netnofeels
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a-Methylstyrene synthesis?
So my brother used this in his paint company a couple years ago and I know it used to be really easy to get hold of but now it seems no one sells it.
How could someone synthesise it? I’ve looked through every forum and tried to think of ways but I can’t find anything. It’s like all of a sudden
it’s a ‘bad’ chemical. The only thing I can think of is i know it’s produced as a by-product in the production of phenol-acetone from cumene.
Up to 2% of the cumene is converted to a-methylstyrene but that’s a very small yield and obviously wouldn’t be an effective way
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Corrosive Joeseph
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Chemical Name: Prop-1-en-2-ylbenzene; alpha-Methylstyrene; 2-Phenyl-1-propene; Isopropenylbenzene; 2-Phenylpropene; 2-Phenylpropylene
CAS RN: 98-83-9
Linear Structure Formula: C6H5C(CH3)=CH2
Molecular Formula: C9H10
Molecular Weight: 118.178 g/mol
All Preps- 477 Reactions.
/CJ
Attachment: REAXYS - alpha-Methylstyrene.rar (4.5MB)
This file has been downloaded 585 times
Being well adjusted to a sick society is no measure of one's mental health
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netnofeels
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Quote: Originally posted by Corrosive Joeseph  | Chemical Name: Prop-1-en-2-ylbenzene; alpha-Methylstyrene; 2-Phenyl-1-propene; Isopropenylbenzene; 2-Phenylpropene; 2-Phenylpropylene
CAS RN: 98-83-9
Linear Structure Formula: C6H5C(CH3)=CH2
Molecular Formula: C9H10
Molecular Weight: 118.178 g/mol
All Preps- 477 Reactions.
/CJ |
Whats that file i couldnt open it?
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netnofeels
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| Quote: Originally posted by Corrosive Joeseph | Chemical Name: Prop-1-en-2-ylbenzene; alpha-Methylstyrene; 2-Phenyl-1-propene; Isopropenylbenzene; 2-Phenylpropene; 2-Phenylpropylene
CAS RN: 98-83-9
Linear Structure Formula: C6H5C(CH3)=CH2
Molecular Formula: C9H10
Molecular Weight: 118.178 g/mol
All Preps- 477 Reactions.
Wow i managed to open it! What is this incredible source?
/CJ |
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TGSpecialist1
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1. Oxidize cumene to cumene hydroperoxide with oxygen: http://www.prepchem.com/synthesis-of-cumene-hydroperoxide/
2. Reduce with sodium sulfite to cumyl alcohol.
3. Distill a mixture of cumyl alcohol and concentrated phosphoric or sulfuric acid to obtain methylstyrene.
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Keras
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Reaxys and SCIFinder are two reaction databases. The first is managed by Elsevier, I think, and the second by the ACS. You can enter the name of a
compound and it will search all reactions that lead to the synthesis of it, for example.
Some are rather arcane or use niche reactants, though.
Here is what I got out of SCIFinder which didn't seem too obtuse.
Attachment: Reaction_06_08_2019_101751.pdf (112kB)
This file has been downloaded 488 times
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