Sciencemadness Discussion Board

Reaction rate homework help

blackmamba123 - 31-5-2015 at 19:50

Hey guys I just stumbled on this question. If you can help that would be great.

The following is a proposed mechanism for this reaction. One of the species has been left out and replaced with "?". Determine what that species is.

Step 1: OCl- + H2O β†’ HOCl + OH- ( fast )
Step 2: I- + ? β†’ IOH + Cl- ( slow )
Step 3: IOH + OH- β†’IO - + H2O ( fast )

- Which three species in the mechanism above are intermediates?

-Which species is the catalyst?

I thought that a catalyst would remain unchanged throughout the reaction and I am a little confused as if i am to consider these steps as one overall reaction?

Thanks for any help

DraconicAcid - 31-5-2015 at 20:21

If you add up the three steps, you will get the overall reaction.

A catalyst will be unchanged, but only because it is consumed in one step, and regenerated in another. An intermediate is the reverse- generated in one, consumed later.

blackmamba123 - 31-5-2015 at 21:50

Could you explain what is meant by intermediates in a little more detail please

DraconicAcid - 31-5-2015 at 21:53

An intermediate is a species which is generated in one step of the reaction, and then consumed, so it does not appear in the overall reaction.

billybob - 2-6-2015 at 18:42

so i would suppose it would be HOCl, IOH, and IO-?

DraconicAcid - 2-6-2015 at 18:46

I'm not going to help you with that part, Grasshopper. You must find your own path.

billybob - 2-6-2015 at 18:51

It is the correct answer!

[Edited on 3-6-2015 by billybob]