vibbzlab
Hazard to Others
Posts: 241
Registered: 6-11-2019
Member Is Offline
Mood: Always curious
|
|
Help in reduction to naphthylamine
Hello everyone
So I have this 1-nitronaphthalene with me. I am planning to reduce it to naphthylamine. I read somewhere that it's possible with Sn/HCl.
Do anyone have a written experimental method for that.
Amateur chemist. Doctor by profession
Have a small cute home chemistry lab.
Please do check out my lab in YouTube link below
This is my YouTube channel |
|
|
Boffis
International Hazard
Posts: 1879
Registered: 1-5-2011
Member Is Offline
Mood: No Mood
|
|
Hi vibbzlab, check out the SM site library and download one of the books on dye chemistry. I can't remember the title of the best one but is something
like "The chemistry of dye processes" by Fierz-Davis and someone else. its an English translation on the site library. I believe Vogel has the
reduction too.
Iron powder and a little HCl is what I generally try first id the amine is volatile in steam. I am not sure that 1-naphthylamine is but the references
above will help.
|
|
|
vibbzlab
Hazard to Others
Posts: 241
Registered: 6-11-2019
Member Is Offline
Mood: Always curious
|
|
Thank you so much for the suggestion. I will definitely try this out and record it
Amateur chemist. Doctor by profession
Have a small cute home chemistry lab.
Please do check out my lab in YouTube link below
This is my YouTube channel |
|
|
Dr.Bob
International Hazard
Posts: 2748
Registered: 26-1-2011
Location: USA - NC
Member Is Offline
Mood: No Mood
|
|
There are nitro reduction reactions in vogel, many internet preps and also in Organic Syntheses, the series.
http://www.orgsyn.org
https://en.wikipedia.org/wiki/1-Naphthylamine and https://en.wikipedia.org/wiki/2-Naphthylamine
https://www.chemeurope.com/en/encyclopedia/1-Naphthylamine.h...
be aware that both isomers are known carcinogens.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
