Fantasma4500
International Hazard
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 1681
Registered: 12-12-2012
Location: Dysrope (aka europe)
Member Is Offline
Mood: dangerously practical
|
|
Water and fuel mix?
i was just thinking about how they used a mixture of a supersaturated chemical in water along with 5% of waxed aluminium
it required a big booster
water takes some heat ouf of the energy output itself, so i thought why not just add more aluminium, so it would maybe react with the water?
and then- why not just use aluminium and water, or maybe deactivated magnesium and water? that should work, right?
non conventional energetics have been made and used, such as silicon and liquid oxygen, so this could work too
i also remember seeing and trying magnesium + snow, and another hint on this being possible is nasa making nano aluminium powder and mixing with ice,
they called it ALICE, rocket propellant
supposedly this would be the reaction
2 Al + 3 H2O = Al2O3 + 3 H2
so you would seemingly still want some oxidizer left in the mix
i gave up trying to find any references on det of this mix as water and aluminium are 2 quite common terms on the internet
|
|
Tsjerk
International Hazard
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 3026
Registered: 20-4-2005
Location: Netherlands
Member Is Offline
Mood: Mood
|
|
Aluminium and water do react, but Al2O3 forms a protective layer over the aluminum.
|
|
Laboratory of Liptakov
International Hazard
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 1371
Registered: 2-9-2014
Location: Technion Haifa
Member Is Offline
Mood: old jew
|
|
On nano aluminium arise too much Al2O3 on ratio at aluminium. Surface layer of Al2O3 is basically same thickness. After a same time after production.
But particles are 100x - 1000x smaller. Therefore amount of Al2O3 can be 100x bigger after same time. Or more. Than at normal micro particles. Yes.
Mixture nano Alu + water as charge will works. But booster I estimate on 100g brizant and main charge minimal 5 Kg. And the all with fresh nano
particles.
Development of primarily - secondary substances CHP (2015) Lithex (2022) Brightelite (2023) Nitrocelite and KC primer (2024)
|
|
Gargamel
Hazard to Others
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 166
Registered: 9-3-2013
Member Is Offline
Mood: No Mood
|
|
Quote: |
Aluminium and water do react, but Al2O3 forms a protective layer over the aluminum. |
I wonder how good this works if the water contains salts ![:D](./images/smilies/biggrin.gif)
Hydro-AN mixtures are very interesting, I wonder how long they store.
Ammonal IS storage stable, and it is never fully dry.
|
|
Admagistr
Hazard to Others
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 350
Registered: 4-11-2021
Location: Central Europe
Member Is Offline
Mood: The dreaming alchemist
|
|
Quote: Originally posted by Antiswat ![](images/xpblue/lastpost.gif) | i was just thinking about how they used a mixture of a supersaturated chemical in water along with 5% of waxed aluminium
it required a big booster
water takes some heat ouf of the energy output itself, so i thought why not just add more aluminium, so it would maybe react with the water?
and then- why not just use aluminium and water, or maybe deactivated magnesium and water? that should work, right?
non conventional energetics have been made and used, such as silicon and liquid oxygen, so this could work too
i also remember seeing and trying magnesium + snow, and another hint on this being possible is nasa making nano aluminium powder and mixing with ice,
they called it ALICE, rocket propellant
supposedly this would be the reaction
2 Al + 3 H2O = Al2O3 + 3 H2
so you would seemingly still want some oxidizer left in the mix
i gave up trying to find any references on det of this mix as water and aluminium are 2 quite common terms on the internet |
Aluminium reacts violently with water, which heats up and produces a lot of hydrogen, just mixing the aluminum with the gallium and heating it up a
little bit so that the aluminum dissolves in the gallium. I tried it and the reaction was pretty energetic![;)](./images/smilies/wink.gif)
|
|
Admagistr
Hazard to Others
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 350
Registered: 4-11-2021
Location: Central Europe
Member Is Offline
Mood: The dreaming alchemist
|
|
2Al+4H2O=2AlOOH+3H2.
|
|
MineMan
National Hazard
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 998
Registered: 29-3-2015
Member Is Offline
Mood: No Mood
|
|
Quote: Originally posted by Laboratory of Liptakov ![](images/xpblue/lastpost.gif) | On nano aluminium arise too much Al2O3 on ratio at aluminium. Surface layer of Al2O3 is basically same thickness. After a same time after production.
But particles are 100x - 1000x smaller. Therefore amount of Al2O3 can be 100x bigger after same time. Or more. Than at normal micro particles. Yes.
Mixture nano Alu + water as charge will works. But booster I estimate on 100g brizant and main charge minimal 5 Kg. And the all with fresh nano
particles. |
I would disagree. The oxide layer is 4nm thick, while most nm Al particles are 100nm. Even after years, 100nm aluminum is still good.
One would be insane not to use a 30 percent hydrogen peroxide instead, it will still be stable but more sensitive and more powerful.
|
|
Fantasma4500
International Hazard
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 1681
Registered: 12-12-2012
Location: Dysrope (aka europe)
Member Is Offline
Mood: dangerously practical
|
|
ammonia for instance prevents steel from rusting
in vietnam they used "daisy cutters"
1m3 of ammonium salt slurry with 5% waxed aluminium
it required a strong booster, but it gave off much more gas as the water would become a gas and cause effective and cheap gas output, supposedly with
lower total heat
as for using H2O2- i think were gonna have to let that one sit until we can come up with very doable ways of making it at home, i would nominate PbO2
electrolysis of perchlorate salts forming ozone, then that reacted with water to form H2O2
i dont think you can rely on oxide layer to protect aluminium, there were cases where wet firecrackers went off all on their own, and thats surely not
nanoparticles, probably around 800 mesh aluminium powder, and due to the low solubility of perchlorate that shouldnt make much of an impact
i doubt the tiny bit of sulfur in the blackpowder from the fuse would have much impact either, i believe aluminium oxide formed on aluminium powder is
somewhat porous, now that i think of it, boric acid is normally used in pyrotechnic mixtures with water and aluminium, and also used for some
productions such as belt-sander with aluminium bar where the dust is caught in a solution of boric acid
|
|
Colleen Ortiz
Harmless
Posts: 19
Registered: 16-12-2021
Member Is Offline
|
|
When Aluminum and Water react, During shipment, handling, outdoor storage, unintentional damage, or cable junction or termination failures, water can
enter a cable. Aluminium interacts with water to generate hydrogen gas according to the equation 2Al + 3H2O 3H2 + Al2O3 because of its significantly
negative redox potential. When this chemical reaction happens between the strands of an aluminum conductor, it may be very important. Evidence
suggests that such a process might result in a considerable build-up of hydrogen gas.
At room temperature, the aluminum metal reacts easily with water to generate aluminum hydroxide and hydrogen. A coating of aluminum oxide naturally
protects the raw metal, preventing it from coming into direct contact with water. This reaction seldom occurs. The aluminum-water interaction
generates hydrogen without emitting any greenhouse gases, and it promises to address the transportation problem in any area with water. The most
effective option is to use radial and longitudinal water blocking prevention measures to prevent water from entering the power conductor system in the
first place. These safeguards, however, are not always present. Copper, rather than aluminum, is a second and as effective alternative. The problem is
solved since copper does not react with water.
The following is the interaction between aluminum metal and water at room temperature to produce aluminum hydroxide and hydrogen:
2 Al + 6 H2O = 2 Al(OH)3 + 3 H2 = 2 Al(OH)3 + 3 H2.
The aluminum oxide layer on the metal is disrupted by these additions.
|
|
MineMan
National Hazard
![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif) ![*](images/xpblue/star.gif)
Posts: 998
Registered: 29-3-2015
Member Is Offline
Mood: No Mood
|
|
Quote: Originally posted by Colleen Ortiz ![](images/xpblue/lastpost.gif) | When Aluminum and Water react, During shipment, handling, outdoor storage, unintentional damage, or cable junction or termination failures, water can
enter a cable. Aluminium interacts with water to generate hydrogen gas according to the equation 2Al + 3H2O 3H2 + Al2O3 because of its significantly
negative redox potential. When this chemical reaction happens between the strands of an aluminum conductor, it may be very important. Evidence
suggests that such a process might result in a considerable build-up of hydrogen gas.
At room temperature, the aluminum metal reacts easily with water to generate aluminum hydroxide and hydrogen. A coating of aluminum oxide naturally
protects the raw metal, preventing it from coming into direct contact with water. This reaction seldom occurs. The aluminum-water interaction
generates hydrogen without emitting any greenhouse gases, and it promises to address the transportation problem in any area with water. The most
effective option is to use radial and longitudinal water blocking prevention measures to prevent water from entering the power conductor system in the
first place. These safeguards, however, are not always present. Copper, rather than aluminum, is a second and as effective alternative. The problem is
solved since copper does not react with water.
The following is the interaction between aluminum metal and water at room temperature to produce aluminum hydroxide and hydrogen:
2 Al + 6 H2O = 2 Al(OH)3 + 3 H2 = 2 Al(OH)3 + 3 H2.
The aluminum oxide layer on the metal is disrupted by these additions.
|
What’s your point?
|
|