iloveloli
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Registered: 8-8-2015
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5-hydroxytetrazole ??
well
i can't get any Guanidine.... so i decide to use urea
First, 5-hydroxytetrazole is exist. (i can find it on Chemspider)
my question is if it can be synthesis by mixing semicarbazide and NO+
like the reaction of aminoguanidine and NO+ ...... to form 5-Aminotetrazole
i saw the mechanism of forming 5-Aminotetrazole in wiki
https://zh.wikipedia.org/wiki/%E5%9B%9B%E5%94%91 ( i am sorry about that it is chinese, but English don't have the mechanism)
i think semicarbazide will be the same
am i right??
please forgive my poor English
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clearly_not_atara
International Hazard
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Registered: 3-11-2013
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http://onlinelibrary.wiley.com/doi/10.1002/prep.201100108/ab...
| Quote: | | Tetrazolone (5-oxotetrazole, 1) is formed by diazotization of 5-aminotetrazole in the presence of CuSO4 |
I'm guessing they would tell you if semicarbazide worked. As it is I'm guessing that semicarbazide + N2O3 reaction produces carbamyl azide, possibly
trimerizing to cyanuric acid and hydrogen azide -- although it may simply produce a loud noise and a lot of smoke, instead.
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