chromium
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Way to propionic acid?
Polymethyl methacrylate is very common plastic. By heating it is said to depolymerize to methyl methacrylate. Later can be saponified with NaOH
solution to make sodium methacrylate which can be converted to methacrylic acid.
Wikipedia says that when fused with an alkali, methacrylic acid forms propionic acid. Can someone comment on this?
When all think alike, then no one is thinking. - Walter Lippmann
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solo
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Reference(s) for synthesis of Propionic acid
Mucientes, A.E., Poblete, F.J., Rodriguez, M.A., and Santiago, F. 1997. J. Phys. Org. Chem. 10:662-668.
Singh, B., Singh, A.K., Singh, N.B., and Saxena, B.B.L. 1984. Ru(III) catalysis in oxidation of n-propanol and n-butanol by acidic solutions of
bromamine-ULE. Tetrahedron. 40:5203-5206.
http://designer-drug.com/pte/12.162.180.114/dcd/chemistry/pr...
[Edited on 22-7-2007 by solo]
It's better to die on your feet, than live on your knees....Emiliano Zapata.
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solo
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Reference Information
KINETIC STUDY OF THE OXIDATION OF PROPAN-1-OL BY ALKALINE HEXACYANOFERRATE(III) CATALYZED BY RUTHENIUM TRICHLORIDE.
Mucientes, A.E., Poblete, F.J., Rodriguez, M.A., and Santiago, F.
J. Phys. Org. Chem. 10:662-668.,1997
[Edited on 22-7-2007 by solo]
Attachment: KINETIC STUDY OF THE OXIDATION OF PROPAN-1-OL BY ALKALINE HEXACYANOFERRATE(III) CATALYZED BY RUTHENIUM TRICHLORIDE.pdf (155kB)
This file has been downloaded 1375 times
It's better to die on your feet, than live on your knees....Emiliano Zapata.
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solo
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Reference Information
Ru(III) catalysis in oxidation of n-propanol and n-butanol by acidic solutions of bromamine-ULE
Singh, B., Singh, A.K., Singh, N.B., and Saxena, B.B.L. .
Tetrahedron. 40:5203-5206.,1984.
Attachment: Ru(III) catalysis in oxidation of n-propanol and n-butanol by acidic solutions of bromamine-ULE.pdf (317kB)
This file has been downloaded 961 times
It's better to die on your feet, than live on your knees....Emiliano Zapata.
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Sauron
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What's wrong with good old CrVI or KMnO4 oxidation of n-propanol?
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not_important
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Or for even more OTC, what's wrong with good old haloform reaction on MEK?
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evil_lurker
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Even more OTC... go to you local new holland dealer and by sodium propionate by the drum.
Not all chemicals are bad. Without chemicals such as hydrogen and oxygen, for example, there would be no way to make water, a vital ingredient in
beer.
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chemrox
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what's the farm application?
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bio2
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Propionates inhibit spoilage in certain foods.
Specifically it is used as a mold inhibitor in bakery products.
[Edited on by bio2]
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