Difference between revisions of "Lithium"

Latest revision as of 18:05, 23 November 2022

Lithium,  ₃Li

Lithium metal from an Energizer battery
General properties
Name, symbol	Lithium, Li
Appearance	White-silvery metal
Lithium in the periodic table
H ↑ Li ↓ Na Helium ← Lithium → Beryllium
Atomic number	3
Standard atomic weight (Ar)	6.94
Group, block	I; s-block
Period	period 2
Electron configuration	[He] 2s1
per shell	2, 1
Physical properties
Silvery-white
Phase	Solid
Melting point	453.65 K ​(180.5 °C, ​356.9 °F)
Boiling point	1603 K ​(1330 °C, ​2426 °F)
Density near r.t.	0.534 g/cm3
when liquid, at	0.512 g/cm3
Critical point	3220 K, 67 MPa(extrapolated)
Heat of fusion	3.00 kJ/mol
Heat of	136 kJ/mol
Molar heat capacity	24.86 J/(mol·K)
pressure
Atomic properties
Oxidation states	+1 ​(a strongly basic oxide)
Electronegativity	Pauling scale: 0.98
energies	1st: 520.2 kJ/mol 2nd: 7298.1 kJ/mol 3rd: 11815 kJ/mol
Atomic radius	empirical: 152 pm
Covalent radius	128±7 pm
Van der Waals radius	182 pm
Miscellanea
Crystal structure	​
Speed of sound thin rod	6000 m/s (at 20 °C)
Thermal expansion	46 µm/(m·K) (at 25 °C)
Thermal conductivity	84.8 W/(m·K)
Electrical resistivity	9.28·10-8 Ω·m
Magnetic ordering	Paramagnetic
Young's modulus	4.9 GPa
Shear modulus	4.2 GPa
Bulk modulus	11 GPa
Mohs hardness	0.6
Brinell hardness	5 MPa
CAS Registry Number	7439-93-2
History
Discovery	Johan August Arfwedson (1817)
First isolation	William Thomas Brande (1821)
view talk edit · references

Lithium is a an alkali metal, the lightest metal and least dense solid element at room temperature, with the atomic number 3 and symbol Li. It is soft, silvery-white metal, with a density of 534 kg/m³. It is highly reactive, and it is usually stored in [[[mineral oil]]. However, because of its extremely low density, it floats in mineral oil, storing the metal proves to be difficult.

Properties

Chemical

Lithium, like all the alkali metals reacts violently with water, releasing hydrogen and can ignite, but this reaction is slightly less violent than the other alkali metals.

Li + H₂O → LiOH + ½ H₂

In open air, it quickly forms a layer of oxide as well as nitride, and if the air also contains water vapors and carbon dioxide, lithium hydroxide and lithium carbonate.

4 Li + O₂ → 2 Li₂O

6 Li + 2 N₂ → 2 Li₃N₂

Lithium will burn in air, and it tends to burn with a red-crimson flame. As noted by NurdRage in his video where he extracted lithium from an energizer battery, this flame is incredibly bright, so welding goggles should be used if this reaction is attempted. Such fires are difficult to extinguish, requiring dry powder extinguishers (class D).

Lithium is also a strong reducing agent. It is also used in organometallic synthesis in the form of organolithium compounds such as n-butyllithium and tert-butyllithium, although they are extremely rarely used by the amateur chemist, mainly because they're very dangerous (pyrophoric and caustic). Molten lithium is probably the most powerful reducing agent known, and will explode on contact with almost anything non-metallic, including wood, glass and concrete. It is the only alkali metal that cannot be safely melted in a glass container, as it reacts exothermically with glass almost immediately.^[1]

Contrary to popular belief, lithium, not cesium, is the most reactive element on the periodic table. It has the lowest reduction potential in aqueous solution, and gram-for-gram (as well as mole-for-mole) has a higher energy content than cesium.

Lithium metal can dissolve in anhydrous ammonia and ethylenediamine, forming its electride salt.

Physical

Lithium is a soft, silver-white metal. It is soft enough to be cut with a knife.

Lithium has the highest specific heat capacity of any solid element, 3.58 kJ/(kg·K), the highest of all solids. Because of this, lithium metal is often used in coolants for heat transfer applications.^[2]

Lithium has a density of only 534 kg/m³, making it the lightest metal and solid element at standard conditions. It is lighter than any hydrocarbon oil, which causes the metal to float in the oil is stored. The only organic hydrocarbons lighter than lithium are liquid methane (465 kg/m³), liquid propane (493.5 kg/m³), liquid propylene (514.4 kg/m³).^[3] Since these solvents are liquid only at very low temperatures or under high pressure, storing lithium in them is impractical.

In addition, lithium has the highest melting point of all alkali metals, at roughly 180 degrees Celsius. This makes it difficult to melt it under oil (a common tactic for removing tarnish from the other alkali metals). Molten lithium is extremely reactive and will react with almost all ceramic materials, therefore lithium is only melted in crucibles made of special metals, such as molybdenum. It also has a high boiling point, of 1330 °C.

Lithium dissolves in liquid ammonia.^[4]

Availability

Lithium can be extracted from lithium batteries, as shown by NurdRage is his video. It comes as a long sheet of lithium metal, that quickly tarnishes in air. It's risky, as the battery can short and overheat. One safer method is to use a pipe cutter and split the battery case in the middle. Larger quantities of lithium can be bought from Galliumsource, though it's pretty expensive (150$/100g). Due to its low molar mass, one may get away with using much smaller amounts of lithium than expected.

In recent years, some jurisdictions in United States limit the sale of lithium batteries, as elemental lithium can be used to reduce pseudoephedrine and ephedrine to the illegal drug methamphetamine.

Preparation

Industrially, elemental lithium is produced electrolytically from a mixture of fused 55% lithium chloride and 45% potassium chloride at about 450 ^oC.^[5]

As molten lithium is highly reactive, this process should be performed in installations made of corrosion resistant alloys and under inert atmosphere, such as argon.

Projects

• Butyllithium synthesis (pyrophoric)
• Isolation of reactive metals, including lanthanides
• Lithium lubricating grease
• Aluminium-lithium alloys
• Cesium synthesis by distillation (DANGER!)

Safety

Handling

Contrary to what one may think, NEVER HANDLE LITHIUM WITH GLOVES OF ANY KIND! You can easily tell if your hands are wet, but not if your gloves are wet, and if you get lithium wet (or it ignites) while handling it with gloves, it will burn through your gloves (and potentially explode) faster than you can remove them.^[6] Pliers are another safe option. Glove boxes are also very good for work with lithium.

Toxicity

Breathing lithium dust or lithium compounds irritate the nose and throat, while higher exposure can cause a buildup of fluid in the lungs, leading to pulmonary edema. Acetic acid a good neutralizing agent.

Storage

Like every other alkali metal, it must be kept away from any fire source. Keeping lithium under mineral oil is difficult because lithium floats on mineral oil, though a small rock may be used to keep it down. The best solution is to keep it in an inert argon atmosphere (nitrogen will react to form lithium nitride). Sulfur hexafluoride can also be used, except when it's molten (it will react).

Disposal

Lithium compounds are not particularly dangerous to the environment, but it's recommended to recycle them when possible.

References

1. ↑ https://www.youtube.com/watch?v=GE-NkVqUiHs
2. ↑ http://hilltop.bradley.edu/~spost/THERMO/solidcp.pdf
3. ↑ http://www.engineeringtoolbox.com/liquids-densities-d_743.html
4. ↑ http://pubs.acs.org/doi/abs/10.1021/j150343a013
5. ↑ https://www.youtube.com/watch?v=cIII542y0C8
6. ↑ Thunderf00t knows what he's talking about. https://www.youtube.com/watch?v=Nn3M1hfjxMU

Relevant Sciencemadness threads

• What are some interesting uses for lithium metal
• Lithium electride in ethylenediamine
• Making Lithium Powder