ | <!-- Physical properties --> | ||
+ | |physical properties comment= | ||
+ | |color=Silvery-white | ||
+ | |phase=Solid | ||
+ | |phase ref= | ||
+ | |phase comment= | ||
+ | |melting point K=1802 | ||
+ | |melting point C=1529 | ||
+ | |melting point F=2784 | ||
+ | |melting point ref= | ||
+ | |melting point comment= | ||
+ | |boiling point K=3141 | ||
+ | |boiling point C=2868 | ||
+ | |boiling point F=5194 | ||
+ | |boiling point ref= | ||
+ | |boiling point comment= | ||
+ | |sublimation point K= | ||
+ | |sublimation point C= | ||
+ | |sublimation point F= | ||
+ | |sublimation point ref= | ||
+ | |sublimation point comment= | ||
+ | |density gplstp= | ||
+ | |density gplstp ref= | ||
+ | |density gplstp comment= | ||
+ | |density gpcm3nrt=9.066 | ||
+ | |density gpcm3nrt ref= | ||
+ | |density gpcm3nrt comment= | ||
+ | |density gpcm3nrt 2= | ||
+ | |density gpcm3nrt 2 ref= | ||
+ | |density gpcm3nrt 2 comment= | ||
+ | |density gpcm3nrt 3= | ||
+ | |density gpcm3nrt 3 ref= | ||
+ | |density gpcm3nrt 3 comment= | ||
+ | |density gpcm3mp=8.86 | ||
+ | |density gpcm3mp ref= | ||
+ | |density gpcm3mp comment= | ||
+ | |density gpcm3bp= | ||
+ | |density gpcm3bp ref= | ||
+ | |density gpcm3bp comment= | ||
+ | |molar volume= | ||
+ | |molar volume unit = | ||
+ | |molar volume ref= | ||
+ | |molar volume comment= | ||
+ | |triple point K= | ||
+ | |triple point kPa= | ||
+ | |triple point ref= | ||
+ | |triple point comment= | ||
+ | |triple point K 2= | ||
+ | |triple point kPa 2= | ||
+ | |triple point 2 ref= | ||
+ | |triple point 2 comment= | ||
+ | |critical point K= | ||
+ | |critical point MPa= | ||
+ | |critical point ref= | ||
+ | |critical point comment= | ||
+ | |heat fusion=19.90 | ||
+ | |heat fusion ref= | ||
+ | |heat fusion comment= | ||
+ | |heat fusion 2= | ||
+ | |heat fusion 2 ref= | ||
+ | |heat fusion 2 comment= | ||
+ | |heat vaporization=280 | ||
+ | |heat vaporization ref= | ||
+ | |heat vaporization comment= | ||
+ | |heat capacity=28.12 | ||
+ | |heat capacity ref= | ||
+ | |heat capacity comment= | ||
+ | |heat capacity 2= | ||
+ | |heat capacity 2 ref= | ||
+ | |heat capacity 2 comment= | ||
+ | |vapor pressure 1=1504 | ||
+ | |vapor pressure 10=1663 | ||
+ | |vapor pressure 100=(1885) | ||
+ | |vapor pressure 1 k=(2163) | ||
+ | |vapor pressure 10 k=(2552) | ||
+ | |vapor pressure 100 k=(3132) | ||
+ | |vapor pressure ref= | ||
+ | |vapor pressure comment= | ||
+ | |vapor pressure 1 2= | ||
+ | |vapor pressure 10 2= | ||
+ | |vapor pressure 100 2= | ||
+ | |vapor pressure 1 k 2= | ||
+ | |vapor pressure 10 k 2= | ||
+ | |vapor pressure 100 k 2= | ||
+ | |vapor pressure 2 ref= | ||
+ | |vapor pressure 2 comment= | ||
+ | <!-- Atomic properties --> | ||
+ | |atomic properties comment= | ||
+ | |oxidation states='''3''', 2, 1 | ||
+ | |oxidation states ref= | ||
+ | |oxidation states comment=(a basic oxide) | ||
+ | |electronegativity=1.24 | ||
+ | |electronegativity ref= | ||
+ | |electronegativity comment= | ||
+ | |ionization energy 1=589.3 | ||
+ | |ionization energy 1 ref= | ||
+ | |ionization energy 1 comment= | ||
+ | |ionization energy 2=1150 | ||
+ | |ionization energy 2 ref= | ||
+ | |ionization energy 2 comment= | ||
+ | |ionization energy 3=2194 | ||
+ | |ionization energy 3 ref= | ||
+ | |ionization energy 3 comment= | ||
+ | |number of ionization energies= | ||
+ | |ionization energy ref= | ||
+ | |ionization energy comment= | ||
+ | |atomic radius=176 | ||
+ | |atomic radius ref= | ||
+ | |atomic radius comment= | ||
+ | |atomic radius calculated= | ||
+ | |atomic radius calculated ref= | ||
+ | |atomic radius calculated comment= | ||
+ | |covalent radius=189±6 | ||
+ | |covalent radius ref= | ||
+ | |covalent radius comment= | ||
+ | |Van der Waals radius= | ||
+ | |Van der Waals radius ref= | ||
+ | |Van der Waals radius comment= | ||
+ | <!-- Miscellanea --> | ||
+ | |crystal structure= | ||
+ | |crystal structure prefix= | ||
+ | |crystal structure ref= | ||
+ | |crystal structure comment= Hexagonal close-packed (hcp) | ||
+ | |crystal structure 2= | ||
+ | |crystal structure 2 prefix= | ||
+ | |crystal structure 2 ref= | ||
+ | |crystal structure 2 comment= | ||
+ | |speed of sound= | ||
+ | |speed of sound ref= | ||
+ | |speed of sound comment= | ||
+ | |speed of sound rod at 20=2830 | ||
+ | |speed of sound rod at 20 ref= | ||
+ | |speed of sound rod at 20 comment= | ||
+ | |speed of sound rod at r.t.= | ||
+ | |speed of sound rod at r.t. ref= | ||
+ | |speed of sound rod at r.t. comment= | ||
+ | |thermal expansion=12.2 | ||
+ | |thermal expansion ref= | ||
+ | |thermal expansion comment=(poly) | ||
+ | |thermal expansion at 25= | ||
+ | |thermal expansion at 25 ref= | ||
+ | |thermal expansion at 25 comment= | ||
+ | |thermal conductivity=14.5 | ||
+ | |thermal conductivity ref= | ||
+ | |thermal conductivity comment= | ||
+ | |thermal conductivity 2= | ||
+ | |thermal conductivity 2 ref= | ||
+ | |thermal conductivity 2 comment= | ||
+ | |thermal diffusivity= | ||
+ | |thermal diffusivity ref= | ||
+ | |thermal diffusivity comment= | ||
+ | |electrical resistivity=0.86·10<sup>-6</sup> | ||
+ | |electrical resistivity unit prefix= | ||
+ | |electrical resistivity ref= | ||
+ | |electrical resistivity comment= | ||
+ | |electrical resistivity at 0= | ||
+ | |electrical resistivity at 0 ref= | ||
+ | |electrical resistivity at 0 comment= | ||
+ | |electrical resistivity at 20= | ||
+ | |electrical resistivity at 20 ref= | ||
+ | |electrical resistivity at 20 comment= | ||
+ | |band gap= | ||
+ | |band gap ref= | ||
+ | |band gap comment= | ||
+ | |Curie point K= | ||
+ | |Curie point ref= | ||
+ | |Curie point comment= | ||
+ | |magnetic ordering=Paramagnetic | ||
+ | |magnetic ordering ref= | ||
+ | |magnetic ordering comment= | ||
+ | |tensile strength= | ||
+ | |tensile strength ref= | ||
+ | |tensile strength comment= | ||
+ | |Young's modulus=69.9 | ||
+ | |Young's modulus ref= | ||
+ | |Young's modulus comment= | ||
+ | |Shear modulus=28.3 | ||
+ | |Shear modulus ref= | ||
+ | |Shear modulus comment= | ||
+ | |Bulk modulus=44.4 | ||
+ | |Bulk modulus ref= | ||
+ | |Bulk modulus comment= | ||
+ | |Poisson ratio=0.237 | ||
+ | |Poisson ratio ref= | ||
+ | |Poisson ratio comment= | ||
+ | |Mohs hardness= | ||
+ | |Mohs hardness ref= | ||
+ | |Mohs hardness comment= | ||
+ | |Mohs hardness 2= | ||
+ | |Mohs hardness 2 ref= | ||
+ | |Mohs hardness 2 comment= | ||
+ | |Vickers hardness=430–700 | ||
+ | |Vickers hardness ref= | ||
+ | |Vickers hardness comment= | ||
+ | |Brinell hardness=600–1070 | ||
+ | |Brinell hardness ref= | ||
+ | |Brinell hardness comment= | ||
+ | |CAS number=7440-52-0 | ||
+ | |CAS number ref= | ||
+ | |CAS number comment= | ||
+ | <!-- History --> | ||
+ | |naming=After Ytterby (Sweden), where it was mined | ||
+ | |predicted by= | ||
+ | |prediction date ref= | ||
+ | |prediction date= | ||
+ | |discovered by= Carl Gustaf Mosander | ||
+ | |discovery date ref= | ||
+ | |discovery date=1842 | ||
+ | |first isolation by= | ||
+ | |first isolation date ref= | ||
+ | |first isolation date= | ||
+ | |discovery and first isolation by= | ||
+ | |named by= | ||
+ | |named date ref= | ||
+ | |named date= | ||
+ | |history comment label= | ||
+ | |history comment= | ||
+ | <!-- Isotopes --> | ||
+ | |isotopes= | ||
+ | |isotopes comment= | ||
+ | |engvar= | ||
+ | }} | ||
'''Erbium''' is a chemical element in the lanthanide series, with symbol '''Er''' and atomic number 68. | '''Erbium''' is a chemical element in the lanthanide series, with symbol '''Er''' and atomic number 68. | ||
Revision as of 21:21, 14 October 2017
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|
General properties | |||||
---|---|---|---|---|---|
Name, symbol | Erbium, Er | ||||
Appearance | Silvery-white | ||||
Erbium in the periodic table | |||||
| |||||
Standard atomic weight (Ar) | 167.259(3) | ||||
Group, block | , f-block | ||||
Period | period 6 | ||||
Electron configuration | [Xe] 4f12 6s2 | ||||
per shell | 2, 8, 18, 30, 8, 2 | ||||
Physical properties | |||||
Silvery-white | |||||
Phase | Solid | ||||
Melting point | 1802 K (1529 °C, 2784 °F) | ||||
Boiling point | 3141 K (2868 °C, 5194 °F) | ||||
Density near r.t. | 9.066 g/cm3 | ||||
when liquid, at | 8.86 g/cm3 | ||||
Heat of fusion | 19.90 kJ/mol | ||||
Heat of | 280 kJ/mol | ||||
Molar heat capacity | 28.12 J/(mol·K) | ||||
pressure | |||||
Atomic properties | |||||
Oxidation states | 3, 2, 1 (a basic oxide) | ||||
Electronegativity | Pauling scale: 1.24 | ||||
energies |
1st: 589.3 kJ/mol 2nd: 1150 kJ/mol 3rd: 2194 kJ/mol | ||||
Atomic radius | empirical: 176 pm | ||||
Covalent radius | 189±6 pm | ||||
Miscellanea | |||||
Crystal structure | Hexagonal close-packed (hcp) | ||||
Speed of sound thin rod | 2830 m/s (at 20 °C) | ||||
Thermal expansion | 12.2 µm/(m·K) (poly) | ||||
Thermal conductivity | 14.5 W/(m·K) | ||||
Electrical resistivity | 0.86·10-6 Ω·m | ||||
Magnetic ordering | Paramagnetic | ||||
Young's modulus | 69.9 GPa | ||||
Shear modulus | 28.3 GPa | ||||
Bulk modulus | 44.4 GPa | ||||
Poisson ratio | 0.237 | ||||
Vickers hardness | 430–700 MPa | ||||
Brinell hardness | 600–1070 MPa | ||||
CAS Registry Number | 7440-52-0 | ||||
History | |||||
Naming | After Ytterby (Sweden), where it was mined | ||||
Discovery | Carl Gustaf Mosander (1842) | ||||
Erbium is a chemical element in the lanthanide series, with symbol Er and atomic number 68.
Contents
Properties
Chemical
Erbium metal tarnishes slowly in air and burns readily to form erbium(III) oxide:
- 4 Er + 3 O2 → 2 Er2O3
Erbium will slowly react with cold water, but the reaction occurs much faster in hot water.
Physical
Erbium is a silvery-white malleable metal. It is stable in air, and does not oxidize as quickly as some other rare-earth metals. Erbium is ferromagnetic below 19 K, antiferromagnetic between 19 and 80 K and paramagnetic above 80 K.
Availability
Erbium can be purchased online. Metallium sells erbium coins.
Preparation
Erbium can be prepared by reducing its oxide or salts with calcium at 1450 °C under argon atmosphere.
- Er2O3 + 3 Ca → 2 Er + 3 CaO
Projects
- Erbium chloride
- Erbium glass
Handling
Safety
Erbium's toxicity is similar to that of other lanthanides.
Storage
In closed bottles, away from moisture and corrosives vapors.
Disposal
Best to try to recycle it.