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Author: Subject: Natural MOFs found in Siberia
Mabus
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[*] posted on 8-8-2016 at 06:00
Natural MOFs found in Siberia


http://gizmodo.com/strange-minerals-from-siberian-mine-are-u...
They were first found in the 1940s, but their discovery went unnoticed until recently. Interesting find, up until now MOFs were only made in lab.




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Morgan
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[*] posted on 8-8-2016 at 07:46


"NaMgAl(ox)3·9H2O was prepared according to a published procedure (22). Synthetic stepanovite was prepared by dissolving stoichiometric amounts of NaOH, MgO (≥99% trace metals basis, ~325-mesh powder; Sigma-Aldrich), and Fe2O3 (nanopowder; Sigma-Aldrich) in aqueous oxalic acid solution. The resulting green solution was stirred overnight, filtered, and left to evaporate at 4°C. Green, rhombohedral crystals were obtained after 2 days."
http://advances.sciencemag.org/content/2/8/e1600621.full
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