Sciencemadness Discussion Board

mercury (I) chromate + photos

vano - 23-12-2020 at 09:01

mercury (I) chromate. It is a red powder. It doesn't dissolve in water. I made it from sodium chromate and mercury(I) nitrate dihydrate.

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vano - 23-12-2020 at 09:04

More photos and reagents which i used.

[Edited on 23-12-2020 by vano.kavt]

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Bedlasky - 23-12-2020 at 22:25

Nice! When I was at high school, I learned about classical qualitative inorganic analysis (and also did some lab practice). But I never worked with Hg(I) salts and I always want to see some Hg(I) compounds. I have small amount of elementar Hg, maybe I'll try make this compound.

Metacelsus - 24-12-2020 at 12:36

How stable is this? Will chromate eventually oxidize the Hg(I) to Hg(II)?

vano - 24-12-2020 at 22:33

Quote: Originally posted by Metacelsus  
How stable is this? Will chromate eventually oxidize the Hg(I) to Hg(II)?


It is stable. Heat to 400 degrees Celsius as follows:
4Hg2CrO4 → 2HgCrO4 + 6HgO +O2

Cou - 24-12-2020 at 23:00

Holy sh*t, mercury AND chromate all in one? That's a toxicity double whammy!

vano - 24-12-2020 at 23:25

Quote: Originally posted by Cou  
Holy sh*t, mercury AND chromate all in one? That's a toxicity double whammy!


Not so poisonous, because it is insoluble, the main thing is not to inhale the powder and because it is a heavy compound the powder does not stay in the air for long.

[Edited on 25-12-2020 by vano.kavt]