Sciencemadness Discussion Board

Polydiallyldimethylammoniumn chloride tidbit

Morgan - 24-3-2011 at 07:56

http://www.physorg.com/news/2011-03-cheap-catalyst-easy.html

watson.fawkes - 24-3-2011 at 15:58

From the article:
Quote:
Dai and research associates Shuangyin Wang and Dingshan Yu found that by simply soaking carbon nanotubes in a water solution of the polymer polydiallyldimethylammoniumn chloride for a couple of hours, the polymer coats the nanotube surface and pulls an electron partially from the carbon, creating a net positive charge.

They placed the nanotubes on the cathode of an alkaline fuel cell. There, the charged material acts as a catalyst for the oxygen-reduction reaction that produces electricity while electrochemically combining hydrogen and oxygen.
As I understand this, it seems they've made some sort of radial electret, with a positive charge on the inside of the tube and a negative one out the outside. The negative outside charge would act similarly to an electron-donating group. Attached to a cathode, it donates and keeps on donating, creating a not just a current path, but one that alters electronic distribution at its surface.

Ideas?