CD-ROM-LAUFWERK
Harmless
Posts: 30
Registered: 23-4-2005
Member Is Offline
Mood: No Mood
|
|
Pyridineperchlorate
what about pyridineperchlorate?
in the urbanski II 2.3.8 they type a few lines about it, but nothing obout its explosive power, its stability or the preperation
someone has this informations or did any tests?
|
|
chemoleo
Biochemicus Energeticus
Posts: 3005
Registered: 23-7-2003
Location: England Germany
Member Is Offline
Mood: crystalline
|
|
I remember reading somewhere ( I thought Federoff) that it has greater power than TNT, which is surprising considering it's bad OB.
As to preparation- well that should be straightforward, with dilute HClO4.
Stability should be fairly high, I'd doubt it has primary characteristics. Hygroscopic possibly.
Never Stop to Begin, and Never Begin to Stop...
Tolerance is good. But not with the intolerant! (Wilhelm Busch)
|
|
BromicAcid
International Hazard
Posts: 3245
Registered: 13-7-2003
Location: Wisconsin
Member Is Offline
Mood: Rock n' Roll
|
|
I also remember something about a complex of silver perchlorate with pyridine being refered to as pyridine perchlorate complex, might run across
simlilar information in your quest for more knowledge on the salt of pyridine and perchloric acid. I know there is also a benzene complex made from
silver perchlorate and benzene that posesses some explosive characteristics. But like Chemoleo said, the preparation of pyridine perchlorate should
be pretty straight foreward, expecially considering the strength of perchloric acid.
|
|
Axt
National Hazard
Posts: 794
Registered: 28-1-2003
Member Is Offline
Mood: No Mood
|
|
It is listed in PATR2700, lead block 95% TNT and about as sensitive as PETN. Low solubility in ethanol so form water solution and precipitate with
ethanol.
This is in contrast to some of the better perchlorates (ethylenediamine/phenylenediamine) which tend to be soluble in everything and hygroscopic so a
pain to extract and dry.
|
|
franklyn
International Hazard
Posts: 3026
Registered: 30-5-2006
Location: Da Big Apple
Member Is Offline
Mood: No Mood
|
|
A Pyridine adduct of Nitroform C5H5N • HC(NO2)3 => 6 CO + 2 N2 + 3 H2
should perform better than TNT , possibly even better than Trinitroaniline
C6H2(NH2)(NO2)3 => 6 CO + 2 N2 + 2 H2
.
|
|
The WiZard is In
International Hazard
Posts: 1617
Registered: 3-4-2010
Member Is Offline
Mood: No Mood
|
|
This from Schumacher.
To stop those who complain that
my post are toooo long and that I Boo-hoo-ho supply
too much information. I am not going to supply the
references, well .... except —
[51] BP 163 946 1920
[52] BP 168 333 1921
[55] BP 155 627 1917
Sorry too keep this short I cannot post any others.
|
|
symboom
International Hazard
Posts: 1143
Registered: 11-11-2010
Location: Wrongplanet
Member Is Offline
Mood: Doing science while it is still legal since 2010
|
|
pyridine perchlorate I would like to add this link to a video on this compound
pyridine perchlorate
https://youtu.be/AEi1nuM2lxc
|
|