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Author: Subject: Inside a spent laptop battery
Amos
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[*] posted on 22-4-2014 at 09:33
Inside a spent laptop battery


I recently acquired an old, and presumably broken (it was in the trash) Macbook Pro Lithium Ion battery. Being the curious fool that I am, I carefully opened it up to reveal 6 tightly wrapped cells. Upon opening one of the cells I found it was made of a 4 foot long ribbon of what appears to be aluminum foil coated in a dry black residue. Now according to an outside source, the reaction inside a battery of this type are as follows:

LiCoO2 + C ---> Li1-x CoO2+CLix

But seeing as this battery is permanently dead, I was lead to believe the reaction was messed up, possibly leading to the formation of any of the following: Li2O, CoO, and CoO2.

My question for anyone that is more tech/electrochemisty-savvy than me, is whether there are some reactions I can carry out to produce lithium and/or cobalt salts of even a limited purity. As an endnote, I've already immersed some of the ribbon from the battery in water and tried setting it on fire; neither of them caused any kind of reaction, so it is doubtful that any elemental lithium is present.

[Edited on 22-4-2014 by No Tears Only Dreams Now]
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elementcollector1
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[*] posted on 22-4-2014 at 09:38


If water resulted in no reaction, Li2O can't be present either, so it is likely to be present as LiCoO2 or either of the products. Not knowing the chemistry of such a curious double salt, I would recommend dissolving in some acid and then adding some base... This might precipitate Co(OH)2.



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Brain&Force
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[*] posted on 23-4-2014 at 15:06


I highly doubt cobalt dioxide could exist for long. Laptop batteries don't contain lithium metal, either - the technology is different from the Energizer Lithium batteries. I don't know much about lithium-ion or lithium-polymer batteries.



At the end of the day, simulating atoms doesn't beat working with the real things...
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Zyklon-A
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[*] posted on 24-4-2014 at 08:12


Yeah, lithium metal batteries are not rechargeable, only lithium ion batteries are.



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