Sciencemadness Discussion Board

Lithium periodate

nezza - 18-3-2012 at 07:05

This is a random question, but how soluble in water is lithium periodate ?. I can't find the answer anywhere.

zoombafu - 18-3-2012 at 08:49

I found on a couple msds' that it is water soluble, but it didn't say a specific g/mL.

Hexavalent - 18-3-2012 at 09:52

Here is some data for potassium periodate in g/100ml, I would expect the lithium salt to be slightly higher.

0°C 0.17
10°C 0.28
20°C 0.42
30°C 0.65
40°C 1
50°C
60°C 2.1
70°C
80°C 4.4
90°C 5.9


This is from Wikipedia's huge solubility table of various compounds, so I can't be certain on reliability.


[Edited on 18-3-2012 by Hexavalent]

[Edited on 18-3-2012 by Hexavalent]

barley81 - 18-3-2012 at 10:38

Sodium metaperiodate (NaIO<sub>4</sub>;)is much more soluble than potassium metaperiodate (80g/L at 20C). Lithium should probably follow the trend and be even more soluble than sodium metaperiodate (greater than 80g/L)

Sodium orthoperiodate (Na<sub>5</sub>IO<sub>6</sub>;) is much less soluble than the metaperiodate.

[Edited on 18-3-2012 by barley81]

phlogiston - 18-3-2012 at 14:07

Quote:
Here is some data for potassium periodate in g/100ml, I would expect the lithium salt to be slightly higher.


It might be a lot higher.
If the trend for the perchlorate salts hold for the periodate:
Potassium perchlorate is only sparingly soluble (1.5 g/100ml at 25 deg C)
While lithium perchlorate is very soluble (56.1 g/100ml at room temperature)
Sodium perchlorate is also very soluble: 209g / 100 ml

Lithium chlorate must be one of the most soluble salts in existence BTW, 372 g/100ml at room temp and an incredible 777 g/100 ml at 60 deg C!



[Edited on 18-3-2012 by phlogiston]

Hexavalent - 19-3-2012 at 11:20

Wow . . .really? I know that urea also has a ridiculous solubility, just done a recrystallization and couldn't believe my eyes when I looked up the solubility data!:)