Sciencemadness Discussion Board

Quick Sulfuric acid question

trevasotilo - 25-11-2013 at 07:03

Sulfuric acid can be produced in the laboratory by burning sulfur in air and dissolving the gas produced in a hydrogen peroxide solution.

SO2 + H2O2 → H2SO4

The above is wrong right?

Metacelsus - 25-11-2013 at 07:12

The equation is balanced, and I believe the oxidation will take place, at least to some extent:

http://www.fmcchemicals.com/Portals/chem/Content/Docs/H2O2%2...

Article on oxidation in the gas phase:
https://www.sciencedirect.com/science/article/pii/0004698181...

Galinstan - 25-11-2013 at 07:14

no, im fairly sure the equation is correct as the oxidation numbers for all the elements involved balance :)
Also this should probably be in beginnings

[Edited on 25-11-13 by Galinstan]

blargish - 25-11-2013 at 10:02

Your equation for the reaction is correct. Nitric acid can also be used instead of hydrogen peroxide, and it has the added benefit of giving an indicator when it has all been used up/reduced (no more NO2 gas is evolved). You can then swap out for more nitric acid and have a very efficient synthesis. When using peroxide, you have no such indicator when all of the peroxide has been reduced. Still, peroxide is much easier to come by than nitric acid...

TheChemiKid - 25-11-2013 at 14:59

Here is a nurdrage video on this subject. It i svery well made and relies on this principle.
My advice: If you can, use nitric acid instead of hydrogen peroxide.