Sciencemadness Discussion Board

Chalk purification

DalisAndy - 15-5-2015 at 16:29

How would I go about purifying calcium carbonate in children's chalk? It should make a handy reagent.

blogfast25 - 15-5-2015 at 16:40

Not all children's chalk is CaCO3, some of it is Gypsum. Test using a bit of acid.

But CaCO3 is a pretty useless reagent, actually.

DistractionGrating - 15-5-2015 at 16:53

Isn't CaCO3 useful as a primary standard for determination of calcium by EDTA titration?

blogfast25 - 15-5-2015 at 17:25

Quote: Originally posted by DistractionGrating  
Isn't CaCO3 useful as a primary standard for determination of calcium by EDTA titration?


Among other things, yes. Highly pure, so-called precipitated CaCO3 is used for it. Highly pure metals (dissolved in acid) like Al, Zn or Pb have also been used as standards.

Another analytical uses (at least at the time) is the extraction of alkali metals from minerals like Lepidolite.

DalisAndy - 15-5-2015 at 18:05

Yep that was my aim with it. Cause it's the sulfate anion more reactive that carbonate anion?

blogfast25 - 16-5-2015 at 06:10

Quote: Originally posted by DalisAndy  
Yep that was my aim with it. Cause it's the sulfate anion more reactive that carbonate anion?


WHAT was your aim?

The second sentence makes no sense whatsoever. 'Reactivity' is a very relative term and depends entirely on chemical CONTEXT.

Dan Vizine - 20-5-2015 at 12:30

Quote: Originally posted by blogfast25  


WHAT was your aim?

The second sentence makes no sense whatsoever. 'Reactivity' is a very relative term and depends entirely on chemical CONTEXT.


Ahhh...I missed that. Good to be back.

But, seriously, why devote any time to this, because you can buy it so cheaply? There are lots of better things to recrystallize than CaCO3.

blogfast25 - 20-5-2015 at 12:35

Quote: Originally posted by Dan Vizine  
There are lots of better things to recrystallize than CaCO3.


Yeah, hydrothermal methods aren't easy! ;)

aga - 20-5-2015 at 15:06

Not all "Children's Chalk" is calcium carbonate anymore.

I bought a box and it's all calcium sulphate or hard white stuff that isn't calcium carbonate.