TNAZ
Harmless
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Kinnear Perren condensation
Hi!
I interested in Kinnear Perren complex! I search on the net and on this forum so i found some pdf about this! Mainly i search this document, but i can
not download from sciencedirect!
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi...
If anybody has this or other useful article in this subject please share with me! Thanks in advance!
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not_important
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More properly known as the Clay-Kinnear-Perren phosphonyl chloride synthesis, or Clay-Kinnear-Perren reaction. SFAIK really only useful for R = Me,
Et, i-Pr, t-Bu, and maybe benzyl.
* Clay J. P., J. Org. Chem., 1951, 16, 892.
* Kinnear A. M., Perren E. A., J. Chem. Soc., 1952, 3437.
* Freedman L. D., Doak G. O., Chem. Rev., 1957, 57, 483.
* Pawar R. A., J. Prakt. Chem., 1974, 316, No.3, 507-510.
Preparation and Mechanism of Formation of the Clay-Kinnear-Perren Complex (PDF)
Attachment: acta_vol_20_p0432-0438.pdf (646kB)
This file has been downloaded 686 times
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Klute
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Interesting reaction, never heard of it before.. What do you plan on doing with the dichloroalkylphosphine formed? Phosphine ligands?
\"You can battle with a demon, you can embrace a demon; what the hell can you do with a fucking spiritual computer?\"
-Alice Parr
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