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Author: Subject: World's most expensive light bulb?
White Yeti
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[*] posted on 27-1-2012 at 10:39
World's most expensive light bulb?


I had a strange idea dating back to two years ago and didn't have the will to look further into it, until now. It's a little more physics than chemistry.

In high school physics, you learn about the origin of electromagnetic waves and photons. Photons as quanta of energy, originate from the energy transitions of electrons in exited atoms. Electromagnetic waves can also be created as a result of the flow of an alternating current through a wire (or antennae). The frequency of the alternating current would correspond to the frequency of electromagnetic radiation emitted.

So theoretically, could you have a source of light resulting from electrons oscillating in a superconductor rotating 4x10^14 times every second in a magnetic field?

This is far beyond anything I could ever try in my crummy little lab, but as a challenge, how could you get a superconductor to spin fast enough in a magnetic field to emit visible light?

Does anyone know how you could make "gears" that would not introduce friction? Magnetic coupling of some kind that would also serve as a mechanical advantage?

Any friction or heat losses at these speeds means the self destruction of the whole thing; hence the use of a superconductor rather than a regular conductor.

Any ideas?
Armchair speculation is welcomed, so long as it is relevant to the topic.




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[*] posted on 27-1-2012 at 11:40


You can suspend it in a magnetic field in transparent glass chamber immersed in some cryogenic cooling liquid (let's use liquid helium to put an even worse price tag on it).

Even if you could spin it by using different set of alternating magnetic fields and even if it does emit visible wavelength (not exactly my area, so bear with me), the problem isn't the setup, but the forces involved. There's no material of any kind, let alone superconductive, that would be able to withstand the centrifugal forces that would arise when the frequency of spinning is 10e14. Even the strongest materials we know, not neccessarily superconductive, would burst to schrapnels way before the frequency reaches that value. Even with small spheres spinning, the forces and velocities would be fantastically huge.




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Lambda-Eyde
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[*] posted on 27-1-2012 at 12:41


Try to calculate the largest possible diameter such a sphere would be required to have in order for the radial speed not to exceed c... ;)



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[*] posted on 27-1-2012 at 12:54


You are about to discover that the setup you imagine pretty much describes an atom!

In the bohr model, an electron revolves around the nucleus at a rate of approximately 2 million meters/sec. Let's use this number in a simple calculation. One rotation in your setup takes 10^-14 seconds, so the length of one lap = 2*10^6/10^14 = 2*10^-8 meters.
A circular lap has a radius of 2*10^8/(2*pi) = 3.18 *10^-9, or 31 Angstrom.

The diameter of a real hydrogen atom is 1.1 Angstrom, so I would say the dimensions are of similar magnitude...

You can't design a device of visible dimensions by assuming faster speeds. Even if your superconductor (or the electron) were traveling at the speed of light, the maximum radius of the rotation will turn out to be only 119 nm, invisibly small and quite a bit smaller than the light it would emit (your rotational rate corresponds to 750 nm, or just barely visible red light)

In the days before quantum mechanics, this is exactly what puzzled phyisists: why does the electron not radiate light, losing energy in the process and eventually fall onto to the nucleus? So your idea would work if classical physics were true. In real life, this problem led to the development of Quantum mechanics, in which there can only be certain orbit(al)s around the nucleus, and once the electron is in the lowest energy orbital, it can't radiate its energy to fall any closer to the nuclus.

[Edited on 27-1-2012 by phlogiston]

[Edited on 27-1-2012 by phlogiston]




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[*] posted on 27-1-2012 at 13:12


Gosh. Is it me or is the quality of threads worsening significantly lately?

In any case, these are the expensive "light bulbs" big girls and boys play with:
https://en.wikipedia.org/wiki/Synchrotron#List_of_installati...

Quote:
The diameter of a real hydrogen atom is 1.1 Angstrom

Interesting. After 1.1 Å the atom suddenly stops or how are we to understand the diameter of an atom? (Maybe you are talking about the VdW radius or the radial electron density maximum?)
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[*] posted on 27-1-2012 at 13:33


What if the magnets were also spinning in the opposite direction to that of the superconductor, thereby cutting the speed down to half (2x10^14 revolutions per second). It doesn't help out much but it's better than nothing. It might make the set-up more complex than it already is.



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[*] posted on 29-1-2012 at 15:06


Quote:
Interesting. After 1.1 Å the atom suddenly stops or how are we to understand the diameter of an atom? (Maybe you are talking about the VdW radius or the radial electron density maximum?)


Not that it matters for this discussion in any way, but I took double the most probably distance between the nucleus and the electron (aka the bohr radius) as the number for the diameter of the hydrogen atom.




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[*] posted on 29-1-2012 at 17:03


Quote:
What if the magnets were also spinning in the opposite direction to that of the superconductor


If you want to move electrons around in order to see some sort of moving-electrical-charges phenomenon, you're a million times better off *just moving the electrons* (i.e creating a current or even an arc, beta ray beam or w/e) than trying to move the heavy matter that they're attached to. In this case, I believe that something sort of similar to what you're proposing has already been done: http://en.wikipedia.org/wiki/Free-electron_laser




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[*] posted on 30-1-2012 at 00:58


Quote: Originally posted by Lambda-Eyde  
Try to calculate the largest possible diameter such a sphere would be required to have in order for the radial speed not to exceed c... ;)

Actually I expect all members to be able to do that in their head without pen and paper (at least the order of magnitude). It's bigger than I had estimated at first.
More interesting calculations: What is the acceleration of particles at the equator of the sphere? And what kind of radiation do you expect from charged particles subjugated to that acceleration? That's the kind of thing the poster should have worked out on paper before posting and included in the original post. You know, showing that you have put some thought into your question. We demand that from people posting in organic chemistry and I think the same level should be required for all Fundamental forums with the exception of Beginnings.

Quote:
Not that it matters for this discussion in any way, but I took double the most probably distance between the nucleus and the electron (aka the bohr radius) as the number for the diameter of the hydrogen atom.

Oh, I think this is more interesting than the rest of this thread, since it shows how flimsy the concept of atom size is. Your definition is a bit like saying the border of our solar system is somewhere in the sun (I'm guessing - the highest radial mass density could also be somewhere else). ;)

Quote:
If you want to move electrons around in order to see some sort of moving-electrical-charges phenomenon, you're a million times better off *just moving the electrons* (i.e creating a current or even an arc, beta ray beam or w/e) than trying to move the heavy matter that they're attached to. In this case, I believe that something sort of similar to what you're proposing has already been done: http://en.wikipedia.org/wiki/Free-electron_laser

Sigh. And why do you think I have posted a link the the Wikipedia page of synchrotrons? Wigglers and undulators are not some "has already been done"-kind of technology. It's routine "performed in numerous locations around the world 24/7"-technology. Used extensively in academia and business: Your sample is too complex (often an euphemism for too crappy)? Send it to the synchrotron. Need a publication? Send random sample to the synchrotron. It's that common. Beta rays? What's wrong with a CRT? :P

And of course the other way to "move electrons around in order to see some sort of moving-electrical-charges phenomenon" is to apply a high frequency electromagnetic field. Commonly know as "light". That's how these things work:
http://en.wikipedia.org/wiki/Dispersion_%28optics%29
http://en.wikipedia.org/wiki/Non-linear_optics
http://en.wikipedia.org/wiki/Second-harmonic_generation
http://en.wikipedia.org/wiki/Diffraction

The basics for all that are known for over a century:
http://en.wikipedia.org/wiki/Maxwell%27s_equations
http://en.wikipedia.org/wiki/Special_relativity
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[*] posted on 30-1-2012 at 01:48


Quote: Originally posted by turd  
Gosh. Is it me or is the quality of threads worsening significantly lately?


No it's not you. Not only that the drive through window people are getting worse if this is possible. While watching 'night of the comet' I started thinking maybe genetic altering space dust really is coming down.




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[*] posted on 30-1-2012 at 04:55


Quote:

Quote:
Not that it matters for this discussion in any way, but I took double the most probably distance between the nucleus and the electron (aka the bohr radius) as the number for the diameter of the hydrogen atom.

Oh, I think this is more interesting than the rest of this thread, since it shows how flimsy the concept of atom size is. Your definition is a bit like saying the border of our solar system is somewhere in the sun (I'm guessing - the highest radial mass density could also be somewhere else).


While I must admit there are many possible definitions of 'atom size' that will give widely different numbers and you could call that 'flimsy', it is perfectly feasible to pick a definition of atom size that is good enough for a given discussion. If you insist that everything in the world has infinite dimensions because of the Heisenberg uncertainty, ofcourse you are right in a sense but it is not helpful to get a meaningful sense of dimensions at the atomic level.

The solar system analogy is very poor for several reasons. If you were to apply the definition of bohr radius to the solar system, you would simply get nearly the same result as what you expect from a classical calculation of its dimensions. The 'most probable distance' of the earth to the sun is nearly the same as the classically defined distance, as quantum effects are negligable at planetary scales.
The 'radial mass density' you speak of is an entirely different thing. The mass of the nucleus has only a infinitely small effect on the electronic orbitals as I am sure you are well aware. The bohr radius is not weighted by mass (or electrostatic charge, which would be the equivalent force to gravity within an atom).




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[*] posted on 31-1-2012 at 17:01


Quote: Originally posted by bbartlog  
If you want to move electrons around in order to see some sort of moving-electrical-charges phenomenon, you're a million times better off *just moving the electrons* (i.e creating a current or even an arc, beta ray beam or w/e) than trying to move the heavy matter that they're attached to. In this case, I believe that something sort of similar to what you're proposing has already been done: http://en.wikipedia.org/wiki/Free-electron_laser


Thanks that was helpful! I didn't know that some lasers operated on this principle, tuneable too. All you'd need is a high intensity source of beta rays and some neodymium magnets aligned around an evacuated tube.




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[*] posted on 1-2-2012 at 02:49


Quote:
I didn't know that some lasers operated on this principle, tuneable too.

You should have known after the fourth post to this thread. We used to complain about people not going to the library. Too lazy to read Wikipedia pages is a new low.

Quote: Originally posted by phlogiston  

While I must admit there are many possible definitions of 'atom size' that will give widely different numbers and you could call that 'flimsy', it is perfectly feasible to pick a definition of atom size that is good enough for a given discussion.

Of course - I'm using various size definitions myself on a regular basis: https://www.sciencemadness.org/whisper/viewthread.php?tid=18... My point was not that the different definitions make the concept flimsy, but that which ever you choose - you're trying to describe a complex (not in the sense of complex numbers, but as in with many parameters) function with a single real. Impossible. Since many of these aspects have exponential and high order polynomial terms it may be "good enough" but there's always some grey area. In a way chemistry is not a hard science. It's all about fuzzy similarities.

Take the Van-der-Waals radius: For light atoms it works OK, but you will always find cases where non-bonding atoms are closer than the VdW radius. Now you could define it as the closest distance that has ever been observed, but that would be quite useless for the common case. And for fatter atoms (e.g. Barium) - LOL. They are so soft that the whole concept just doesn't make any sense.

So people go from one to two parameters: http://en.wikipedia.org/wiki/Bond_valence_method but even that doesn't work with fat atoms, since the bond length distributions are very broad.

One exception is the scattering length of the neutron diffraction people. That's a nice number. But what is a negative length?? ;)
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[*] posted on 1-2-2012 at 12:08


Quote: Originally posted by turd  
You should have known after the fourth post to this thread. We used to complain about people not going to the library. Too lazy to read Wikipedia pages is a new low.


I am not lazy, I simply did not know these types of lasers existed. I can't look up something I don't know exists. If I were lazy, I would have asked you how a synchotron or a FEL works; point out any place that shows evidence of laziness and I will take all this back

I know how synchotrons work, and apparently FELs operate on the same basic principle; deflecting the trajectories of electrons in a beam, thus converting their kinetic energy into coherent electromagnetic radiation.




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