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Thiodinitromethane
[quote]
According to the web there is no such thing
[/quote]

Do you have access to Scifinder a ...
6-1-2014 at 13:00
by: vulture
Observations on forum "atmosphere" and negativity - a rant
You're completely right, I only talk about how great and without fault I am. And I only posted it fo ...
12-12-2013 at 14:36
by: vulture
Observations on forum "atmosphere" and negativity - a rant
Actually the title of this post is misleading - on purpose- and maybe by the end of this "rant" you' ...
12-12-2013 at 13:35
by: vulture
The true mad science, hydrogen azide distillation
[quote]
if I were to make this myself, I would have done it at 1/30th the scale in a short path di ...
7-12-2013 at 05:59
by: vulture
Experiments in Electronics
My electronics knowledge is pretty limited, but couldn't this also be the result of induction in the ...
6-12-2013 at 07:12
by: vulture
Pseudoscience & Willful Ignorance
[quote]
You can use 'other measurements' such as gravitational or Hawking radiation effects but thi ...
6-12-2013 at 07:09
by: vulture
The true mad science, hydrogen azide distillation
[quote]
You seem proud of what you did, and as a chemist I feel that you have no respect for my fie ...
6-12-2013 at 06:49
by: vulture
cutting shapes in metal with shaped charge
This discussion is too practical and you're asking to be spoonfed.

I hope you get to meet bubba w ...
5-12-2013 at 12:34
by: vulture
Pseudoscience & Willful Ignorance
[quote]
I'd argue that vaccines are actually an example of homeopathy that works: they use a dilute ...
3-12-2013 at 14:25
by: vulture
The true mad science, hydrogen azide distillation
I'm taken aback by the negative responses in this thread.


[quote]
If you are seeking to risk y ...
3-12-2013 at 13:46
by: vulture
Is this vacuum pump likely to be at all useful?
Filtration, yes.

Distillation, if you are satisfied with 400 mbar vacuum, maybe.

It looks like ...
3-12-2013 at 13:35
by: vulture
Dye Sensitized Solar Cell- TiO2 not sticking to glass
You can try making the glass more hydrophilic by treatment with ammonia and peroxide (3:1) or piranh ...
3-12-2013 at 13:08
by: vulture
Synthesis of calcium carbide with electric arc
Given the possible hydrogen content I would caution against the chlorine test.
25-11-2013 at 14:31
by: vulture
CaC2 + H2O2 30% => BOOM ??
Probably nothing is going to happen. The autoignition temperature of acetylene is listed as 350C, th ...
24-11-2013 at 15:09
by: vulture
Synthesis of calcium carbide with electric arc
Making copper acetylide is indeed a good test for acetylene. The question is how to safely dispose o ...
24-11-2013 at 15:06
by: vulture
2,5-Dibromo-1,4-benzoquinone Reactivity?
In the second step, are you sure you will only selectively epoxidize one double bond?

I don't und ...
23-11-2013 at 03:33
by: vulture
HCl + AgNO3 = HNO3 + AgCl : How?
Generally I classify acids as acids when they are capable of protonating water. I find this a useful ...
22-11-2013 at 06:04
by: vulture
heating lithium aluminum hydride with heating mantle
Excess LAH can be destroyed safely (no H[sub]2[/sub] formation) by adding ethylacetate.

[Edited on ...
22-11-2013 at 01:50
by: vulture
HCl + AgNO3 = HNO3 + AgCl : How?
[quote]
I think so, yes. If, say, HCl wasn't dissociated then the chlorine atom would be less readi ...
22-11-2013 at 01:46
by: vulture
urushibara catalyst preparation
Pyridine is a very good complexing agent for nickel.

NiCl[sub]2[/sub] has limited solubility in E ...
21-11-2013 at 02:44
by: vulture
2,5-Dibromo-1,4-benzoquinone Reactivity?
I had a quick look at the file, but not long enough to say anything definitive.

It seems that the ...
19-11-2013 at 14:37
by: vulture
Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]
I don't agree that you can talk about a "(MgiPr)+ moiety" for a bulk metal surface, there a ...
19-11-2013 at 01:00
by: vulture
Speculative reaction of alcohols to carbonic acids with Mg and CO2
Your iPr-Mg species, or whatever you want to call it, cannot exist.

To form it from Mg(OiPr)[sub ...
18-11-2013 at 14:16
by: vulture
Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]
The forward reaction: iPrOCO2- + e- => iPr* + CO32-, makes CO32- which means this step i ...
18-11-2013 at 12:16
by: vulture
Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]
I hear you, but alkyl carbonates are also alkylating agents... granted weak ones, but never ...
18-11-2013 at 10:24
by: vulture
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