Sciencemadness Discussion Board

Natural MOFs found in Siberia

Mabus - 8-8-2016 at 06:00

http://gizmodo.com/strange-minerals-from-siberian-mine-are-u...
They were first found in the 1940s, but their discovery went unnoticed until recently. Interesting find, up until now MOFs were only made in lab.

Morgan - 8-8-2016 at 07:46

"NaMgAl(ox)3·9H2O was prepared according to a published procedure (22). Synthetic stepanovite was prepared by dissolving stoichiometric amounts of NaOH, MgO (≥99% trace metals basis, ~325-mesh powder; Sigma-Aldrich), and Fe2O3 (nanopowder; Sigma-Aldrich) in aqueous oxalic acid solution. The resulting green solution was stirred overnight, filtered, and left to evaporate at 4°C. Green, rhombohedral crystals were obtained after 2 days."
http://advances.sciencemag.org/content/2/8/e1600621.full