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Author: Subject: Tetrahalomercurates + photos
vano
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[*] posted on 1-1-2021 at 12:33
Tetrahalomercurates + photos


• Today i made some tetrahalomercurates. I usually made copper Tetraiodomercurate. I overheated it and when the water evaporated it turned brown due to thermochromism. It is usually red in color. I have a little more red, it will just precipitate overnight and this time I will dry it at a low temperature.

CuCl + K2[HgI4] = Cu2[HgI4] + 2KCl

• Lead diiododibromomercurate is as follows. I added potassium bromide to the mercury iodide and dissolved it in water. Then I heated the solution slightly and added lead acetate solution. The second photo shows lead diiododibromomercurate. That is why in the first photo their mixture is in a test tube.

Pb(CH3COO)2 + K2[HgI2Br2] = Pb[HgI2Br2] + 2CH3COOK

• I did the same with cadmium diiododibromomercurate. It is a very nice red compound. It will probably turn yellow when heated. I do not know. But the interesting thing is that yesterday I mixed cadmium bromide solution and mercury iodide, but nothing happened. And in this way it easily precipitated. The solution was initially yellow but soon reddened. very strange. I think I will make more of a similar compound.

CdSO4+ K2[HgI2Br2] = Cd[HgI2Br2] + K2SO4

received_164658418747580.jpeg - 234kB received_3527674207317978.jpeg - 337kB



This is a solution of potassium diiododibromomercurate.
received_736631226965404.jpeg - 459kB

[Edited on 1-1-2021 by vano.kavt]

[Edited on 1-1-2021 by vano.kavt]
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