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Using the Acetone enolate from Sodium Hydroxide
[rquote=327499&tid=30097&author=AvBaeyer]You can use sodium hydroxide to form the enolate of ...
13-4-2014 at 17:53
by: FireLion3
Using the Acetone enolate from Sodium Hydroxide
Hmmm just read a few articles that say the condensation product is favored at lower temperatures, ye ...
13-4-2014 at 16:44
by: FireLion3
Using the Acetone enolate from Sodium Hydroxide
The acetone enolate is useful for a variety of reactions, though when searching for instances of its ...
13-4-2014 at 15:46
by: FireLion3
Easy OTC oxidative cleavage of alkenes - Real or more BS?
[rquote=324231&tid=29702&author=forsh]Yeah. I'm getting everything together and i'm going to ...
25-3-2014 at 22:24
by: FireLion3
What sort of base is strong enough to deprotonate aldehydes but not ketones?
What kinds of bases would be best suited to deprotonate an aldehyde but not a ketone? For my particu ...
22-3-2014 at 21:33
by: FireLion3
Halogenation of alkyl side chains, selectivity?
I read that for instance N-Bromosuccinimide would brominate at a different position than would eleme ...
20-3-2014 at 11:46
by: FireLion3
Halogenation of alkyl side chains, selectivity?
What causes some side-chain halogenations to take place adjacent to the aromatic ring, while others ...
19-3-2014 at 22:24
by: FireLion3
What conditions favor dehydration of aldol condensation products?
Most literature, formal and informal, imply after the Ph-Nitroalcohol is formed during a Nitroaldol ...
8-3-2014 at 12:46
by: FireLion3
Pd/H2 reduces aldehydes to alkanes or alcohols?
We can use the example above. In the case of a benzyl alcohol, how easily does it go to the alkane? ...
27-1-2014 at 11:36
by: FireLion3
Pd/H2 reduces aldehydes to alkanes or alcohols?
I haven't really been able to find a clear answer on this. Rather, many sources claim Pd takes aldeh ...
27-1-2014 at 06:54
by: FireLion3
Methylenation - Where does the halogen go?
Thanks... that is what I was assuming, though initially I wasn't sure if the halogen would evaporate ...
19-1-2014 at 15:28
by: FireLion3
Methylenation - Where does the halogen go?
[rquote=316000&tid=28591&author=DraconicAcid]If an anionic nucleophile reacts with a haloalk ...
19-1-2014 at 14:07
by: FireLion3
Methylenation - Where does the halogen go?
I have indeed read the paper..... probably 10x+... that portion you quoted tells me nothing about wh ...
19-1-2014 at 13:28
by: FireLion3
Methylenation - Where does the halogen go?
I have attached a paper below which I will be using as my main reference.

I've occasionally look ...
19-1-2014 at 13:20
by: FireLion3
How does Pd/C catalytic hydrogenations work?
Exactly. Palladium temporarily dissolves/separates the H2 so that it can gain or lose its electrons ...
12-1-2014 at 09:35
by: FireLion3
How does Pd/C catalytic hydrogenations work?
Indeed thank you for the link, leu. That is probably far more than what I asked for, as I feel it ex ...
11-1-2014 at 19:41
by: FireLion3
How does Pd/C catalytic hydrogenations work?
Pd is put on carbon to maximize the surface area and increase the reaction, to my knowledge.

Wha ...
11-1-2014 at 16:42
by: FireLion3
How does Pd/C catalytic hydrogenations work?
I haven't been able to find much information about this online. Information that I have found is lim ...
11-1-2014 at 16:10
by: FireLion3

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