Difference between revisions of "Urea nitrate"
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Urea nitrate can be prepared by reacting urea with nitric acid. The reaction is exothermic, so it's best to do it at low temperatures. | Urea nitrate can be prepared by reacting urea with nitric acid. The reaction is exothermic, so it's best to do it at low temperatures. | ||
| − | Urea nitrate can be prepared via a [[double replacement]] by combining urea with a nitrate salt and concentrated hydrochloric acid in water. | + | Urea nitrate can be prepared via a [[double replacement]] by combining urea with a nitrate salt and concentrated hydrochloric acid in water. Gentle heat, as from a water bath, should be added to bring the urea and nitrate into solution before the HCl is added. The turbid solution clears as the HCl is added and a copious precipitate of urea nitrate is obtained when the solution is cooled below 0 Celsius. The remaining solution contains a small amount of product and the chloride salt of the cation whose nitrate was used.<ref>[http://www.angelfire.com/empire/megapyro6/Pyro/UN.html Making Urea Nitrate without Nitric Acid]</ref> |
==Projects== | ==Projects== | ||
| − | *Make blasting | + | *Make blasting charges |
| − | *Prepare Urea | + | *Prepare Urea nitrate from assorted nitrates, recovering the chloride in each case. |
==Handling== | ==Handling== | ||
===Safety=== | ===Safety=== | ||
| − | Urea | + | Urea nitrate appears to be a flame retardant. Filter paper soaked in it and dried will char in a butane lighter flame but not catch fire. |
===Storage=== | ===Storage=== | ||
| − | Storage should be limited to very small amounts, as larger amounts may invite visits by ''Les Gendarmes | + | Storage should be limited to very small amounts, as larger amounts may invite visits by ''Les Gendarmes''. |
===Disposal=== | ===Disposal=== | ||
| Line 144: | Line 144: | ||
==References== | ==References== | ||
| − | + | <references/> | |
===Relevant Sciencemadness threads=== | ===Relevant Sciencemadness threads=== | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=13470 Synthesizing UN with calcium nitrate] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=13470 Synthesizing UN with calcium nitrate] | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=10362 Urea Nitrate Procedure Mechanism] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=10362 Urea Nitrate Procedure Mechanism] | ||
| + | |||
[[Category:Chemical compounds]] | [[Category:Chemical compounds]] | ||
[[Category:Organic compounds]] | [[Category:Organic compounds]] | ||
Revision as of 17:13, 15 February 2016
| Properties | |
|---|---|
| CH5N3O4 | |
| Molar mass | 123.068 g/mol |
| Density | 1.69 g/cm3 |
| Melting point | 163 °C (325 °F; 436 K) |
| 15 g/100 ml | |
| Solubility | Soluble in ethanol |
| Hazards | |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Urea nitrate is the nitrate salt of the organic base urea. It is an explosive material used in various applications, but it has gained a bad reputation due to its use in many terrorists plots, such as the World Trade Center bombing in 1993.
Contents
Properties
Chemical
Urea nitrate is unstable in basic solution. It also hydrolyzes in solution, which is quite acidic (urea being a very weak base); hot water causes the hydrolysis to proceed more fully, and nitric acid can be distilled back from the solution if heated enough.
Physical
Urea nitrate is a white solid, sparingly soluble in water (less so than urea itself). Its solubility in cold water is significantly less than in warm water.
Availability
Due to being an explosive material, the sale of urea nitrate is restricted.
Preparation
Urea nitrate can be prepared by reacting urea with nitric acid. The reaction is exothermic, so it's best to do it at low temperatures.
Urea nitrate can be prepared via a double replacement by combining urea with a nitrate salt and concentrated hydrochloric acid in water. Gentle heat, as from a water bath, should be added to bring the urea and nitrate into solution before the HCl is added. The turbid solution clears as the HCl is added and a copious precipitate of urea nitrate is obtained when the solution is cooled below 0 Celsius. The remaining solution contains a small amount of product and the chloride salt of the cation whose nitrate was used.[1]
Projects
- Make blasting charges
- Prepare Urea nitrate from assorted nitrates, recovering the chloride in each case.
Handling
Safety
Urea nitrate appears to be a flame retardant. Filter paper soaked in it and dried will char in a butane lighter flame but not catch fire.
Storage
Storage should be limited to very small amounts, as larger amounts may invite visits by Les Gendarmes.
Disposal
Casual tests are planned to evaluate using Urea Nitrate as a house plant food.
