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Author: Subject: Dimethylcalcium synthesis cracked
Mabus
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[*] posted on 5-2-2018 at 09:12
Dimethylcalcium synthesis cracked


https://cen.acs.org/articles/96/i5/Dimethylcalcium-synthesis...
https://pubs.acs.org/doi/abs/10.1021/jacs.7b12984?source=cen
So they obtained this compound by reacting methyllithium with calcium bis(trimethylsilyl)amide. Apparently obtaining this compound was complicated as all routes also gave lithium and calcium chlorides, which could not be separated from the product.




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