Did they correct for the amount of volume in the sphere? If the wallthickness of the sphere decreases due to a larger cavity with increasing explosive
amount, then the energy is of course increasingly more efficiently transferred to aid expansion.
There probably is a large database having all these test data for a large number of known explosives. Wondered if it would be interesting to put them
all in a statistical model and look at correlations and interactions between various physical properties. Most likely however, many of the test
results would show strong correlations with many factors but also interactions, which would limit it's use to make ab inito predictions, even more so
since the conditions of the test itself probably interact somewhat with the explosive used to determine the outcome. All explosive properties like
density, VoD, energy released, volume and nature of gasses produced, etc will interact not only with each other, but also with the test itself. Even
with a very large dataset and all tests performed under the most rigorously controlled conditions, there would be far to many factors to separate to
come to a robust predictive model IMO.
Although not directly related to your post, similar things might happen when comparing primaries using LBT, a big confounder here would be the
acceleration of the detonation wave, which is much faster for azides for example then for DDNP. It would be interesting to see whether small scale LBT
for primaries like you desribe indeed would be a good predictor of "initiation potential".
[Edited on 2-1-2016 by nitro-genes] |