Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: what is this stuff?
condennnsa
Hazard to Others
***




Posts: 217
Registered: 20-4-2010
Location: Romania
Member Is Offline

Mood: No Mood

[*] posted on 25-1-2012 at 05:26
what is this stuff?


So I was searching the internet for methods of breaking concrete, and accidentally came upon this:
http://www.archerusa.com/

I didn't know that stuff like this existed and can create such huge pressure to break reinforced concrete safely.

I looked up this dexpan's msds and it says it contains 60-100% Ca(OH)2 , but it doesn't make sense... as far as I know Ca(OH)2 only dissolves in water to a minor degree, and provided there is CO2, it will slowly turn to calcium carbonate, right?

How does it expand when combined with water so fast (max 24 hours) and create such huge pressure?

Here is a video of it in action
http://www.youtube.com/watch?v=YlDQvgM4pKM

the MSDS:
http://www.archerusa.com/nonexplosivesblastingdemolition/dex...

Is this really Ca(OH)2?
View user's profile View All Posts By User
White Yeti
National Hazard
****




Posts: 816
Registered: 20-7-2011
Location: Asperger's spectrum
Member Is Offline

Mood: delocalized

[*] posted on 25-1-2012 at 10:18


Hmm...

You're right, Ca(OH)<sub>2</sub> doesn't make sense, there must be another component to that mixture. It might react with dissolved carbon dioxide in the water, but there's no way that reaction can happen over as little as 24H.

I can't help but think this is a scam of some kind.




"Ja, Kalzium, das ist alles!" -Otto Loewi
View user's profile View All Posts By User
UnintentionalChaos
International Hazard
*****




Posts: 1454
Registered: 9-12-2006
Location: Mars
Member Is Offline

Mood: Nucleophilic

[*] posted on 25-1-2012 at 10:49


Quote: Originally posted by White Yeti  
Hmm...

You're right, Ca(OH)<sub>2</sub> doesn't make sense, there must be another component to that mixture. It might react with dissolved carbon dioxide in the water, but there's no way that reaction can happen over as little as 24H.

I can't help but think this is a scam of some kind.


No, I've used it before...I'm not sure what the stuff is, but it certainly works.




Department of Redundancy Department - Now with paperwork!

'In organic synthesis, we call decomposition products "crap", however this is not a IUPAC approved nomenclature.' -Nicodem
View user's profile View All Posts By User
neptunium
National Hazard
****




Posts: 990
Registered: 12-12-2011
Location: between Uranium and Plutonium
Member Is Offline


[*] posted on 25-1-2012 at 10:56


is it the kind of reaction like water freezing increases its volume hence craks the glass?
hence the "stuff" disolves slowly in water increassing its volume dramaticaly and bang! cracks the concret??
just a wild guess...




View user's profile Visit user's homepage View All Posts By User
Adas
National Hazard
****




Posts: 711
Registered: 21-9-2011
Location: Slovakia
Member Is Offline

Mood: Sensitive to shock and friction

[*] posted on 25-1-2012 at 11:01


Sodium polyacrylate increases volume massively when soaking water. It can absorb very much water (1000 times more than own weigth/volume ??)

EDIT: Not sure if it can break concrete, though.

[Edited on 25-1-2012 by Adas]




Rest In Pieces!
View user's profile Visit user's homepage View All Posts By User
neptunium
National Hazard
****




Posts: 990
Registered: 12-12-2011
Location: between Uranium and Plutonium
Member Is Offline


[*] posted on 25-1-2012 at 11:06


yeah seems like a long shot ....



View user's profile Visit user's homepage View All Posts By User
MrHomeScientist
International Hazard
*****




Posts: 1806
Registered: 24-10-2010
Location: Flerovium
Member Is Offline

Mood: No Mood

[*] posted on 25-1-2012 at 11:09


Yeah there's no way sodium polyacrylate would break anything. While it does expand, it turns into a gel when a lot of water is used and a snow-like consistency with less water. Either way, it's very compressible and I really doubt it would exert enough force to do anything.
View user's profile Visit user's homepage View All Posts By User
Lambda-Eyde
National Hazard
****




Posts: 860
Registered: 20-11-2008
Location: Norway
Member Is Offline

Mood: Cleaved

[*] posted on 25-1-2012 at 11:24


It's most likely calcium oxide, CaO. A similar product is sold where I live which contains relatively pure CaO.



Edit: Turns out I wasn't completely correct - the product above contains 10-30 % aluminate cement and 60-80 % CaO according to the MSDS. The package says 60-100 % CaO, IIRC.

[Edited on 25-1-2012 by Lambda-Eyde]




This just in: 95,5 % of the world population lives outside the USA
Please drop by our IRC channel: #sciencemadness @ irc.efnet.org
View user's profile View All Posts By User
neptunium
National Hazard
****




Posts: 990
Registered: 12-12-2011
Location: between Uranium and Plutonium
Member Is Offline


[*] posted on 25-1-2012 at 11:27


judging by the gnome pushing against rocks with his elbow it must be strong stuff!!!!



View user's profile Visit user's homepage View All Posts By User
condennnsa
Hazard to Others
***




Posts: 217
Registered: 20-4-2010
Location: Romania
Member Is Offline

Mood: No Mood

[*] posted on 25-1-2012 at 21:06


You're right, Lambda-Eyde, i did more searching on calcium oxide expansive mortar and found this paper http://arxiv.org/ftp/arxiv/papers/1107/1107.0074.pdf which makes it clear that it is the hydration of CaO doing all the work.

It pisses me off, why would a producer claim in the material SAFETY datasheet that their product contains Ca(OH)2, which is a mostly inert chemical, instead of the truth, CaO, which is very corrosive and dangerous in moist environments... ?!

I have never worked with CaO, and don't have any but I wound have thought that upon mixing it with water it would heat up, but continue to stay as a slurry and not 'set'.. there must be some strong interlocking of Ca(OH)2 crystals going on..
I have an electric furnace that i got to 800C I'll try and dehydrate some Ca(OH)2 which wiki says it takes 512C , going to check water loss by weight difference

[Edited on 26-1-2012 by condennnsa]
View user's profile View All Posts By User
GreenD
National Hazard
****




Posts: 623
Registered: 30-3-2011
Member Is Offline

Mood: Not really high anymore

[*] posted on 26-1-2012 at 10:13


This would be great with a long drill on some train bridge pillars.
View user's profile View All Posts By User

  Go To Top