LL8 from Dr. Liptakov

Due to the unexpected properties of the examinate substance, I would like to start a new thread on his theme. And also because almost nothing but safe and comfortable initiation is addressed in energetic materials.The substance was gived working name LL8. Because CHP is closest to the new substance, it is used for comparison. Just like the notorious ETN.

Basic results are on two pictures. Output segment with high density was set on 400 mg. Starting DDT segment with low density set on 250 mg. Other space is filled classic BP to full height.
Density for output segments ETN in steel cavity 6/8 x 50 mm. = 1.75g /cm3 + - 0,03 g/cm3.
Density for output segment LL8 in steel cavity 6/8 x 50 mm. = 1.87g /cm3 + - 0,03 g/ cm3.
Density for output segment CHP in steel cavity 6/8 x 50 mm. = 1,56 g /cm3 + - 0,03 g/ cm3.
Density of LL8 / 250g which is use a like primary for all tests 1,4 - 1,6 g/cm3.
BP is pressed on cca 20 - 30 Kg.








Control measurement on pic.7,8 with exact output edges.




Differences between LL8 / CHP

1) LL8 is demonstrably more brizantely than CHP.
2) LL8 not releasing NH3 gas from molecule, is without smell.
3) LL8 can be mixed with metals and other EMs with less doubt.
4) LL8 has preparation procedure without ammonia water.

Properties which are same or similar for LL8 and CHP:

5) No hygroscopicity as free heap on air within days at laboratory huminidity.
6) Primarily - secondary energetic material.
7) Detonator must have metal cavity. (Soft cavities are in exam)
8) Friction sensitivity similar (exact values later, subjectively without accident)
9) Impact sensitivity similar (exact values later)
10) Burning on air only, without DDT, with speed similarly as quality BP
11) Not sensitive for over-pressing dead


Disadvantage LL8 against CHP:

1) Basic precursor HClO4 is usually expensive or unavailable. (Preparation HClO4 from NH4ClO4 available on LL pages YouTube)
2) Preparation Cu(ClO4)2 can be difficulty against preparation TACP.
3) Other method preparation Cu(ClO4)2 from else perchlorates salts not found. Experienced chemists can complement it.


Reagents for preparation:

Cu(ClO4)2 (hexahydrate)........2,4g
Hexamine ...............................0,6g
Ethanol commerce grade .......1,5g
H2O distiled.............................0,5g

Preparation:
Mixing CuP and hexamine on inert surface at 20 C with Ethanol and distil water.




Make the fine slurry. Pour slurry on inert surface 70 - 80 C. Evaporate EtOH+H2O and make the grain using a 1x1 mm sieve. Notice: During evaporate arises gas which irritate eyes and nose, same effect a like at second glue. Ventilation recommended.
Drying 20 minute on inert surface at 50 - 80 C.





Final color after drying on picture:





Cu(ClO4)2 can be prepared, Method 1:

Heate solution CuO + HClO4 of 40% conc. with 2O% exces CuO for 80 C. Wait on pH 4. Neutralize by drop of ammonia water for pH near neutral. Cooling on zero C. Can arised small amount NH4ClO4 which crystallize firstly. Separate exces CuO+NH4ClO4 on filter. Evaporate (blue transparent) solution at 100 C on inert plate. (Tested,works in det.)

Method 2:

Heate solution of HClO4 (30 - 40% conc.) at 20 C and add CuCO3 in small portions. Arises CO2. Add exces 20% CuCO3 until to zero bubble CO2. At 20C.
Heate on 80C and wait on pH 4. Neutralize by drop of ammonia water for pH near neutral. Cooling on zero C. Arise small amount NH4ClO4 which crystallized firstly. Separe exces CuCO3+NH4ClO4 on paper filter. Evaporate water from solution at 100 C on inert plate.(prepared,works in det.)

Solubility NH4CLO4 11,5g in 100g H2O at zero C.
Solubility Cu(ClO4)2 . 6H2O...146g in 100g H2O at 30C, melting point 82 C as hexahydrate.

Tested also in different ratios, results on witness plate: (without picture)
CuP : HEX
50 : 50 = failed, flat steel
70 : 30 = failed, slight bending of steel only
80 : 20 = best results, bigest hole
85 : 15 = good results, but smaller hole


Test for stability LL8 in detonator. One detonator filled before 14 days and storage. Second detonator filled after 14 days, from else batch, but with two identical design and conditions. Result on pic9.




Detail preparation LL8 and basic properties published from today without the right to a reward or patenting. For all researchers of science madness free.

Dr. Liptakov.......

Quote: Originally posted by Laboratory of Liptakov

The Cu (ClO4) 2 used was found to still contain the HClO4 from which it was made. The residual acid, together with Cu (ClO4) 2 together with hexamine, to form hexamine copper diperchlorate + another unknown substance. The residual acid is evaporated in a pan at 80 DEG C. and the mixture becomes non-hygroscopic in this step. Therefore, a pungent gas is smelled during evaporation. I estimate that the whole process will not be possible without HClO4. Of course, it is possible to mix everything with everything and look for another 10 different similar mixtures. However, in such a case, the work (for free) will take an infinite amount of time. The above substance works. And it has unexpectedly good properties as described. The development of similar, similarly powerful energy substances costs millions in commercial laboratories. And after, all the information about them will end up in the military government vault.

Quote: Originally posted by MineMan

Quote: Originally posted by Laboratory of Liptakov   The Cu (ClO4) 2 used was found to still contain the HClO4 from which it was made. The residual acid, together with Cu (ClO4) 2 together with hexamine, to form hexamine copper diperchlorate + another unknown substance. The residual acid is evaporated in a pan at 80 DEG C. and the mixture becomes non-hygroscopic in this step. Therefore, a pungent gas is smelled during evaporation. I estimate that the whole process will not be possible without HClO4. Of course, it is possible to mix everything with everything and look for another 10 different similar mixtures. However, in such a case, the work (for free) will take an infinite amount of time. The above substance works. And it has unexpectedly good properties as described. The development of similar, similarly powerful energy substances costs millions in commercial laboratories. And after, all the information about them will end up in the military government vault. I hate doing this because it seems like I am minimizing your work! I am trying to take out the hazardous and excotic chemicals such as perchloric acid. What you discovered is amazing! I do wonder. What if you mixed ammonium perchlorate, copper ammonia, hexamine and water together.

Elemental Phosphorus: Thanks .... When I saw the first holes from this substance,
I couldn't believe my eyes. Some were as large as those of ETN. Some even bigger. With sharp bottom edges. More accurate measurements have shown that it is not as strong as ETN. The current estimate is approximately 90-95% ETN brisance. During further tests, it was found that the presence of ethanol was not a condition. Just 2g of distilled water is needed to dissolve. Precipitation of fine powder occurs immediately after mixing CuP and hexamine.
Water-insoluble turquoise particles. However, the process also requires heating in a thin layer on stainless steel. Until completely dry. Or another inert surface. It often happened that the porridge baked in the pan. So I used a steel scraper. At least 30 times. The surface was heated to 80 C at that moment. And yet nothing happened. Shield, of course, thick gloves, earplugs. And always removed from the area a small amount. And closed aside. And then the scratching continued. Still no incident.
And also thanks for the procedure for HClO4. It looks easy and is mainly described in detail.

The observation of filter paper burning led to the preparation of a new substance. Which burned so energetically that he blew out any lighter flame. It was as if a stream of gas with a pressure of several atmospheres was coming out of the paper. Such behavior has not been observed with any other perchlorate. Sharp blue flame in one direction. Like an autogenous flame. So if the paper burns like this, what will hexamine do?

MineMan...Perchloric acid not smell, not fuming. Is it a like water. From my experience is it most friendly acid between others....



[Edited on 9-1-2022 by Laboratory of Liptakov]

Quote: Originally posted by Laboratory of Liptakov

Elemental Phosphorus: Thanks .... When I saw the first holes from this substance, I couldn't believe my eyes. Some were as large as those of ETN. Some even bigger. With sharp bottom edges. More accurate measurements have shown that it is not as strong as ETN. The current estimate is approximately 90-95% ETN brisance. During further tests, it was found that the presence of ethanol was not a condition. Just 2g of distilled water is needed to dissolve. Precipitation of fine powder occurs immediately after mixing CuP and hexamine. Water-insoluble turquoise particles. However, the process also requires heating in a thin layer on stainless steel. Until completely dry. Or another inert surface. It often happened that the porridge baked in the pan. So I used a steel scraper. At least 30 times. The surface was heated to 80 C at that moment. And yet nothing happened. Shield, of course, thick gloves, earplugs. And always removed from the area a small amount. And closed aside. And then the scratching continued. Still no incident. And also thanks for the procedure for HClO4. It looks easy and is mainly described in detail. The observation of filter paper burning led to the preparation of a new substance. Which burned so energetically that he blew out any lighter flame. It was as if a stream of gas with a pressure of several atmospheres was coming out of the paper. Such behavior has not been observed with any other perchlorate. Sharp blue flame in one direction. Like an autogenous flame. So if the paper burns like this, what will hexamine do? MineMan...Perchloric acid not smell, not fuming. Is it a like water. From my experience is it most friendly acid between others.... What percentage is needed to add a perchlorate ion to hexamine, melamine, creatine and other materials. Perchlorate seem perfect for DDT. For aminoguanidine you can do meta thesis, tho I don’t know why. Does anyone have a discord name who could explain these things further? [Edited on 9-1-2022 by Laboratory of Liptakov]

In addition, copper perchlorate is fun. I mentioned burning filter paper. Of course, the test paper filter is very hygroscopic. It contains XX percent Cu (ClO4) 2. 6H2O. Which in itself hygroscopic pretty enough. But it stays dry for 1 minute. When you place such paper on an anvil and strike it with a hammer, it behaves the same as paper with a drop of nitroglycerin. Attention! Small pieces of paper act like micrometeorites. They get stuck under the skin. If you don't have gloves. ETN heated on foil has the same effect, thus flying micrometeorites. According to ongoing research, Cu (ClO4) 2 appears to form high-performance energy mixtures with almost any fuel. Solid or liquid. CuP is very high soluble in ethanol, good soluble in acetone, insoluble in nitromethane....

LL8 impact test

I have one more funny story from the shoot. Impact sensitivity has only been tested once. I assumed that the gases would escape down both sides around the steel brick. The same amount as in the picture was used. The guide tube will have to be made of something stronger ....



LL8 with the addition of 4% Aluminum bright gives holes with an identical diameter as ETN. And plus, LL8 has more precise and sharper edges on the output side than ETN. Thats mark of high detonatiom pressure for LL8.





[Edited on 10-1-2022 by Laboratory of Liptakov]

Compared to distilled water, the pH paper shows a slight acidity. But it is not the acid content that would cause a significant change in the properties of the final product. This is my current assumption. Furthermore, I do not know how to produce absolutely neutral Cu (ClO4) 2.

LL8

According tests above is LL8 really brizantely than CHP. NHN was not tested at same conditions. The assumption is that NHN will have a lower brisance than LL8.
LL8 is very insensitive to friction. Withstands scraping from a hot pan (50 - 80 C) with a steel plate. 30 batches scratched without incident.
On impact is sensitive similarly a like heads pieces from safety matches.

Cu(ClO4)2 is Copper perchlorate. Tetraamine copper perchlorate is (TACP) : [Cu(NH3)4](ClO4)2. From TACP during decopmose is impossible prepare Cu(ClO4)2
From TACP + HCLO4 is impossible prepare Cu(ClO4)2.
Is necessary classic method HClO4 + CuCO3 = Cu(ClO4)2 + H2O + CO2.

Videos: My information is too accurate. In the case of LL8, almost strategic. If I make a video with a detailed procedure, (and properties) I will have problems with the authorities.

Quote: Originally posted by Laboratory of Liptakov

According tests above is LL8 really brizantely than CHP. NHN was not tested at same conditions. The assumption is that NHN will have a lower brisance than LL8. LL8 is very insensitive to friction. Withstands scraping from a hot pan (50 - 80 C) with a steel plate. 30 batches scratched without incident. On impact is sensitive similarly a like heads pieces from safety matches. Cu(ClO4)2 is Copper perchlorate. Tetraamine copper perchlorate is (TACP) : [Cu(NH3)4](ClO4)2. From TACP during decopmose is impossible prepare Cu(ClO4)2 From TACP + HCLO4 is impossible prepare Cu(ClO4)2. Is necessary classic method HClO4 + CuCO3 = Cu(ClO4)2 + H2O + CO2. Videos: My information is too accurate. In the case of LL8, almost strategic. If I make a video with a detailed procedure, (and properties) I will have problems with the authorities.

LL8

//From TACP + HCLO4 is it impossible to prepare Cu(CIO4)2 or do you mean it is possible?// Is it Impossible.

For prepare HClO4 you need NH4ClO4, HNO3, HCl. Is it method from Horace C. Adams 1925. Described here above.
You can try dry matchhead at 80 C during 30 minute. On hotpan. And after you can use hammer agains the vise. Or similary. And you see the sensitivity on impact. Without any phosphorus.

NHN is sure more stable than CHP. NHN is good material. But is it work with hydrazine. From this reason I leaved the preparation of NHN.
On flame is CHP and LL8 same sensitive a like NHN.

For exact measurement you need own falling hammer. Is it basic equipment of researcher....

Yes, you understand that correctly. No booster is needed. LL8 is not just a primary compound. It is primary - secondary filling consisting of only one substance. In a cavity, a single substance (eg LL8 or CHP) differs only in density.
1) With a low density (approx. 1.0 - 1.4 g / cm3) it plays the role of a primary substance. A resistance bridge is placed in this density. This is where the transition from combustion to detonation (DDT) occurs at a lower rate. For example zero up to 3000m / s.
However, this detonation rate is sufficient to initiate the detonation of the output segment. In which DDT would be (due to its high density) difficult or impossible or unreliable.
2) The output segment is of the same composition, but with a higher density (1.7 - 1.9) and therefore has a higher detonation rate = pressure. The outlet pressure is so strong that it can initiate EM based on AN. This is true for both CHP and LL8 substances.
NHN has a detonation pressure 20,8 GPa
CHP has a detonation pressure 22 - 25 GPa.
LL8 has a detonation pressure 27 - 29 GPa.
ETN has a detonation pressure 30 GPa

Another advantage: If there is only one substance, it cannot eat each other.

[Edited on 13-1-2022 by Laboratory of Liptakov]

Thanks for offer of aminoguanidine. But I am lazy prepare AG, especially, when hexamine (+CuP) give very good pressure. Almost same as ETN.
Any way, interesting reccomendation is it for future.
Yes, Lithium Perchlorate will tested soon.

In my opinion, Cu (ClO4) 2 is an unexplored substance. Respectively as oxidizer with various fuels. Copper holds the molecule together only very weakly, compared to other metals. Copper provide weak hold in a lot elses molecules. For example Copper acetylide. Just a guess, nothing more.
Thanks for the recognition, MineMan ...



[Edited on 13-1-2022 by Laboratory of Liptakov]

S.C. Wack:
Links are relevants. Only metals (Zn, Ni, Mn) are different. Is it almost CHP. Thus perchlorate metal complex + hexamine + Ammonium perchlorate. Thus TACP 88% // [Cu(NH3)4](ClO4)2 // + hexamine 6% + AP 6%. It is popular CHP. Thaks for links. Cu(OH)2 + AP + Hexamine under ammonia water sure create CHP. Is necessary only set exact ratios, temperature, concentrations and time for boiling, I estimate. For all compounds. Easily is use dry TACP, dry hexamine , dry AP. And mixed under a few drops of NH4OH aq. Heated on 80C and dry. This is classic prepare CHP. Same method with Ni in molecule, not works, no holes. Tested repeatedly. Zn comlex was not tested.

B(a)P: Thanks for the acknowledgment, I appreciate it ...



[Edited on 14-1-2022 by Laboratory of Liptakov]

Quote: Originally posted by yobbo II

Cannot Copper Perchlorate be prepared using (say) Calcium Perchlorate and Copper Sulphate. The Calcium Sulphate will PPT leaving Cu Perk. Ca Perk. can by had my electrolysis. Barium Perchlorate, Lead Perchlorate and others could be used. Yob

Cu8 and Li8

Due to the discovery of another substance based on perchlorate and hexamine, I enclose a table. I renamed LL8 on Cu8 . The new primary-secondary substance is referred to as Li8 as a communication abbreviation. The preparation of Li8 is the same as for Cu8. Lithium perchlorate with hexamine has been shown to give excellent results. And it is even non hygroscopic in laboratory conditions, which is quite surprising. Same as Ba, K, Cu, NH4. Sodium perchlorate is extremely hygroscopic when mixed with hexamine. The disadvantage of Li8 is can be the availability or price of LiClO4 . 0 - 3 H2O in factory quality.
Interestingly, the preparation of Li8 is free of pungent gas during the evaporation of water and bound water. (Unlike Cu8 where is prepapration unpleasant) In addition, at Li8 the stainless steel surface can be heated up to 150 Celsius during the final evaporation. Without change of color or final properties. Absolutely dry Li8 burns with difficulty, purple but it always ignites in the cavity from the wire. Post-explosive gases are odorless at Li8. Unlike Cu8. Conclusion: Li8 is comfortable primary-secondary substance with 2x less impact sensitivity than CHP and Cu8. For Li8 was used factory quality LiClO4 .2H2O without acidity in crytstalls. In table are next tested perchlorate mixtures, which are unusable as primary - secondary compounds. Lithium perchlorate can be manufactured by reaction of sodium perchlorate (relatively easy prepare) with lithium chloride which can be cheap and available.

Thus, the preparation of LiClO4 may ultimately be easier than the preparation of Cu (ClO4) 2, or the preparation of NH4ClO4 and the subsequent production of TACP and the subsequent production of CHP. In addition, the final Li8 product is less sensitive to stimuli during preparation and handling and its detonation pressure is the highest of these perchlorate mixtures.






[Edited on 18-1-2022 by Laboratory of Liptakov]

Li8

Burning Li8 on alu foil

Li8

LiClO4 without water has OB + 60.15 available values. Hexamine - 205.41. Utility counter show ratio 77 : 23 with OB - 0,929. But was used
LiClO4 x 2H2O. Therefore was added 3%. Thus ratio 80:20. Also line of powder in alu foil V shape long 7 cm show best speed at ratio 80:20. Was pressed a new cylinder. Height 1,240 cm in diameter 8,00 mm. Pressed in 4 steps in vise on maximal density while maintaining the diameter of the cavity 8 mm. Density of 1000 mg in this cavity
should by 1.605 g/ cc. It can't be more in amateur conditions. 4x twisting the rod from cavity is Russian roulette.
Of course, the ratios for Li8 and Cu8 can be calculated more accurately during further research. Urazine a aminoguanidine is research of Microtek.
I have only 2 hands.





[Edited on 19-1-2022 by Laboratory of Liptakov]

Quote: Originally posted by Laboratory of Liptakov

Exactly. An ordinary one table with results like here above will take up all free time for the whole week. For provide results free. If such a job were done by a professional laboratory, results in table would be cost thousands of dollars.

Probably ten thousand. But don’t worry LL, when I hit the big bucks you can work in my lab and do this professional all the chemicals you want, including ethanol and DMT!

Shouldn’t the density be higher still, for example 2.1g/cc? Anyway to drive the water from the Li perchlorate? In fact it’s not a dry mix, it’s a ligand , water should be removed? Tho I have no knowledge. Burning spending unconfined does not relate to Detonation performance we know.

Li8 Cu8

Is it weird, the low density. 2,42 80% + 1,33 20% should by 2,20g / cm3...

Quote: Originally posted by Laboratory of Liptakov

Is it weird, the low density. 2,42 80% + 1,33 20% should by 2,20g / cm3...

Li8 and Cu8

For sure was tested mixture Li8 + Cu8 50:50. Brisance is bigger than CHP, but weaker than at others on picture. Pretty surprisingly is, that Li8 is difficult fired as free heap. During a 2 second goes out after ignition. But detonation pressure of Li8 is the highest of all examined mixtures. I don't know of any other primary mixture (or primary-secondary) that will go out on its own if you ignite it. For reliable DDT of course Li8 require solid metal cavity. From unknown reason is surface of crater from Li8 pretty smooth. Against all others. And after test was this crater as only one clear, without black residuum. Explosive fumes were also odorless only at Li8. But that has been mentioned before.
List in brizance order:
ETN ...........5,34 mm
Li8..............4,17 mm
Cu8............4,10 mm
Li8/Cu8......3,67 mm
CHP...........3,46 mm

There are hundreds of different mixtures with hexamine. Hundreds of old patents on similar theme. But accurate test is crucial. And importantly, don't be afraid to mix it. And to press it. Only then will the results come....

Attachment: Kruszynski2015_Article_OnTheCoordinationBehaviourOfTh.pdf (971kB)
This file has been downloaded 541 times

Li8 - Lithex

There is no mention of energy properties in the attached Kruszynski link. This link was found back only after verifying the energy properties of Li8. It can be used to form said ligand.
Similar method of preparation: 80% LiClO4 dihydrate x 2 H2O + 20% hexamine. Dissolve 4 g of LiP + 1 g of hexamine in 5.2 g of dH2O. Heat to boiling point and cool in an ice bath. The solution almost "solidifies". The resulting slurry is filtered off. Fine needle crystals remain on the filter. Color and consistency like snow. Vacuum suction is a condition. The crystals thus formed are transferred to a stainless steel pan. The temperature is adjusted to 80 DEG C. At this temperature, the crystals soon dissolve, a liquid is formed. The liquid is a dihydrate-ligand. When the temperature is raised to 100 C, the dihydrate dries. And it becomes a monohydrate - a ligand. When the temperature is raised to 120 ° C, the monohydrate dissolves again. When the temperature is raised to 150 C, the monohydrate dries. The material requires constant friction with a steel plate in all steps. The preparation of Li8 is not for the faint of heart. It requires strong nerves. After drying at 150 DEG C., the temperature is reduced to 80 DEG C. And at this 80 C is filled material into the cavity. Li8 anhydride was shown to be hygroscopic. Arised monohydrate overnight, at room conditions. Monohydrate looks a like dry powder. But at increase temperature on 120 C created solution. LiClO4 can be trihydrate, dihydrate, monohydrate, anhydride. Same behavior are for Li8. Next method for preparation Li8 is create anhydride of LiClO4. And after mixing 77 % + 23% of hexamine. Add dH20 to full dissolve at 100 C. And increase temperature on 150 C to total dry powder. I recommend working with an amount of about 1 gram.
Gloves, shield, ear plugs. First described method with filtering provide better results for finally brisance.....

Lithex

Quote: Originally posted by Laboratory of Liptakov

For sure was tested mixture Li8 + Cu8 50:50. Brisance is bigger than CHP, but weaker than at others on picture. Pretty surprisingly is, that Li8 is difficult fired as free heap. During a 2 second goes out after ignition. But detonation pressure of Li8 is the highest of all examined mixtures. I don't know of any other primary mixture (or primary-secondary) that will go out on its own if you ignite it. For reliable DDT of course Li8 require solid metal cavity. From unknown reason is surface of crater from Li8 pretty smooth. Against all others. And after test was this crater as only one clear, without black residuum. Explosive fumes were also odorless only at Li8. But that has been mentioned before. List in brizance order: ETN ...........5,34 mm Li8..............4,17 mm Cu8............4,10 mm Li8/Cu8......3,67 mm CHP...........3,46 mm

Yes there are primary/secondary mixtures that can DDT and self extinguish… they are the holy grail because of safety, a stray spark unconfined does nothing. Congress LL, this is a big invention )). I am genuinely jealous, I wish it were me instead, that’s how big this is

Lithex

No need to be jealous. Drying of the Li8 mixture at 150 C could end in an explosion. Fortunately, this did not happen. Drying and scraping and crushing at 150 C were repeated at least 30 times. No accident. Fortunately. But not everyone wants to be an astronaut. Because it's a very risky way up there. A professional chemist would never heat a perchlorate ligand with hexamine to 150 C. On a metal surface. Plus no thermometer. The temperature is only estimated. But it must be such that the crystalline barrier is overcome and the ligand gives up all the water. This is certainly possible at lower temperatures in a vacuum. Maybe only at 50 C. This ligand has been known for many years. But no one dared to deprive him of water. Either way, vacuum or classic. This happened for the first time 1.1. 2022. At the temperature at which you fry the eggs. Until it turns black.
A lower temperature is used for Cu8, estimated at 80 - 100 Celsius. But pungent gas is produced, which is uncomfortable. There is basically nothing to feel about Li8. You just have to pray. And occasionally set the pan and cool a little. Especially when crushing larger agglomerates 2x2 mm. For example, at 100 Celsius. And then increase again to 150 C for drying. And repeat the whole procedure until a fine powder is formed. Which can easily get rid of the last remnants of water. The grain must be almost like powder, ie less than 0.1 mm. A well-dried pile of 100 mg burns whole, without residue. Slowly, but it burns. In aluminum foil V-shaped closure, it burns quite quickly, about 10 - 15 cm / s. Another thing: Few people have LiClO4 to do such an experiment at all. It is pretty expensive chemical. 100g over 100 Dollars. This dramatically reduces the likelihood that someone will try or have tried it before. Like almost all inventions, it is usually a more coincindences together. No need to envy, be jealous.
It was a coincidence. And nothing bad happened....

Lithium nitrate maybe will work. You can try it. Or someone. Also sodium perchlorate provide interesting properties. In table is writte zero. But not is exact truth. NaP + hexamine ligand also can detonate as DDT substance in solid cavity. But his power is weak. Also sometimes worked, sometimes not worked. Shortly is unreliable. Yet. NaP is easily available
and maybe will work with ETN in one solid cavity. In some ratio. Also with adding alu powder. Or small % diethyleneglycol.
Because NaP + DEG is powerful EM. But not primary, is it insensitive secondary. In parts: 75 NaP + 25 DEG + 5 - 15 H2O. Maybe without water, but with hexamine + DEG (small amount about 1 -5 % I estimate) It will works. It was not tested....
NaP I see a like interest way for research. Is cheap, can create ligand with hexamine. Maybe from it some will.

--------------I specify the temperature for drying Li8 to anhydrite. The minimum is 150 C, the maximum 165 C.---------------

Another interesting fact is that there is no need to add water when mixing LiP + Hexamin. If LiP dihydrate is used, simply strew both components onto the pan. Internal water from LiP will take care of dissolution. The dihydrate therefore serves as a fairly accurate thermometer for measuring surface temperature. And it shows the minimum temperature required for mixing.The performance of such a mixture after drying is the same (same holes) and the preparation is faster. As soon as the dihydrate crystals start to melt, the heating is stopped. And at this temperature, mixing and drying are continued.
During 10 - 15 minute is done. Arise very fine white powder. Li8 is more white than method with adding water. Used ratio 2,98 LiP x 2 H2O + 0,69 hex x 0 H2O.


[Edited on 25-1-2022 by Laboratory of Liptakov]

Quote: Originally posted by Laboratory of Liptakov

There are hundreds of different mixtures with hexamine. Hundreds of old patents on similar theme.

Quote: Originally posted by Laboratory of Liptakov

Another thing: Few people have LiClO4 to do such an experiment at all. It is pretty expensive chemical. 100g over 100 Dollars. This dramatically reduces the likelihood that someone will try or have tried it before. Like almost all inventions, it is usually a more coincindences together.

Quote: Originally posted by Laboratory of Liptakov

In Kruzsynski (link) was tested a lot exotic metals. But only Lithium and Sodium created ligand.

Lesson: Lab Depot still more dramatically reduces the likelihood that someone will try make LiClO4....
Maybe will better HClO4 from NH4ClO4/HNO3/HCl. In method Horace C. Adams. And then HClO4 + Li (or LiOH)


[Edited on 25-1-2022 by Laboratory of Liptakov]

Quote: Originally posted by S.C. Wack

"Lab Depot" charges $63.60 (not including $19 shipping) for 25 g LiCl...it's easily made even without the acid, from LiCl and the Na salt (even starting from HTH). It's mentioned in that airbag patent.

Lithex preparation

Good links, thanks Herr Haber....


LiCl https://onyxmet.com/index.php?route=product/product&path...

HClO4 https://chemcraft.su/product/25786

LiClO4 https://chemcraft.su/product/23226 19 USD / 100g very cheap

NaClO4 https://chemcraft.su/product/25565

hexamine https://chemcraft.su/product/25713




Maybe this should by works.


Solubility compounds in 100g acetone:
LiCl ................1,2g
NaClO4.........52g
LiClO4.........137g
NaCl............ 0,000042g
I estimate, that double recrystallization provide pretty pure LiClO4.
Better of course will buy directly LiClO4 by 19 USD





[Edited on 27-1-2022 by Laboratory of Liptakov]

Quote: Originally posted by Herr Haber

Meanwhile in other shops...

Every hobby costs something. For example, aircraft modeling, drones, RC planes and the like cost about 5x to 10x as much as unit-level research of up to tens of grams in the field of chemistry. So that one can have fun entires days. My life experience shows that chemistry is one of the cheapest hobbies ever...

Lithex

The molecular structure of Cu8 is still a mystery. Because it is prepared from slightly acidic Cu (ClO4) 2. After the reaction, the acidity decreases because an acid-base reaction occurs between hexamine and HClO4. Similar to preparing hexamine diperchlorate.

Acidity in Cu8 (LL8) is not some horrible. But is it product of alchemy yet.
Li8, ie Lithex, looks more promising. Pure neutral LiClO4 is used and the Lithex structure will almost certainly be more stable. Just because it can withstand an hour of heating at 150 C.
There are certainly dozens of mixtures with calcium, nitrate and who knows what else. Maybe some from them will works.
But this fiber deals with functional and tested mixtures, especially based on LiClO4.

Quote: Originally posted by Herr Haber

Quote: Originally posted by S.C. Wack   "Lab Depot" charges $63.60 (not including $19 shipping) for 25 g LiCl...it's easily made even without the acid, from LiCl and the Na salt (even starting from HTH). It's mentioned in that airbag patent. Meanwhile in other shops... 5.48 Euros for 25 grams of the perchlorate from Chemcraft. 500 grams for 73 Eu. They also have Li metal and HCLO4 for those who like to make everything from scratch. 10 grams for 5 Euros from Onyxmet. Best for last: LiCl x H2O for 70 Euros a kilo (compared with the 63$ for 25 grams from Lab Direct!) These businesses are a huuuge opportunity for the researcher with little needs and little means.

Quote: Originally posted by Laboratory of Liptakov

Good links, thanks Herr Haber.... LiCl https://onyxmet.com/index.php?route=product/product&path... HClO4 https://chemcraft.su/product/25786 LiClO4 https://chemcraft.su/product/23226 19 USD / 100g very cheap NaClO4 https://chemcraft.su/product/25565 hexamine https://chemcraft.su/product/25713 Maybe this should by works. Solubility compounds in 100g acetone: LiCl ................1,2g NaClO4.........52g LiClO4.........137g NaCl............ 0,000042g I estimate, that double recrystallization provide pretty pure LiClO4. Better of course will buy directly LiClO4 by 19 USD [Edited on 27-1-2022 by Laboratory of Liptakov]

This is comedy gold right here ))

Quote: Originally posted by Laboratory of Liptakov

LiClO4 is proving to be a promising oxidant. For example, LiClO4 anhydride 70% + diethylene glycol (DEG) 30% provides an interesting energy substance. This substance has a melting point of 70 Celsius. In the liquid state, it is sensitive to impact, similar to nitroglycerin. And it gives similarly loud blows. But once it solidifies, it is impossible to detonate the mixture. Even with a strong hammer blow, there is no detonation. The mixture can be heated to 165 Celsius for a long time without changing the properties. It can be allowed to solidify and reheat. It will most likely be hygroscopic which is difficult to detect. On V-shaped aluminum foil burns with an effective, regular red-violet flame. No jets and irregularities in burning. But speed of burning is relatively high. This could be an interesting alternative for small rocket engines. In the liquid state, the viscosity is like a thin oil. This would allow casting at low temperature. Due to the lightness of Lithium, such a mixture could have a high specific impulse. The disadvantage will be the price of such a composition. A mixture of LiClO4 + DEG as base + Alu powder + hexamine or another similar composition based on LiP + DEG is also possible. Not examined.

LiDEG

Of course zirconium could be added… but if sensitivity is that of NG mineman scared.......
Sensitivity is high only over 70 C as liquid.
But if it worked (with unknown ingredients under 70C), casting into the cavity would be possible without pressing. LiDEG will be further investigated.

Further trials have shown that Lithex is pretty resistant. Stress test: Lithex was dissolved in a concentrated solution of NH4OH 25% aq for 24 hours 1g / 10g. The solution was then poured onto a pan and dried at 165 ° C. The temperature was maintained at 120 ° C for 2 hours. Its properties did not change. The resulting hole in the 2 mm sheet is still 7.8 - 8 mm. Under standard conditions of the whole set, of course.

Quote: Originally posted by MineMan

Does chemcraft ship world wide.

Quote: Originally posted by B(a)P

Quote: Originally posted by MineMan   Does chemcraft ship world wide. Pretty much, check their web site. There are a few places they won't ship to. I have purchased from them many times with delivery to Australia.

Quote: Originally posted by MineMan

They seem way better than the polish oxnymet. Are there any better sites even? Nothing like this but a Chinese version?

Yahhh any update on increasing the density to the holy 2.0g/cc?

LITHEXAL

A new measurements shows (reccommended of MineMan) that adding 10% aluminium powder (bright type) into Lithex as two dry mixed fine powder compounds, provides very good results. Mixed at 150 celsia against moisturity, at dry. Time of mixing 2 minute. The brisantion is same but total energy of detonation is demonstrably bigger. Thus:

1) Aluminium (10%) can provide advantages of use less amount of Lithex, at retention same brisantion.
2) Aluminium (10%) increasing sensitivity for ignition to reliable level.
3) Because Lithex is neutral salt and mixing run in dry, the degradation of surface of Aluminium can be low in order weeks, months. ( only estimation yet)
4) Aluminium (10%) increases overall energy of detonation at same weight of compound.

By others examinations shows on variability of content of Aluminium, which can be from 3% to 12%. And always lends better properties than pure Lithex. A new mark LITHEXAL from Liptakov-MineMan research center....

[Edited on 13-2-2022 by Laboratory of Liptakov]

Lithex and Lithexal

To verify the critical diameter, a structure with an inner diameter of 4 mm was tested. Pure Lithex 150mg and 250mg were used as the output segment. For the starting DDT segment, 250 mg of low density Lithexal was used in both experiments.
The result is a coffee spoon with reduced resistance at stirring....

Quote: Originally posted by Laboratory of Liptakov

A new measurements shows (reccommended of MineMan) that adding 10% aluminium powder (bright type) into Lithex as two dry mixed fine powder compounds, provides very good results. Mixed at 150 celsia against moisturity, at dry. Time of mixing 2 minute. The brisantion is same but total energy of detonation is demonstrably bigger. Thus: 1) Aluminium (10%) can provide advantages of use less amount of Lithex, at retention same brisantion. 2) Aluminium (10%) increasing sensitivity for ignition to reliable level. 3) Because Lithex is neutral salt and mixing run in dry, the degradation of surface of Aluminium can be low in order weeks, months. ( only estimation yet) 4) Aluminium (10%) increases overall energy of detonation at same weight of compound. By others examinations shows on variability of content of Aluminium, which can be from 3% to 12%. And always lends better properties than pure Lithex. A new mark LITHEXAL from Liptakov-MineMan research center.... [Edited on 13-2-2022 by Laboratory of Liptakov]

Quote: Originally posted by Laboratory of Liptakov

To verify the critical diameter, a structure with an inner diameter of 4 mm was tested. Pure Lithex 150mg and 250mg were used as the output segment. For the starting DDT segment, 250 mg of low density Lithexal was used in both experiments. The result is a coffee spoon with reduced resistance at stirring....

Lithex from Schweizer's reagent

I have no idea how is finelity of aluminum. It is aluminum for use as a silver colorant. So probably very fine, with oxidation protection. But we also need to think about those researchers who have no powdered aluminum or magnesium. For those, there is a variant with CuO. A new method for preparing flame-sensitive Lithex was also tested. Dissolve 1 g of Lithex in 10 g of Schweizer's reagent. The exact value of concentration of reagent ​​are not important. Briefly, concentrated Schweizers reagent 25% NH 4 OH in aq. The solution is poured onto a pan (at 20C) and dried at 170 ° C. At 80 C arise green heterogenous mixture. The dry mixture has a light brown color and is very sensitive on flame. Its brisance is about 10% lower than that of pure Lithex. His sensitivity on impact it higher. But as a starting - wire segment, it is excellent. The disadvantage of Lithex remains his hygroscopicity. Filling must take place at 40 Celsius. This applies to all handling tools and components. I guess the copper detonator wouldn't explode even if hitted with a hammer. But I won't try ....

SWL

To diversify of thread, I enclose the production and test of SWL, ie Lithex, prepared from white basic Lithex (LiClO4 77 / hexamine 23) + Schweizer reagent. The concentration was 2g Lithex per 10g reagent. Thus, twice the Lithex content than stated above (1:10) The results are almost the same. High sensitivity on flame.

Thanks,
It may be tried sometime in the future. At present, this thread deals mainly with primary-secondary compositions based on LiClO4....

Lithex - shaped charge

Rhodium is obviously interesting, but also very expensive. I doubt anyone will try. Including me.
Next: A test was performed to determine if Lithex was able to create a beam. The insert: Copper 0.4 mm, diameter 8 mm, angle cca 80 deg. , distance 12 mm from target. Unfortunately, the experiment was not very successful, two rays were generated. The penetration depth was estimated at 5 - 7 mm. So the beam did not penetrate even the first steel target 10 mm.

Nitrosio from time to time appears as a mysterious spirit and utters a cryptic formulas mixtures that only the greatest experts understand ............



[Edited on 17-2-2022 by Laboratory of Liptakov]

Quote: Originally posted by Laboratory of Liptakov

Nitrosio from time to time appears as a mysterious spirit and utters a cryptic formulas mixtures that only the greatest experts understand ............ [Edited on 17-2-2022 by Laboratory of Liptakov]

Oh yes, I know ethyleglycol...In short, it came to me as such a mysterious link....

Quote: Originally posted by Laboratory of Liptakov

Nitrosio from time to time appears as a mysterious spirit and utters a cryptic formulas mixtures that only the greatest experts understand ............

Quote: Originally posted by Laboratory of Liptakov

Oh yes, I know ethyleglycol...In short, it came to me as such a mysterious link....

LL LMAO

Quote: Originally posted by Laboratory of Liptakov

Rhodium is obviously interesting, but also very expensive. I doubt anyone will try. Including me. Next: A test was performed to determine if Lithex was able to create a beam. The insert: Copper 0.4 mm, diameter 8 mm, angle cca 80 deg. , distance 12 mm from target. Unfortunately, the experiment was not very successful, two rays were generated. The penetration depth was estimated at 5 - 7 mm. So the beam did not penetrate even the first steel target 10 mm.

TACP from LiClO4

TACP can be prepared from LiClO4. In same method as with NH4ClO4. Unfortunately, it is a trihydrate. And crystalline water is impossible to remove. At 180 C, TACP decomposes to copper and LiClO4. However, this compound it is possible to decompose in boiling water to CuO + LiClO4. The LiClO4 thus obtained can be used again for the production of Lithex. (80:20) Which provides a standard brisance, like Lithex prepared from pure LiClO4 + hexamine 80:20.

Thanks. MineMan. Thanks for the great support. Much of what you write is true. Many similar substances (with DDT capability) end up in the vaults of national laboratories. I'm sure of that. But Lithex is hygroscopic and requires a solid cavity. So it is not a particularly revolutionary invention. On the other hand, Lithex is interesting in that:

1) is highly thermally stable.
2) can be easily overdried before filling. (at 170 C in 10 minutes)
3) its preparation consists in simply mixing oxidizer and fuel.

No need for desiccator, Buchner device + vacuum pump, pH measurement, distillation, cooling, crystallization. Or other laboratory equipment or procedure. All you need is a pan and a steel scraper. There are not many pyrotechnic compounds in the world that can withstand frying in a pan. And scraping at 170 C. Often similar mixtures decompose. Or they explode when scratched. However: I think, that Lithex has pretty good international interest. The thread is 6 weeks old and has over 6,000 views. Not everyone wants to present a comment. Especially in this strategic field. It will be similar to CHP. Takes years than Lithex (or derivates as Lithexal) will recognized as usefulness compound for safetely initiation. The history of inventions has one thing in common. Any new thing in the first place ... I repeat in the 1st row ..has meets with distrust.....This is a natural law.

Quote: Originally posted by Laboratory of Liptakov

Thanks. MineMan. Thanks for the great support. Much of what you write is true. Many similar substances (with DDT capability) end up in the vaults of national laboratories. I'm sure of that. But Lithex is hygroscopic and requires a solid cavity. So it is not a particularly revolutionary invention. On the other hand, Lithex is interesting in that: 1) is highly thermally stable. 2) can be easily overdried before filling. (at 170 C in 10 minutes) 3) its preparation consists in simply mixing oxidizer and fuel. No need for desiccator, Buchner device + vacuum pump, pH measurement, distillation, cooling, crystallization. Or other laboratory equipment or procedure. All you need is a pan and a steel scraper. There are not many pyrotechnic compounds in the world that can withstand frying in a pan. And scraping at 170 C. Often similar mixtures decompose. Or they explode when scratched. However: I think, that Lithex has pretty good international interest. The thread is 6 weeks old and has over 6,000 views. Not everyone wants to present a comment. Especially in this strategic field. It will be similar to CHP. Takes years than Lithex (or derivates as Lithexal) will recognized as usefulness compound for safetely initiation. The history of inventions has one thing in common. Any new thing in the first place ... I repeat in the 1st row ..has meets with distrust.....This is a natural law.

It looks like there has been another breakthrough in the Lithex brisance. The unsuccessful reaction of TACP production from LiClO4 gave a change in color and consistency after 3 days. The dark blue turned to a light blue suspension. The light blue color is most likely copper hydroxide. Hydroxy-contaminated LiClO4 was dried. At 180 C. The hydroxide decomposed to CuO. (estimate) A sample of thus contaminated LiClO4 was mixed with hexamine in the usual ratio of 80:20. The maximum pressure was used when filling the cavity. A density of 1.818 g / cm3 was achieved. For an output segment weighing 400mg. The brisance at this density is the same as that of highly pressed ETN 400 mg.
Thus, the depth of the crater is 7.5 mm with a crater diameter of 19 mm. Because the tests are shot in lead, an error of at least 10% must be taken into account.
Anyway, MineMan had truth. If the Lithex can be compressed to high density, its brisance will be identical to ETN. Which has just been confirmed. The mixture thus prepared has, of course, excellent flame sensitivity. Therefore, it is not necessary to use a different chemical substance for ignition in the cavity. Lithex with CuO (xy%) works as a monopropelant with incredible brisance.