Sciencemadness Discussion Board

unknown peroxides from cyclic ketones

PsychoPate - 8-11-2002 at 18:32

Are someone know possibilities to synthesize large-molecule-peroxides
by nucleophilic addition of not tested cyclic ketones ?

for examble:
X [CH3(CH2)3CH(C2H5)CH2OOC(CH2)4COOCH2CH(C2H5)(CH2)3CH3] +
X [H2O2] + (acid)-cat =
> {[CH3(CH2)3CH(C2H5)CH2O] X [C(CH2)4CO] X [CH2CH(C2H5)(CH2)3CH3]} >

???

unknown energetic materials

The_Possessed_Stallion - 11-11-2002 at 08:07

This are not basically a peroxide but i don`t open a new topic because of this material.
I suppose this would be exist as a powerful energetic explosive.
You should look at this formula as one.

X { Y [ HOHCHCHCHNO2HOHCHC(NO2)a
HCHNO2HHOHCHCHCHNO2HOHCHCHNO2HC(NO2)b
HHOHCHCHCHNO2HOHCHCHNO2HC(NO2)c
HHOHCHCHCHNO2HOHCHCNO2HC(NO2)d
HHOHCHCHCHNO2HOHCHC(NO2)e
HCNO2HHOHCHCHCHNO2HOHCHC(NO2)f
HCNO2H ] }

not mentioned explosives

total_insane - 15-11-2002 at 04:53

Does anybody hear of

2.2`[oxybis(methylen)bis(hydroxymethyl)]-1,3-propandiolhexanitrate
C10H16N6O13

?
:P:P:P

Krypton - 29-5-2003 at 10:13

I believe the correct product to post
two in one dimension is the octadecanitrate
of a hexaoxo cyclic component of
3,4-dihydroxy-6-hydroxymethylpentamethyleneoxide


>{O[>CHCH(CH2ONO2)OCH(ONO2)CH(ONO2)>]6}>

KABOOOM(pyrojustforfun) - 31-8-2003 at 20:04

there's one exess O (the first O)
correct formula is >{[>CHCH(CH2ONO2)OCH(ONO2)CH(ONO2)>]6}> I know u were joking but all I saw under this thread was nonesense :mad:.