Sciencemadness Discussion Board

Calcium electrolysis with alternative salts

John paul III - 2-11-2019 at 03:42

Shouldn't it be easy (in theory) to find a Calcium salt with a low melting point (CaH2PO4 melts at 109°C) and perform an ordinary electrolysis to obtain Calcium? Calcium is said to be hard to make by an amateur

wg48temp9 - 2-11-2019 at 04:23

Quote: Originally posted by John paul III  
Shouldn't it be easy (in theory) to find a Calcium salt with a low melting point (CaH2PO4 melts at 109°C) and perform an ordinary electrolysis to obtain Calcium? Calcium is said to be hard to make by an amateur


I would think using an acid phosphate the hydrogen would be released first.

Using a eutectic with salts that can not be reduced easily, from memory the eutectic can contain sodium or potassium. I think there is a thread about it.

Sorry I could not find the thread.

[Edited on 11/2/2019 by wg48temp9]

John paul III - 2-11-2019 at 04:46

Damn I wish I could find this thread. Do you remember any details, like what the anions could have been?

WGTR - 2-11-2019 at 04:51

Have fun:

http://www.crct.polymtl.ca/fact/documentation/FTsalt/FTsalt_...

John paul III - 2-11-2019 at 06:19

Thank you!

wg48temp9 - 2-11-2019 at 07:19

Quote: Originally posted by John paul III  
Damn I wish I could find this thread. Do you remember any details, like what the anions could have been?


I had an other search and found the following but I don't think its the one I was thinking about.

We successfully made a small amount of calcium metal by electrolysis of a barium chloride, calcium chloride, strontium chloride and potassium chloride (http://www.google.com/patents/US3226311). Addition of the other chlorides lowers the melting point of the mixture to around 600 C (and calcium is pretty much the product). We were wondering if barium could be made in a similar way.

Does anyone know anything about this?

[Edited on 11/2/2019 by wg48temp9]

wg48temp9 - 2-11-2019 at 07:34

Quote: Originally posted by John paul III  
Thank you!


Search for "Calcium electrolysis" there are a few more