Sciencemadness Discussion Board

hexanitroinositol

Trotsky - 17-3-2013 at 00:38

I can find only one reference to this compound on this site, and only a brief mention at that. In addition, I have come across one brief paragraph from the 1930s regarding the simplicity and cheapness off the compound, saying that it was equal to nitroglycerin in properties, except it was a solid and do easier and safer to handle.

There must be some unannounced downside to it or it would have gained greater popularity, I believe.

Has anytime here any experience with the compound?

franklyn - 17-3-2013 at 08:17

It would not be nitro but rather nitrate same nomenclature as for glycerine
a nitro compound of this aliphatic ring would be a cyclohexane variant.

vulture cites two patent references submitted by
Mr. Anonymous , alias Rosco Bodine , here _
www.sciencemadness.org/talk/viewthread.php?tid=890#pid8043

My own contribution , for actual hands on , read the posts following
www.sciencemadness.org/talk/viewthread.php?tid=9201#pid10645...

_________________________________________


Search for Inositol on site here to get more hits.

.

Trotsky - 18-3-2013 at 22:43

Ah, yeah, that's how it was referred to in the document I read. That explains why I didn't see those threads when I searched.

Thanks!

AndersHoveland - 18-3-2013 at 22:56

Quote: Originally posted by Trotsky  
There must be some unannounced downside to it or it would have gained greater popularity

Perhaps low yields and impurities? These long chain sugar alcohols tend to be vulnerable to destructive oxidation. The initial product from the nitration might contain some partially nitrated oxidation products. The only way to purify the product would be crystallization (not really a feasible industrial route, for obvious reasons).

For those of you wanting more chemistry details, the central CH group in nitroglycerin is also vulnerable to oxidation, but if it does get oxidized it opens up the entire molecule to immediate oxidative destruction. Usually any by-products that are only partially oxidized are very soluble in the acids, so do not contaminate the product.

[Edited on 19-3-2013 by AndersHoveland]