Sciencemadness Discussion Board

reduction nitrate

Filemon - 29-7-2007 at 04:02

Can it reduce the nitrate with Al? I have even read that it can reduce with S + NaOH to produce nitrite and NaSO4. Is this safe? There is explosion risk?

[Edited on 29-7-2007 by Filemon]

UnintentionalChaos - 29-7-2007 at 09:57

uNitrate + aluminum = fireworks. S + NaOH makes a messy mixture of compounds and the final product would be hard to isolate. The standard procedure is to use lead, IIRC.

Per - 29-7-2007 at 10:19

I tried this reaktion with sodium nitrate and lead,
putted the lead in the molten NaNO3 and stirred for a while.
After half an hour noething happened, donĀ“t know why but after the mix solidifies I could see that the lead has just molten and accumulated at the bottom of the glass pot.
- No yellow PbO at all.

Filemon - 29-7-2007 at 11:29

Which the yield is heating nitrate? There would be a mixture nitrate and nitrite. It would be necessary to separate them.

not_important - 30-7-2007 at 02:44

see here

http://www.sciencemadness.org/talk/viewthread.php?tid=6620

and here

http://www.sciencemadness.org/talk/viewthread.php?tid=8301

and the long thread here

http://www.sciencemadness.org/talk/viewthread.php?tid=52#pid...