nitro-genes - 18-2-2019 at 14:14
Here a rough first version of the copper/ascorbic mediated reduction of styphnic acid to styphnamic acid and some properties of the corresponding
diazo derivative. Ha! Another obscure diazoquinone bites the dust! ![:D](./images/smilies/biggrin.gif)
Thoughts, ideas, criticism welcome
Input on the most likely mechanism by which
the cupric/ascorbic mediated reduction works would be especially appreciated. ![:)](./images/smilies/smile.gif)
Attachment: Synthesis and some properties of 2-amino 4,6-dinitroresorcinol and 2-diazo 4,6-dinitroresorcinol (rough version).pdf (2.5MB)
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[Edited on 18-2-2019 by nitro-genes]
VSEPR_VOID - 13-7-2019 at 14:30
very good work