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Synthesis of longer chain tertiary alcohols
[rquote=434809&tid=15171&author=aga]

What second double bond ?

[/rquote]

[file]471 ...
10-1-2016 at 15:09
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434803&tid=15171&author=aga]In this JPL paper

[url]https://www.researchgate.net/p ...
10-1-2016 at 14:14
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434798&tid=15171&author=aga][b]I.[/b] The catalyst (the acid) is clearly explained i ...
10-1-2016 at 13:54
by: blogfast25
Synthesis of longer chain tertiary alcohols
Apart from Wagner–Meerwein rearrangment(s), other common by products like β and γ-terpineol can ...
10-1-2016 at 12:21
by: blogfast25
Synthesis of longer chain tertiary alcohols
@aga:

Nice!

Could you cut and paste the conversion of the chloral hydrate to TCA for me here? ...
10-1-2016 at 10:17
by: blogfast25
Preparation of Ammonium Molybdate from Molybdenum Disulfide
[rquote=434728&tid=25611&author=j_sum1]Thanks for this Magpie.
I am considering making some ...
10-1-2016 at 09:41
by: blogfast25
Problem with the "sup" button
"I wonder if there's a way to format:

We have a force
$$F=ma$$
acting..."

... in such a wa ...
10-1-2016 at 09:07
by: blogfast25
Synthesis of longer chain tertiary alcohols
An example of (hydro)chlorination, without solvent and with dry HCl:

http://www.orgsyn.org/demo.a ...
10-1-2016 at 08:50
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434765&tid=15171&author=aga]
Using the last of the 99%+ ethanol (~150ml) in a test ...
10-1-2016 at 08:29
by: blogfast25
Hydrochlorination of alk-1-ene?
Does anyone have experience/information on the (hydro)chlorination of alk-1-enes with anhydrous HCl ...
10-1-2016 at 08:26
by: blogfast25
Synthesis of longer chain tertiary alcohols
[quote]Page 99 of "Practical Organic Chemistry, J B Cohen" (available in the SM library) details the ...
10-1-2016 at 07:30
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434745&tid=15171&author=Nicodem]
Trichloroacetic acid with its pKa of 0.66 is hardl ...
10-1-2016 at 07:05
by: blogfast25
And then there's limonene...
[url=https://en.wikipedia.org/wiki/Limonene]Limonene[/url] is very OTC and very cheap and a known pr ...
10-1-2016 at 07:03
by: blogfast25
Synthesis of longer chain tertiary alcohols
Very good research, aga.

Let's keep TCA on hold for a minute but it could be useful also with reg ...
10-1-2016 at 06:31
by: blogfast25
Synthesis of longer chain tertiary alcohols
Thanks for the *.pdf. TCA is hard to get and expensive.

[rquote=434700&tid=15171&author=a ...
9-1-2016 at 17:01
by: blogfast25
Synthesis of longer chain tertiary alcohols
Got a link to the paper with trichloroacetic acid as catalyst?

Without a minimum of H[sub]3[/sub] ...
9-1-2016 at 15:36
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434688&tid=15171&author=aga]Initially the mixture is spun up for 20 to 24 hours.

...
9-1-2016 at 13:25
by: blogfast25
Preparation of Anhydrous Aluminum Chloride from Cupric Chloride and Aluminum
[rquote=434682&tid=64677&author=aga][rquote=434643&tid=64677&author=blogfast25]As fa ...
9-1-2016 at 12:45
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434683&tid=15171&author=aga]Another batch of alpha-terpineol has been prepared as pe ...
9-1-2016 at 12:42
by: blogfast25
The Short Questions Thread (4)
[rquote=434684&tid=25055&author=arkoma]Thanx Blog. So to get KOH:

K[sub]2[/sub]CO[sub]3[ ...
9-1-2016 at 12:36
by: blogfast25
Titanium compounds out of TiO2
[rquote=434661&tid=64967&author=mohd jalal]I want to prepare Titanium nitrate tetrahydrate ...
9-1-2016 at 07:03
by: blogfast25
Preparation of Anhydrous Aluminum Chloride from Cupric Chloride and Aluminum
@Magpie:

As far as I know Al doesn't combine with Cl[sub]2[/sub] when starting at RT (unlike with ...
8-1-2016 at 19:24
by: blogfast25
The Short Questions Thread (4)
[rquote=434636&tid=25055&author=arkoma]have crude, dark KOH from oak ashes--decolorizing adv ...
8-1-2016 at 19:14
by: blogfast25
When Chemistry Goes Wrong
[rquote=434630&tid=63645&author=aga]

I noticed butyric acid a while back, although saw no ...
8-1-2016 at 16:02
by: blogfast25
Preparation of Anhydrous Aluminum Chloride from Cupric Chloride and Aluminum
[rquote=434626&tid=64677&author=clearly_not_atara][quote] 'peach', many moons ago, tried to ...
8-1-2016 at 15:29
by: blogfast25
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