Sciencemadness Discussion Board

Electrodes

Joe - 24-3-2005 at 16:19

What is the best material to use for electrodes that is commonly available that won't oxidize when used in electrolysis? I've tried stainless steel coated in cadmium(galvanized), and am trying zinc plated bolts currently. I heard nickel is a good one but isn't available locally.

[Edited on 25-3-2005 by Joe]

Dave Angel - 24-3-2005 at 16:50

Hey, it's funny, I've just posted about my electrolysis experiment today in which I mentioned the used of graphite over copper, but it depends on your purpose. I've found that graphite is fairly resistant; in the case of acetate ions it's preferable to copper at least, but it was attacked in an ancient experiment I performed with NaCl solution.

Give it a go though; you may have more luck with your experiment!

One good thing about a graphite electrode is that if it does get attacked, whilst some may go into solution as who-knows-what, most of it tends to flake off as a pile of insoluble rubbish that can be filtered off.

I have just been considering myself that one could go a bit more up-market and visit a jewellers, who may sell scrap noble metals, or better yet be able to craft them into electrodes:

"Can you make them into rods with holes at the top please?" :D

12AX7 - 24-3-2005 at 19:19

Bah, graphite is cheap as heck. Go down to your local welding store and ask for gouging rods, 1/8" to 3/8" dia. or so. Usually copper plated for conductivity (since they are supposed to be passing 50-300 amperes...) but that can be stripped off.

Tim

fishy1 - 1-5-2005 at 09:05

what would you recommed for NAOH electrolysis?

12AX7 - 1-5-2005 at 10:16

To what purpose?

Is NaOH the electrolyte, or are you making it say from NaCl?

Besides graphite of course, stainless seems to work well in NaOH electrolyte. LOL

Tim

neutrino - 1-5-2005 at 10:26

For strong bases, you definitely want nickel. It’s about the only common material that is completely resistant to these things at elevated temperatures. For nickel crucibles, try Cynmar.

Madandcrazy - 17-5-2005 at 07:14

neutrino,

nickel crucibles completely resistant to all these processes ?

Cynmar a chemsource of you ?

neutrino - 17-5-2005 at 12:50

If I understood you, yes and yes.

BromicAcid - 17-5-2005 at 18:09

Which country do you live in, for a good nickel source the indigenous currency can occasionally provide, even in the US some currency still has a high nickel precentage and as such can serve as an electrode in basic mediums.

The_Davster - 17-5-2005 at 18:13

Canadian nickels with the date between 1955 and 1981 are pure nickel.