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DIPEA from alanine?
A quick SciFinder search gives no examples of N-disopropylations of alpha-amino acids. Of course, N- ...
10-3-2009 at 03:29
by: Nicodem
heptamethylbenzenium ion
It's just the sigma complex of hexamethylbenzene with methyl cation. Put this SMILE-s notation in a ...
9-3-2009 at 00:04
by: Nicodem
DIPEA from alanine?
In that trp.decarbox.enone.html page I could not find a single example of a N,N-dialkyl-alpha-aminoa ...
8-3-2009 at 23:58
by: Nicodem
DIPEA from alanine?
Please provide a reference for N-alkylation of aminoacids with isopropanol under acidic conditions.
...
7-3-2009 at 07:32
by: Nicodem
Condensation of substituted phenols with aldehydes
[quote][i]Originally posted by Ebao-lu[/i]
But i think, authors of the petant are not just junkies ...
7-3-2009 at 06:19
by: Nicodem
DIPEA from alanine?
What is IpOH? And what kind of thermal decarboxylation is supposed to work on such a substrate?

P ...
7-3-2009 at 06:09
by: Nicodem
The short questions thread (1)
[quote][i]Originally posted by kclo4[/i]
Does anyone know how to determine if a chemical will pass ...
6-3-2009 at 00:16
by: Nicodem
Preparation of cyanides
Acylcyanides (R-CO-CN) also very easily hydrolyse to carboxylic acids (carboxylates in basic) and hy ...
4-3-2009 at 00:58
by: Nicodem
oxalic acid reaction with secondary amines
I don't have a clue what "a heavier secondary amine" is supposed to mean, but I guess this should go ...
2-3-2009 at 00:35
by: Nicodem
anit-markovnikov HBr
There are several examples of radical addition of HBr to styrene in the literature. Why don't you do ...
2-3-2009 at 00:31
by: Nicodem
PABA > Aniline
In literature there are only examples using the Cu/quinoline method for decarboxylating p-aminobenzo ...
2-3-2009 at 00:20
by: Nicodem
The short questions thread (1)
[b](1R)-N-Methylisobornylamin[/b]: bp 89-90°C at 10 torr; Alpha<sub>D</sub> = -73.2° ...
27-2-2009 at 04:33
by: Nicodem
Thiourea Dioxide --> better than borohydride?
[quote][i]Originally posted by Ebao-lu[/i]
I guess the reaction with carbonyl compounds is not obli ...
26-2-2009 at 02:36
by: Nicodem
The short questions thread (1)
Which isomer? Endo or exo at the amine group? Why don't you give a CAS number or correct name. It is ...
26-2-2009 at 02:31
by: Nicodem
Threads disappearing highhandedly
[quote][i]Originally posted by chief[/i]
Sauron was loosing a self-started argument ... ; noone can ...
26-2-2009 at 00:21
by: Nicodem
Thiourea Dioxide --> better than borohydride?
Thanks, that is exactly what I wanted. I'm glad they made an ESR experiment that confirmed the radic ...
25-2-2009 at 23:51
by: Nicodem
Cinnamamide purification
It seems obvious you are trying to work up a reaction mixture from a Heck coupling, so first of all ...
25-2-2009 at 04:09
by: Nicodem
Thiourea Dioxide --> better than borohydride?
I would have to be able to read and understand Chinese to tell you which page or paragraph. Surely t ...
25-2-2009 at 02:04
by: Nicodem
Thiourea Dioxide --> better than borohydride?
Bolt: No they are not. You misread.

Baphomet, thanks a lot, but could you please also take care a ...
24-2-2009 at 10:29
by: Nicodem
The short questions thread (1)
[quote][i]Originally posted by pantone159[/i]
I have a bottle of sodium sulfide, that I got about 2 ...
23-2-2009 at 00:43
by: Nicodem
Thiourea Dioxide --> better than borohydride?
Baphomet, for the beginning it would be enough if you could only translate the tittles and substrate ...
23-2-2009 at 00:16
by: Nicodem
Alkenes from alcohols- a problem
[quote][i]Originally posted by Sandmeyer[/i]
I don't see why Chugaev would be selective for that pa ...
20-2-2009 at 10:06
by: Nicodem
Salting out Caffeine
As far as I know cocoa ([i]Theobroma cacao[/i] seeds) is the only plant product that contains large ...
20-2-2009 at 00:41
by: Nicodem
Alkenes from alcohols- a problem
Artemisia, up to now you only tried various methods for E2 elimination, but that can not be selectiv ...
20-2-2009 at 00:31
by: Nicodem
Thiourea Dioxide --> better than borohydride?
[quote][i]Originally posted by 497[/i]
For example its redox potential at pH 13 is -750mV while NaB ...
20-2-2009 at 00:13
by: Nicodem
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