VinnyC
Harmless
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Registered: 11-8-2007
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Oppenauer Oxidation
Hey everyone... Been ages I guess. Some of you may remember me. Wondering if anyone has performed an Oppenauer Oxidation, and if so, what form of the
procedure was found to be most appealing? What catalyst, amounts/%'s worked for a good reaction, etc? Could you describe the setup and process?
Thanks
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solo
International Hazard
Posts: 3975
Registered: 9-12-2002
Location: Estados Unidos de La Republica Mexicana
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Mood: ....getting old and drowning in a sea of knowledge
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Reference Information
Oppenauer oxidation, named after Rupert Viktor Oppenauer [1], is a gentle method for oxidizing secondary alcohols to
ketones.......source,
http://en.wikipedia.org/wiki/Oppenauer_oxidation
this reaction found in the org. synthesis gives the working conditions and apparatus used......
The Oppenauer oxidation of cholesterol to Δ4-cholesten-3-one ...
http://www.orgsyn.org/orgsyn/default.asp?formgroup=basenpe_f...
[Edited on 19-8-2007 by solo]
It's better to die on your feet, than live on your knees....Emiliano Zapata.
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