Sciencemadness Discussion Board

Xenon Electronegativity

Darkfire - 4-1-2003 at 15:28

If Xenon is a noble gas how does it have such a high electronegativity of 2.60? It the only noble gas i know of that can form compound such as xenon tetrafloride, how can this be?

CTR

madscientist - 4-1-2003 at 16:00

Electronegativity of Xe is just a figure found by comparing the strength of a Xe-Xe and a F-F single bond to the strength of a Xe-F single bond. 2.6 isn't an especially high electronegativity, by the way.

Darkfire - 4-1-2003 at 23:28

Not high when compared to other elements, but high for a noble gas, which has full orbitals. My question is with full orbitals, how can xenon even form molecules.

CTR

vulture - 5-1-2003 at 12:44

There is another thread where I posted some info about several noble gas compounds.
Electronegativity is an invented value. There are 4 different ways to calculate it which Pauli actually pulled out of his ass.
It can sometimes be useful, but electronegativity is often abused.
Pauli is an authority in the field of chemical bonding btw.

As electronegativity is purely calculated from bonding enthalpy, it doesn't take into account the high amount of energy that is necessary to initiate the reaction.