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lightning storms
Lightning rockets...amazing! :) What are the odds of actually triggering a lightning strike and how ...
1-6-2018 at 12:27
by: nitro-genes
Bad days in the lab or with glassware?
It is always one of these unforeseen interactions in seemingly simple systems that can make large di ...
30-5-2018 at 15:46
by: nitro-genes
Azides
[file]68323[/file]

[Edited on 22-5-2018 by nitro-genes]
22-5-2018 at 04:34
by: nitro-genes
Azides
Silver azide directly from hydrazine sulfate


[b] Be very cautious with this reaction, don't sc ...
19-5-2018 at 05:06
by: nitro-genes
Short question / quick answer - Thread
https://www.youtube.com/watch?v=ctJDPjnZ3Ag

Curious how easily one of these could be sanded down ...
11-5-2018 at 12:59
by: nitro-genes
Looking over the border: EU-Regulations
All challengers? Traffic lights included? :P

6-5-2018 at 09:30
by: nitro-genes
SM Challenge - thoughts?
Production of synthetic precious opal seems like an interesting challenge. Basically, opal consists ...
29-4-2018 at 13:52
by: nitro-genes
Short question / quick answer - Thread
The 3-nitrogroup of 2,3,4,6-tetranitroaniline is easily displaced by nucleophiles:

1. Reaction wi ...
21-4-2018 at 12:59
by: nitro-genes
What is cause of global warming? Heat or gases?
This seems relevant:

http://uscentrist.org/platform/positions/environment/context-environment/doc ...
17-4-2018 at 11:16
by: nitro-genes
What is cause of global warming? Heat or gases?
If CO2 and temperature are showing an not completely known interaction, why did they use CO2 measure ...
28-3-2018 at 17:07
by: nitro-genes
synthesis of O-nitroaniline
Would the sulfonation/nitration also work for toluene? Adding toluene to a very large excess of 98% ...
26-3-2018 at 16:09
by: nitro-genes
DDNP & related compounds: The über thread!
Would be interesting to know how exactly the reduction is occuring. Would something like this (Copp ...
26-3-2018 at 11:32
by: nitro-genes
A strange explosive from the Internet
This also seems like an interesting read.

https://www.chemistryworld.com/opinion/comment/3005172. ...
24-3-2018 at 06:30
by: nitro-genes
synthesis of O-nitroaniline
Stupid, ethanol is much more easily oxidized than methanol, also the cyanuric by product is much mor ...
24-3-2018 at 03:45
by: nitro-genes
synthesis of O-nitroaniline
Thanks for the replies, the route going from chlorobenzene was considered, because, apart from aceta ...
23-3-2018 at 11:25
by: nitro-genes
A strange explosive from the Internet
Seems to be based on the synthesis of acetylene multimers, like was first thought to be the result o ...
22-3-2018 at 14:58
by: nitro-genes
synthesis of O-nitroaniline
Without glacial acetic acid and acetic anhydride, would the following synthesis, starting from chlor ...
22-3-2018 at 11:55
by: nitro-genes
DDNP & related compounds: The über thread!
Regarding the Cu(II)/ascorbic reduction of picric to picramic:

Would nano-copper itself be able t ...
21-3-2018 at 13:05
by: nitro-genes
Strange observation during ascorbic reduction of copper(II) sulfate
so here is a simple experiment of which I'm not sure how to explain it.


Experiment 1:

1 g co ...
17-3-2018 at 05:13
by: nitro-genes
Picric to Styphnic
It seems the internal diazo derivative of 3-amino picric (or the diazonium nitrate) can be precipita ...
12-3-2018 at 11:53
by: nitro-genes
Picric to Styphnic
[rquote=510048&tid=5406&author=hissingnoise]Has anyone on this thread considered nitrating r ...
10-3-2018 at 10:01
by: nitro-genes
DDNP & related compounds: The über thread!
On heating picric to its ignition point, there is a definite sign of reduction going on, maybe picra ...
9-3-2018 at 15:31
by: nitro-genes
Picric to Styphnic
Tried the amination of picric on a larger scale this time:

All glassware and stirrerbars were tho ...
9-3-2018 at 15:07
by: nitro-genes
DDNP & related compounds: The über thread!
There is no way iron will work in high yield using ascorbic or using Fe(0). The Fe(II)(hydr)oxide me ...
7-3-2018 at 17:20
by: nitro-genes
DDNP & related compounds: The über thread!
Of all transition metals, copper seems to have the highest catalyzing effect on the reaction of asco ...
7-3-2018 at 15:44
by: nitro-genes
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