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Novichoks and Related 3rd/4th Gen. OP Agents
The Russians call the reaction between phosphites and alpha-trihalonitro/nitrosoalkanes to form oxim ...
8-7-2008 at 08:53
by: Sauron
CBrCl3 -> CCl4 or CHCl3?
CBrCl3 boils at 105 C.

CCl4 at 76 C.

How about using NCS or TCCA as Cl2 source, refluxing the ...
8-7-2008 at 08:13
by: Sauron
4-dimethylaminopyridine
This stuff is very toxic.

If you buy it, buy it in prilled form, easily handles, easily recovered ...
8-7-2008 at 07:22
by: Sauron
CBrCl3 -> CCl4 or CHCl3?
Antimony trichloride or pentachloride, maybe.

I found some p-chem lit. on using these equilibria ...
8-7-2008 at 07:14
by: Sauron
Small complaint on moving new post.
You can't fight city hall. Nicodem is moderator of the Org.Chem. forum and moderator at large.

It ...
8-7-2008 at 06:48
by: Sauron
7-zip Problem
So I'm a chauvinist. So is that news?

Seriously, there ought to simply be a language selection in ...
8-7-2008 at 06:36
by: Sauron
7-zip Problem
Thanks much. I now have 7-zip in English (and did not need to use regedit.)

However, all attempts ...
8-7-2008 at 06:01
by: Sauron
CBrCl3 -> CCl4 or CHCl3?
Generating the Cl3C. radical is a good way to get hexachloroethane which isn't my target.

So at t ...
8-7-2008 at 05:35
by: Sauron
7-zip Problem
I installed this archiver in order to unpack Chem Rev from MadHatter.

The installer gives no opti ...
8-7-2008 at 01:27
by: Sauron
CBrCl3 -> CCl4 or CHCl3?
As it happens, chloroform and carbon tetrachloride are restricted where I live. Fortunately, bromotr ...
7-7-2008 at 23:44
by: Sauron
Which Operating System do you use?
I am using XP Pro SP2 also and have previously used every version of Windows since and including 3.0 ...
7-7-2008 at 20:14
by: Sauron
Code for 'diester'?
It has come to my attention that my claim upthread to be the first to illustrate the structures of a ...
7-7-2008 at 18:44
by: Sauron
Errata and Corrections
A few errors to correct:

All references to A-240 and A-244 should read A230 and A-234.

There i ...
7-7-2008 at 18:14
by: Sauron
Names of dicarboxylic acids
I long for the days when it was just a lactone and BDO was just a glycol and GHB was a health food s ...
7-7-2008 at 06:11
by: Sauron
Names of dicarboxylic acids
I'd have thought you were capable of recognizing sarcasm when it stares out from the page.
7-7-2008 at 01:32
by: Sauron
Novichoks and Related 3rd/4th Gen. OP Agents
Note that the Na2S2O4 is sodium dithionite and NOT dithionate which is Na2S2O6. Sodium dithionate i ...
6-7-2008 at 18:53
by: Sauron
Novichoks and Related 3rd/4th Gen. OP Agents
Hmmm. It appears that bromotrichloromethane (a heavy liquid) is commercially available and cheap, an ...
6-7-2008 at 18:11
by: Sauron
5MeO - DMT
No that thread has not been deleted. The FSE found it right away.

http://www.sciencemadness.org/t ...
6-7-2008 at 17:44
by: Sauron
5MeO - DMT
I believe in my Melatonin thread you proposed this and Nicodem explained to you why it won't work.
...
6-7-2008 at 05:48
by: Sauron
Novichoks and Related 3rd/4th Gen. OP Agents
The Prandtl paper with preparation of sodium trichloromethanesulfinate is attached. Most of the pape ...
6-7-2008 at 05:33
by: Sauron
Novichoks and Related 3rd/4th Gen. OP Agents
In regard to the oxidation step of the rxn scheme above for trichloronitrosomethane, the oxidation r ...
5-7-2008 at 22:24
by: Sauron
Methcathinone - watch that manganese!
I'm shocked and dismayed that clandestine drug cooks anywhere could be so incompetent and negligent ...
5-7-2008 at 19:44
by: Sauron
Novichoks and Related 3rd/4th Gen. OP Agents
As the alpha-substituents on the nitro or nitrosoalkanes have to be Cl plus any combination of Cl, ...
5-7-2008 at 07:42
by: Sauron
Psychoactive monoterpenes from natural oils
I know nothing about pulegone, but thujone (which is by the way pronounced two-yone) is a mild GABA ...
5-7-2008 at 07:24
by: Sauron
Novichoks and Related 3rd/4th Gen. OP Agents
Now we are ready to fully understand the reaction of alpha-trihalonitroalkane or -nitrosoalkane with ...
5-7-2008 at 01:19
by: Sauron
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