Lithium chlorate LiClO3

Has somebody know how about LiClO3? His produce seems be pretty easy. Metal Lithium is easy get from old battery. On YT is many videos about it. Get Potassium and sodium is difficult. But Lithium is everywhere. Water and Li = LiOH solution in water. H2O + LiOH+Cl2 = LiClO3 + 5 LiCl + 3 H2O. LiCl has 3,5x less solubility in water than LiClO3. His solubility in water is huge, 777g in 100g H20 at 60 C. Even 250g at 0 Celsia. Solubility LiCl in 0 celsia is only 70g. This properties his predispose for contruction water gel or water plastic energetic materials. With suitable fuel. Principle should be similarly as NaClO4 + diethylene glycole + water. And It is very powerful water plastic EM. Prepare Cl is easy from HCl + KMnO4 (school methode on YT). Information about LiClO3 + fuel is very small, less, nothing. Prepare LiClO3 seems, maybe easily, than Na ClO3 from bleach.
Types of reactions:
• KClO3 + LiOH = KOH + LiClO3
• 6 LiOH + 3 Cl2 = 5 LiCl + LiClO3 + 3 H2O
• LiOH + HClO3 = H2O + LiClO3
• LiClO3 + K = Li + KClO3
Thanks for answers. ...LL...

[Edited on 13-2-2016 by Laboratory of Liptakov]

[Edited on 13-2-2016 by Laboratory of Liptakov]

If arises from Li hydroxide 5 parts LiCl and 1 part LiClO3, is produce really expensive. Even perhaps you have very cheap Li cell. Or free. Maybe some get 5 Kg of cells free. After is possible do it experiments. You have right. Thanks....LL...

Thanks for link, I read all. Producing any EM on based LiClO3 or LiClO4 is so disadvantage, that all others EM are better. Even in NASA used and prefer NH4ClO4. Only in cause, that Santa Claus should bring 2 Kg pure LiClO4 under tree. It is last possibility, how tested Lithium chlorate or perchlorate.
Santa........

By chance, I'm the owner of 100kg LiOH, two 50kg drums from a bank-routed chemical grocery company --> kind of "garage sale" at 1€/kg...that was a very good deal 100 €/100 kg .
It is one of my valuable war treasure...aside with AgCN (1kg/1€) and about 1000 kg (or L) of valuable chemical grade reagents and solvants, glassware, ...

Quote: Originally posted by PHILOU Zrealone

By chance, I'm the owner of 100kg LiOH, two 50kg drums from a bank-routed chemical grocery company --> kind of "garage sale" at 1€/kg...that was a very good deal 100 €/100 kg . It is one of my valuable war treasure...aside with AgCN (1kg/1€) and about 1000 kg (or L) of valuable chemical grade reagents and solvants, glassware, ...

Quote: Originally posted by Laboratory of Liptakov

H2O + LiOH+Cl2 = LiClO3 + 5 LiCl + 3 H2O Types of reactions: • KClO3 + LiOH = KOH + LiClO3 • 6 LiOH + 3 Cl2 = 5 LiCl + LiClO3 + 3 H2O • LiOH + HClO3 = H2O + LiClO3 • LiClO3 + K = Li + KClO3

•KClO3 + LiOH = KOH + LiClO3
Maybe, depends on solubility of LiOH vs LiClO3 and of KClO3 vs KOH, I think the favored side of reaction is the left because both left compounds are least soluble...

•6 LiOH + 3 Cl2 = 5 LiCl + LiClO3 + 3 H2O
If you had AgClO3; then you could simply add it to LiCl or to your batch to get precipitated AgCl and all LiCl converted to LiClO3...

• LiOH + HClO3 = H2O + LiClO3
HClO3 is interesting but even better is its conversion with +/-50% yield into HClO4 by disproportionation heating of the 35% solution upon boiling....avoid using over 35% as starting material because (explosive ClO2 goes out of solution above 40% cold HClO3).
4 HClO3 --> 3 HClO4 + HCl
HClO3 + HCl --> Cl2 + H2O + O2
--------------------------------------
5 HClO3 --> 3 HClO4 + Cl2 + H2O + O2
Then
LiOH + HClO4 --> LiClO4 + H2O

• LiClO3 + K = Li + KClO3
Nope! You of course know what happens when mixing eletropositive metals like Mg or Al with chlorate salts...flash powder....
What would you think will happen with super electropositive metal like potassium and a super oxydiser like a chlorate?
--> Big deflagration or detonation ... maybe even contact explosive!
--> LiClO3 + 2 K --> LiCl + K2O + O2

Side notes:
Weird reaction LiCl somehow also hydrolyses back to base and acid...
LiCl + H2O <----> LiOH + HCl

Apparently conversion of LiClO3 to LiClO4 must be possible and easy via electrolysis...so all way down from LiCl to LiClO4 easier than for NaCl or KCl?

[Edited on 15-2-2016 by PHILOU Zrealone]

Believe

Well, thanks for everybody. Almost all the life I would think, that Santa Claus no exist. However, Important caution, ladies and gentlemans: Penguins from Antarctica believe. Madagascar and all his inhabitants believe. Kowalski believe. Coca Cola believe. And maybe even Putin early believe, that really Santa Claus is

PHILOU Zrealone. And I personally? In Frame of energetic materials? Of course. I believe .. ...



[Edited on 14-2-2016 by Laboratory of Liptakov]

Quote: Originally posted by Laboratory of Liptakov

Well, thanks for everybody. Almost all the life I would think, that Santa Claus no exist. However, Important caution, ladies and gentlemans: Penguins from Antarctica believe. Madagascar and all his inhabitants believe. Kowalski believe. Coca Cola believe. And maybe even Putin early believe, that really Santa Claus is PHILOU Zrealone. And I personally? In Frame of energetic materials? Of course. I believe .. ... [Edited on 14-2-2016 by Laboratory of Liptakov]

I'm a true believer and in Belgium he comes twice a year under close related names ... on 6th december as Santa-Nicolaus (Santa-Nicklaus, Saint-Nicolas, Sint-Niklaas, Sinterklaas, Saint-Nicholas) and on 24th december as Santa Claus (Père Noel, Kerstvader, Father Christmas, Weihnachtsmann).