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Author: Subject: Iron(II) sulfate monohydrate from eBay - looks suspicious
chloric1
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[*] posted on 31-1-2023 at 09:12


It’s not critical so long as you have a slight excess of acid. You will be adding more iron into solution anyways.

As long as metallic iron is present ferric will be reduced to ferrous in acid solution




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chloric1
International Hazard
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Posts: 1147
Registered: 8-10-2003
Location: GroupVII of the periodic table
Member Is Offline

Mood: Stoichiometrically Balanced

[*] posted on 31-1-2023 at 16:27


Quote: Originally posted by woelen  
Recovering oxidized iron(II) sulfate is very difficult and is not worth the effort. If you want an iron(II) salt, then next time I would purchase Mohr's salt, Fe(NH4)2(SO4)2.12H2O. Mohr's salt is MUCH more stable in air than ferrous sulfate. It is not so easily oxidized.


Sorry but no. It’s so easy. I have purchased “copperas” from a fertilizer co-op store, took it home, and made up 20% sulfuric acid solution added the brownish yellow iron salt and boiler with regular nails for about an hour or two and let it cool and got beautiful blue green crystals




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