Sciencemadness Discussion Board

preparation of aluminum chloride

neptunium - 13-12-2011 at 07:37

everyone knows how usefull aluminum chloride (dry) can be for all type of chlorination reaction...but water destroys it,
it can be made from its element in a dry environment ...
ok now what about aluminum powder in suspention in carbon tetrachloride (or chloroform) with chlorine bubbling in?
could the same be done to prepare AlBr3? and the iodide?

could methylen chloride be the solvent ? has anyone thought about it before? sorry if i missed a post about it

Neil - 13-12-2011 at 07:40

Lots of threads! The best involves a BBQ, I won't spoil the surprise for you by posting a direct link. Heads up if you post a question to which has been asked a lot - you'll get stone walled and beaten with the search engine. ;)

[Edited on 13-12-2011 by Neil]

neptunium - 13-12-2011 at 07:41

well thanks for the heads up...

Neil - 13-12-2011 at 07:45

http://www.sciencemadness.org/talk/viewthread.php?tid=14224

http://www.sciencemadness.org/talk/viewthread.php?tid=14371

No problem, welcome to the forum.

neptunium - 13-12-2011 at 08:00

lol! love it ....thanks

blogfast25 - 13-12-2011 at 09:42

For small quantities this established anhydrous AlCl3 synth. seems very doable:

http://www.sciencemadness.org/talk/viewthread.php?tid=14111&...

(*.pdf link in the post by 'rrkss')