Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
 Pages:  1  2
Author: Subject: good rubber solvent
blogfast25
International Hazard
*****




Posts: 10562
Registered: 3-2-2008
Location: Neverland
Member Is Offline

Mood: No Mood

[*] posted on 23-6-2011 at 06:32


Something seems to have been missed here: the word ‘vulcanised’. Vulcanised rubber (of whatever kind) CANNOT be dissolved in ANYTHING, unless you devulcanise them first. Rubbers based on sulphur based vulcanisation methods can be devulcanised (the sulphur bearing crosslinks split), but other types of vulcanisates (like peroxide based systems) resist devulcanisation almost 100 %. But devulcanising sulphur based vulcanisates is messy and requires chemistry, not mere dissolution.

Vulcanised rubbers belong to the class of ‘thermoset materials’ (like the mother of all: Bakelite) and are essentially one large macromolecule: all polymer chains being interlinked with each other by means of so-called crosslinks.

Sulphur ‘cured’ rubbers include: NR, IR, IIR, SBR, CR, NBR, most types of EPDM (EPR), polysulphide and a few others. Most other synthetic elastomers are cured with irreversible means: peroxides and a small army of propriety chemical packages.

Trust me, I was a rubber technologist for about 15 years. :)



[Edited on 23-6-2011 by blogfast25]
View user's profile View All Posts By User
 Pages:  1  2

  Go To Top